Addition/Correction pubs.acs.org/JACS
Correction to Fusarisetin A, an Acinar Morphogenesis Inhibitor from a Soil Fungus, Fusarium sp. FN080326 Jae-Hyuk Jang, Yukihiro Asami, Jun-Pil Jang, Sun-Ok Kim, Dong Oh Moon, Kee-Sun Shin, Daisuke Hashizume, Makoto Muroi, Tamio Saito, Hyuncheol Oh, Bo Yeon Kim,* Hiroyuki Osada,* and Jong Seog Ahn* J. Am. Chem. Soc. 2011, 133, 6865−6867. DOI: 10.1021/ja1110688 S Supporting Information *
Page 6866. In the discussion of compound 6, the following sentences should be corrected: (i) The magnitudes of ... at C-8 and C-9 are axial and equatorial, respectively; (ii) The observed negative exciton chirality ... leading to the assignment of the 8R and 9S configurations in 6; and (iii) Therefore, the absolute stereochemistries ... determined as 1R, 3S, 4R, 5S, 6S, 7S, 10S, 12R, 15R, and 16S. Consequentially, the structures for compounds 1−6 (Chart 1) were drawn with incorrect stereochemistry and have been corrected, as shown below. These structures have also been corrected in the Supporting Information. Chart 1. Structures of Compounds 1−6
Page 6867. The secondary y axis of Figure 4A should be changed from cell growth inhibition to cell viability. The authors apologize for any inconvenience caused by these errors. Page 6867. The following should be included in the Acknowledgment: The authors express their thanks to Dr. Go Ueno for his kind assistance with synchrotron radiation experiments. The synchrotron radiation experiments were performed at BL26B2 at SPring-8 with the approval of RIKEN (Proposal No. 20090072).
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ASSOCIATED CONTENT
S Supporting Information *
Experimental details, spectral data for compounds, and biological data (corrected). This material is available free of charge via the Internet at http://pubs.acs.org.
Published: April 10, 2012 © 2012 American Chemical Society
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dx.doi.org/10.1021/ja302285e | J. Am. Chem. Soc. 2012, 134, 7194−7194