Addition/Correction Cite This: J. Phys. Chem. B XXXX, XXX, XXX−XXX
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Correction to “Correspondence between Spectral-Derived and Viscosity-Derived Local Composition in Binary Liquid Mixtures Having Specific Interactions with Preferential Solvation Theory” Alif Duereh, Yoshiyuki Sato, Richard Lee Smith, Jr.,* and Hiroshi Inomata
J. Phys. Chem. B Downloaded from pubs.acs.org by 185.14.195.225 on 12/22/18. For personal use only.
J. Phys. Chem. B 2018, 122 (48), 10894−10906. DOI: 10.1021/acs.jpcb.8b09511 The authors found that the images of Figure 4 and Figure 8 were transposed in the production process. Proper images of Figure 4 and Figure 8 including captions are shown below in which water−acetonitrile is seen to have a maximum in its viscosity versus composition diagram, whereas the viscosity of hexane−2-propanol mixtures are monotonically increasing. The transposition of the images does not change the conclusions of the study.
Figure 8. Nonpolar−polar mixture of hexane (component 1) with 2propanol (component 2) showing (a) viscosity-derived local compositions 2, (b) spectral-derived local compositions, (c) dynamic viscosity (η), and (d) UV wavelength (λmax) of 4-nitroaniline indicator as a function of bulk mole fraction of component 2 (x2) at 25 °C. Lines: xL1 (blue), xL2 (red), and xL22 (---).
Figure 4. Aqueous mixture of acetonitrile (component 2) showing (a) viscosity-derived local compositions, (b) spectral-derived local compositions, (c) dynamic viscosity (η), and (d) UV wavelength (λmax) of 4-nitroaniline indicator as a function of bulk mole fraction of component 2 (x2) at 25 °C. Local compositions in parts (a) and (b) are calculated using eqs 12−14 with viscosity- and spectral-derived preferential solvation parameters in Table 1. Lines: xL1 (blue), xL2 (red), and xL12 (---).
© XXXX American Chemical Society
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DOI: 10.1021/acs.jpcb.8b11928 J. Phys. Chem. B XXXX, XXX, XXX−XXX
