Monograph pubs.acs.org/doi/book/10.1021/acsreagents
Diethylamine (N-Ethylethanamine) Part 4, Monographs for Reagent Chemicals: General Descriptions, Specifications, and Tests eISBN: 9780841230460 Tom Tyner Chair, ACS Committee on Analytical Reagents James Francis Secretary, ACS Committee on Analytical Reagents
ABSTRACT This monograph for Diethylamine provides, in addition to common physical constants, a general description including typical appearance, applications, change in state (approximate), aqueous solubility, density, and pKa. The monograph also details the following specifications and corresponding tests for verifying that a substance meets ACS Reagent Grade specifications including: Assay, Monoethylamine, Triethylamine, Color (APHA), and Water.
C4H11N
Formula Wt 73.14
CAS No. 109-89-7
GENERAL DESCRIPTION Typical appearance . . . . . . . . Applications . . . . . . . . . . . . . Change in state (approximate) . Aqueous solubility . . . . . . . . . Density . . . . . . . . . . . . . . . . pKa . . . . . . . . . . . . . . . . . .
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clear liquid buffer formulation boiling point, 56 °C very soluble 0.71 11.0
SPECIFICATIONS Assay . . . . . . . . . . . . . . . . . . . . . . . . . . . . ≥99.0% C4H11N Maximum Allowable Color (APHA) . . . . . . . . . . . . . . . . . . . . . . . 20 Monoethylamine . . . . . . . . . . . . . . . . . . . . . 0.5% Triethylamine . . . . . . . . . . . . . . . . . . . . . . . 0.5% Water (H2O) . . . . . . . . . . . . . . . . . . . . . . . . 0.1%
© 2017 American Chemical Society
A
DOI:10.1021/acsreagents.4119 ACS Reagent Chemicals, Part 4
ACS Reagent Chemicals
Monograph
pubs.acs.org/doi/book/10.1021/acsreagents
TESTS Assay, Monoethylamine, and Triethylamine Analyze the sample by gas chromatography using the general parameters cited in [Part 2: Chromatography; Recommended Procedures; Gas Chromatography]. The following specific conditions are also required. Column . . . . . . . . . . . . . . . . . . . . . . . . . . Type I, methyl silicone Measure the area under each peak, and calculate the diethylamine, monoethylamine, and triethylamine content in area percent. Correct for water content.
Color (APHA) [Part 2: Measurement of Physical Properties; Color (APHA); Procedure for Color (APHA)].
Water [Part 2: Titrimetric Methods; Water by the Karl Fischer Method; Coulometric Procedure; Coulometric Procedure for Samples Using Karl Fischer Reagent, Method 2]. Use 50 µL (35 mg) of the sample.
© 2017 American Chemical Society
B
DOI:10.1021/acsreagents.4119 ACS Reagent Chemicals, Part 4
