Correction to Chelate Restrained Boron Cations for ... - ACS Publications

Correction to Chelate Restrained Boron Cations for Intermolecular Electrophilic Arene Borylation. Alessandro Del Grosso , Robin G. Pritchard , Chris A...
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Addition/Correction pubs.acs.org/Organometallics

Correction to Chelate Restrained Boron Cations for Intermolecular Electrophilic Arene Borylation Alessandro Del Grosso, Robin G. Pritchard, Chris A. Muryn, and Michael J. Ingleson* 2010, 29 (1), 241−249

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n Table 3 and the related discussion, the assignment of the two major products from the borylation of toluene using equimolar CatBCl/Et3Si[CbBr6] and then CatBH were originally incorrectly assigned as ortho and para CatB(tolyl). Subsequent studies have unambiguously shown that the two major products are actually the meta and para isomers of CatB(C6H4Me) (with a relative ratio of 1.2:1), with only negligible quantities of the ortho regioisomer formed.

Published: February 22, 2012 © 2012 American Chemical Society

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dx.doi.org/10.1021/om3000899 | Organometallics 2012, 31, 2116−2116