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Apr 23, 2012 - Enantioenriched secondary allylic carbamates have been deprotonated with sBuLi and reacted with boronic esters. In contrast to other electrophiles, high α-selectivity was observed and the boronate complexes were formed with almost com
Apr 23, 2012 - Soc. , 2012, 134 (17), pp 7570â7574 ... [email protected] ... The boronate complexes underwent a stereospecific 1,2-migration leading to tertiary ... Jeffrey BruffaertsAlexandre VasseurSukhdev SinghAhmad MasarwaDorian .... Jou
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Nov 16, 2010 - School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 ... 132, 48, 17096-17098 ... boronic esters) or TBAF·3H2O (on tertiary aryldialkyl boronic esters) .... LithiationâBorylation Methodology and Its Application i
Apr 17, 2017 - Highly enantioselective rhodium-catalyzed hydroboration of allylic phosphonates by pinacolborane affords chiral tertiary boronic esters. The β-borylated phosphonates are readily converted to chiral β- and γ-hydroxyphosphonates and a
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Addition/Correction pubs.acs.org/JACS
Correction to Synthesis of Enantioenriched Tertiary Boronic Esters from Secondary Allylic Carbamates. Application to the Synthesis of C30 Botryococcene Alexander P. Pulis and Varinder K. Aggarwal* J. Am. Chem. Soc. 2012, 134, 7570−7575. DOI: 10.1021/ja303022d S Supporting Information *
The Supporting Information file containing experimental details was not included with the original publication. The Supporting Information file is now available.
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ASSOCIATED CONTENT
S Supporting Information *
Experimental procedures and analytical data for all compounds. This material is available free of charge via the Internet at http://pubs.acs.org.
