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A nexus approach for sustainable urban EnergyWater-Waste systems planning and operation Xiaonan Wang, Miao Guo, Rembrandt H.E.M. Koppelaar, Koen Haziel van Dam, Charalampos P Triantafyllidis, and Nilay Shah Environ. Sci. Technol., Just Accepted Manuscript • DOI: 10.1021/acs.est.7b04659 • Publication Date (Web): 31 Jan 2018 Downloaded from http://pubs.acs.org on January 31, 2018

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A nexus approach for sustainable urban Energy-Water-Waste

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systems planning and operation

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Xiaonan Wanga,b*, Miao Guoa*, Rembrandt H.E.M. Koppelaara,c, Koen H. van Dama,

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Charalampos P. Triantafyllidisa,d, and Nilay Shaha

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a

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London SW7 2AZ, UK

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b

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117585

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c

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d

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* Email: [email protected] [email protected]

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Centre for Process Systems Engineering, Department of Chemical Engineering, Imperial College London,

Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore

Centre for Environmental Policy, Imperial College London, South Kensington, London SW7 2AZ, UK Department of Chemical Engineering, University College London, London WC1E 7JE, UK

Tel: +65 6601 6221 +44 020 7594 5705

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ABSTRACT:

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Energy, water and waste systems analyzed at a nexus level is key to move towards more

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sustainable cities. In this paper, the “resilience.io” platform is developed and applied to emphasize

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on waste-to-energy pathways, along with the water and energy sectors, aiming to develop waste

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treatment capacity and energy recovery with the lowest economic and environmental cost. Three

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categories of waste including wastewater (WW), municipal solid waste (MSW) and agriculture

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waste are tested as the feedstock for thermochemical treatment via incineration, gasification or

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pyrolysis for combined heat and power generation, or biological treatment such as anaerobic

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digestion (AD) and aerobic treatment. A case study is presented for Ghana in Sub-Saharan Africa,

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considering a combination of waste treatment technologies and infrastructure, depending on local

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characteristics for supply and demand. The results indicate that the biogas generated from waste

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treatment turns out to be a promising renewable energy source in the analyzed region, while more

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distributed energy resources can be integrated. A series of scenarios including the business-as-

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usual, base case, natural constrained, policy interventions and environmental and climate change

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impacts demonstrate how simulation with optimization models can provide new insights in the

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design of sustainable value chains, with particular emphasis on whole-system analysis and

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integration.

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1. Introduction

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With rapid urbanization, particularly in the developing world, cities are facing sustainability

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challenges on the nexus of energy, water and waste commensurate to financially feasible and

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reliable infrastructure systems planning.1,2 The projected 50% increase in global population in 21st

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century will lead to 11.2 billion people by the end of this century.3 This combined with the non-

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OECD economic growth is expected to bring a 33% increase in energy demand globally by 2050.4

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Energy is the dominant contributor to Greenhouse Gas (GHG) emissions and waste-to-energy

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pathways have been identified by the IEA as one of the promising solutions for a low-carbon

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pathway towards the 2°C warming scenario.5 Moreover, rising waste generation yields additional

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GHG contributions and other environmental impacts. For instance, one-third of food produced

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globally is lost or wasted every year, which is responsible for over 7% of the GHG emissions and

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the waste of 250 km3 water (8.5% annual withdrawn).6 The choice of waste-to-energy

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technologies, their deployment and logistics of which depend on local conditions including

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demands and availability of resources and associated networks, imply that a spatially explicit

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representation and computer-aided planning is imperative.7 To support investments and

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operational decisions for sustainable infrastructure systems development in cities, systems

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modeling approaches can be deployed taking into account energy-water-waste cross-sectoral

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integration, spatial-temporal resource flows and allocation, long-term socio-economic and

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environmental targets as well as technical constraints from a whole systems perspective.8–10 Our

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thorough literature review shows that previous research has been conducted in the energy supply-

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demand optimization and system analysis under a developing country context, e.g., energy system

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planning and forecasting, remote-area distributed renewable energy, bioenergy research

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optimization and waste-to-energy systems.11–13 Applications in support of the energy-water-food

