[6]Paracyclophane - Journal of the American Chemical Society (ACS

Vinayak V. Kane, Anthony D. Wolf, and Maitland Jones Jr. J. Am. Chem. ... Suzanne W. Slayden and Joel F. Liebman ... Joel F. Liebman and Arthur Greenb...
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Kt, and K, are similar,lg reasonable since R and R’ are both primary. Kt

R’MgR

+ MgBrz 1-RMgBr + R’MgBr

(5)

K“

R’MgR’

+ MgBrz I_ 2R’MgBr

(6)

Since k,, B, and [R]o are known, kl and K , can be determined from eq 4. This task is simplified by noting that when [RzMg]