Correction to “Synthesis of Mono- and Diiron Dithiolene Complexes as

Publication Date (Web): February 21, 2019. Copyright © 2019 American Chemical Society. Cite this:Organometallics XXXX, XXX, XXX-XXX. View: ACS ...
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Correction to “Synthesis of Mono- and Diiron Dithiolene Complexes as Hydrogenase Models by Dithiolene Transfer Reactions, Including the Crystal Structure of [{Ni(S2C2Ph2)}6]” Harry Adams, Michael J. Morris,* Craig C. Robertson, and Helen C. I. Tunnicliffe Organometallics, 2019, 38(3), 665−676. DOI: 10.1021/acs.organomet.8b00852

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e have been informed by Prof. Ulrich Fekl that his group has prepared and structurally characterized a third example of a hexanuclear palladium dithiolene cluster, [{PdS2C2(CF3)2}6].1 Their paper also includes an elegant analysis which proves that the S6 and chiral C2 isomers are the only two possible for clusters of this type. The authors apologize for this omission.



REFERENCES

(1) Moscattini, J.; Lough, A. J.; Fekl, U. C2-isomer of [Pd(tfd)]6 [tfd is S2C2(CF3)2] as its benzene solvate: a new member of the small but growing class of homoleptic palladium(II) monodithiolenes in the form of hexameric cubes. Acta Crystallogr. 2017, E73, 957−962.

© XXXX American Chemical Society

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DOI: 10.1021/acs.organomet.9b00090 Organometallics XXXX, XXX, XXX−XXX