A Facile Pyrimidine Ring Cleavage: Corrections - ACS Publications

1, line 21, for “4-allyl” read “4-alkyl.” Page 6059: In col. 1, formula III should be. (SCH,COO. ^ -('ß 5. >™Xl X. HA.O. N. CeHe ill. SCH.C...
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CORRECTIONS

2786

Kinetic Studies of ADP Reactions with t h e Temperature Jump Method-Corrections BY

h f A N P R E D EIC;EhTAND

GORDON G. HAMMES’

The original communication2 concerning kinetic studies of A D P reactions contained several printing errors in the tables of rate constants. In order to rectify this matter, the tables are reprinted correctly here. The definitions of the various rate constants are contained in the original publication.

Vol. 83

In line 6 , for “have” read “has.” I n line ZJ, for “(X-XII)” read “ ( X - X I ) . ” I n line 34, delete “ ( R = -SCHa).” In col. 2, line : S i , for “tleriv~ttions” read “derivatives.” I n the last line, delete

“9.’> Page ( i O i j 0 : I n col. 1, lormulas XlI’c ant1 X\s’J should be

TABLE I kij.1O-a >\.I-’h i . l O - ‘ sec. -1 sec. -1

J,si,lO-:

.w-’

Reactants

+ PR

sec. -1

ksa.lO-1@

M-1 kdkp4“

sec. - 1

3 4 3.0 21 7 0.06 A4DP CPK 20 1 1.9 2.3 0.53 ATP f PK 4.8 7 0.06 3.0 15 ATP CPR 20 0.8 1 9 2.3 0.39 (’Deterrnitied from the equilibrium constarits of ,4DP, .‘ITP3 and the indicators (measured by pH- arid spcctrophot mietric tit rat i o i i ~ , *\UP

+ +

In line F, for “were’ read “ 1 ~ 5 I n col. 2, the formula T h e formula to the right of X X I I I should be under X X I should be

TABLE I1 kulO-J Reactants

kIg++ + A D P Mg-+ ATP C a + + f ADP c a + + ATP

+ +

sec.

-1

2.5 1.2 >400 >250

kri. 10 -7 iw10 .n .If-: k z t ~ l O ~1 L~ P ’ k?i/k1aY k n i l l l n r ’ sec. - 1 sec. -1 sec. -1 .W-1 M-1

0.3 1.2 >25 >io0

3 3

... ...

1 3 ,

..

...

103.1

101.5

Page G O G 1 :

102,” 102.8 . . io36

111

col 1, the loriiiulds slioultl be

a &

i01-fi

(1) D e p a r t m e n t of C h e m i s t r y , Rlassachusetts I n s l i t u t e of Techiiology, Cambridge, Massachusetts. ( 2 ) >I. Eigen a n d G. G. H a m m c s , J . A i n . Cheiii. Sor., 82, 3951

(I!EO). ( 8 ) A. E. YIarteII and G. S c h a a r z e n b a c h , Helv. C/ii.n. R ; i i i . 39, Q.j.3 (IS.jli!.

Max PLAXCK INSTITUT FUR PHYSIKALISCHE C ~ m m G U E T T I N G E X , GERMANY RECEIVED APRIL1, 1961 ~~

~~

A Facile Pyrimidine Ring Cleavage : Corrections Ur- EULVARD C. TAYLOR, ROBERT J. LNOPF, J. -4. COGLIASO, J. W. BARTONA N D WOLFGASCPFLEIDERER

’The text of this article as it appears in Tins 82, (iO38.:( 1XiO) was not seen in proof by the author before printing, and hence contains a number of errors which are corrected herein : tlic author’s reprints h a r e been printed from the correctcd forin. Page (XES: I n the list of authors, for “I’leitferer” read “Pfleiderer.” I n col. 1, line 21, for “4-allyl” read “4-alkyl ” Page (XL59: 111 col JOURNAL,

~

SXV 0

I’agc ( M 2 : 111 col. 1, liiic ;jlj, for “ref. 7” r e a 1 “ref. 17.” 111 footnote (?I), for “ AZauiitncr” read “llautiier.” 111 col. 2 , line 17, for “pryiinidinc” read “pyriniidiiic.*’ 111 line 3:3, for “,50 g.” r e d Til liiie “50 g.” I n line 39, for ‘‘15’’rcnd “150,” 46,for “forin” read “froin.” F K I C K CHEMICAL T , A B U R A r O R Y

PRINCETOS UNIVERSITY PRISCETOS, K, J

K E C l l I \ . t s l > J.4NUARY

20, I?((;]