A Forty Year Odyssey in MetalloâOrganic Chemistry. Kenneth M. ... Journal of the American Chemical Society 1980 102 (22), 6887-6888. Abstract | PDF | PDF w/ ...
Reaction of electrochemically generated iron(â0") porphyrins with alkyl halides allows one to ... formation of tertiary alkyl iron porphyrins has not hitherto .... 7, 1989. Gueutin et al. 0EP. ETIOP. Figure 1. Iron porphyrins investigated in this w
May 15, 1994 - Structures and Reactivity of the Acyl Complex toward Dioxygen. Alan L Balch,* Marilyn M. Olmstead, Nasser Safari, and Tamara N. St. Claire.
Apr 3, 2008 - Andrew D. Burrows , Ross W. Harrington , Andrew S. Kirk , Mary F. Mahon , Frank Marken , John E. Warren and Michael K. Whittlesey.
Alan L. Balch, Marilyn M. Olmstead, Nasser Safari, and Tamara N. St. Claire. Inorg. Chem. , 1994, 33 (13), pp 2815â2822. DOI: 10.1021/ic00091a023.
Nov 26, 2008 - Neutral and cationic iron alkyl complexes supported by diimine ligand (Ph2CN)2C2H4 were prepared. For cationic iron alkyl complex ...
Qiuming Liang , Andrew Salmon , Patrick Jinhyung Kim , Linfan Yan , and Datong .... Sylviane Isoz and Carlo Floriani , Kurt Schenk , Angiola Chiesi-Villa and ...
Jun 21, 2018 - When a suspension of Fe2(CO)9 and 1 in CH3CN was transferred in a sealed microwave glass vial and stirred for 18 h at 110 °C the complex [Fe(PCPNEt-iPr)(CO)2Cl] (2) was obtained. In an attempt to ... Protonation of 5 with HBF4·Et2O a
Jun 21, 2018 - *K.K.: E-mail, [email protected]; tel, (+43) 1 58801 163611; fax, (+43) 1 58801 16399. ... glass vial and stirred for 18 h at 110 °C the complex [Fe(PCPNEt-iPr)(CO)2Cl] (2) was obtained. ... Protonation of 5 with HBF4·Et2O a
N
II
N
Ar
N
N
- e-
Fe iPr
+
iPr
N
N II Fe
N
Ar N
- eiPr
N
Ar
II Fe
N
N iPr
iPr
Low Spin Fe(II) [PDI]2-
iPr
High Spin Fe(II) [PDI]1-
High Spin Fe(II) [PDI]0
Bis(imino)pyridine iron alkyl complexes across three oxidation states have been synthesized and it has been shown that all redox changes occur at the ligand, not the metal center. The cationic versions of these compounds are the first single component iron polymerization catalysts and shed important light on the nature of the active species in these important processes.
