Correlated transition structure for the 1,5-sigmatropic hydrogen shift

May 1, 1987 - J. Am. Chem. Soc. , 1987, 109 (10), pp 3139–3140. DOI: 10.1021/ja00244a043. Publication Date: May 1987. ACS Legacy Archive. Note: In l...
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3139

J. Am. Chem. SOC.1987, 109, 3139-3140 related to the enzyme-catalyzed hydrolysis of the phosphate. TWO major lines of evidence are consistent with this conclusion. When the enzyme concentration is varied over a factor of 4, the rate constant changes only slightly (