Diastereoselection in intermolecular nitrile oxide ... - ACS Publications

Jerry R. Mohrig, Robert E. Rosenberg, John W. Apostol, Mark Bastienaansen, ... Randall W. King, Christopher J. Larson, Hallie A. Latham, David A. Owen...
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5788

J. Am. Chem. Sot. 1982, 104, 5788-5789

0, were carried out for prolonged periods, -5 h, with less than 50% loss of [Q/QH2lsurf,.Since the reduction of 0, is mass transport limited, fractional loss of [Q/QH2],,,f, need not lead to an equal fractional decline in observed current density. In such experiments we have determined >lo6 turnovers at > l o 0 turnovers/s for the [Q/QH21surf,reagent without decline in current density. Concentrations of several millimolar H202in pH 7.2 H,O/electrolyte have been generated with >90% Coulombic efficiency. The W/ [Q/QH2lsurf, electrodes are durable in deliberately prepared 0.1 M H202pH 7.2 solutions and still efficiently reduce 0, to H202under these conditions for at least 30 min with