Addition/Correction Cite This: J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
pubs.acs.org/JACS
Correction to “Tunneling Control of Chemical Reactions: The Third Reactivity Paradigm” Peter R. Schreiner J. Am. Chem. Soc. 2017, 139, 15276−15283. DOI: 10.1021/jacs.7b06035 Pages 15279 and 15280. Reference 60 was inadvertently placed out-of-context on p 15280, right column, line 23, after the sentence ending “...making mass spectrometric observation challenging.” The citation should have appeared instead on p 15279, right column, line 18, after “...all barriers have very similar overall shapes).” The following sentence should also be added at the same place: “These findings have been supported and extended through the independent preparation of a chargetagged phenylhydroxycarbene derivative, namely 4-(trimethylammonio)phenylhydroxycarbene, that also undergoes facile [1,2]H-tunneling at temperatures of 320−350 K with a half-life of about 10 s as probed by infrared ion spectroscopy utilizing an infrared free electron laser.60 ” The author thanks Mathias Schäfer, Jos Oomens, Anthony Meijer, and Albrecht Berkessel for alerting him to this issue.
© XXXX American Chemical Society
A
DOI: 10.1021/jacs.8b00446 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