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nexus planning has become a central focus in the current research agenda of developing systematic

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modeling tools.14–18 However, there is a significant gap on the decision-making tools bridging

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water-energy-waste sectors with supply-demand needs at both spatial and temporal scales, despite

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the fact that many tools have been developed and used effectively for individual domains.19–21

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In this paper we present the application of an integrated decision-making tool based on the

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resilience.io platform, which provides a series of modules to allow forecasting of socio-

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demographic scenarios, simulating spatio-temporal activities, and planning investment and

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operational strategies to meet the Sustainable Development Goals (SDGs).22 We developed the

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platform to study urban systems interactions through socio-economic forecasting, agent-based

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modeling, and resource-technology network optimization. The consensus among multiple sectors

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in decision making using these simulation and optimization tools has been effectively applied to

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the water-energy-food nexus in previous research to deliver both economic and environmental

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benefits.23,24 By introducing life cycle sustainability assessment (LCSA) and optimization into the

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developed resilience.io platform, system-wide economic, environmental and social sustainability

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perspectives have been incorporated and bridged with supply and demand across multiple-sectors.

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LCSA addresses the overall sustainability impacts associated with infrastructure, individual

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sectors and their interrelationship, or the entire urban development plan from a cradle-to-grave

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perspective.25 In combination with assessing policy support, such as a Feed-In Tariff (FIT) scheme

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(remunerating the sales of surplus electricity from technology operation back to the grid), our

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modeling tool incorporated green financial investment strategies to investigate the policy

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implications on the system performance.26 In addition to the commonly existing centralized

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systems, decentralized technologies have also been incorporated into our model, where the

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application of a systematic optimization tool is of critical importance for transparent urban service

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systems planning.27 A case study and scenario-based approaches demonstrate our model’s

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applicability in a developing country context, where possible cross-sector solutions for water,

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energy, waste and food for Ghana were scrutinized.28

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The capital city of Ghana and its neighboring administrative districts form the Greater Accra

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Metropolitan Area (GAMA). It is a rapidly growing metropolitan region, where great efforts have

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been placed to improve local community livelihood and city sustainable development particularly

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in the water sector. Household access to piped water grew by more than 80% from 2000 to 2010

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and potable water provisioning has been improved dramatically in recent years. The city has seen

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large expansions of potable water treatment at the Kpone site north of the city-region (several

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hundreds of thousands m3 per day), as well as the addition of a 60,000 m3 per day desalination

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plant.29,30 However, the percentage of total wastewater treatment (WWT) declined from around

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10% to nearly zero between 2000 and 2010, whilst the population of GAMA grew from 3 to 4

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million people. Nearly all untreated wastewater therefore is discharged to the environment. Minor

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improvements have been made by introducing a lagoon-based treatment plant with a capacity of

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6,400 m3 per day at the University of Ghana Legon and efforts are underway to rehabilitate the

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Jamestown treatment plant. Yet, these facilities are far from being adequate and the WWT sector

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in this region still faces significant challenges on system development and maintenance due to the

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financial constraints which conflict with the increasing environmental concerns.

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A promising solution would be to recover the resources contained in the wastewater. Anaerobic

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digestion (AD) has been widely acknowledged as an effective technology for the energetic

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valorization of various organic feedstock which is not only constrained to the wastewater, but also

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applicable to organic solid wastes such as agro-industrial residuals and municipal solid waste.31

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AD can transform waste treatment from an energy consumer to a net producer due to a 2-4 times

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higher energy recovery from the waste than the AD operational demands.32 The generated biogas,

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as one of the highlighted prioritized renewable fuels, has multiple applications, e.g. direct

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and compressed as transport fuel. In fact, biogas has been recognized as a rising renewable energy

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source in both rural and urban areas of many African countries.33 Such a combined production of

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heat, electricity and fertilizer provides a transitional scheme for local residents in Ghana. It can

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allow the mitigation of being heavily relied on burning traditional biomass and waste (e.g.

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firewood and charcoal) for household cooking and heating, which in turn has caused numerous

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environmental, health and safety concerns. Ghana has the potential to install a large number of

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biogas plants (54-865 MW installed capacity per year by estimation).34

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To incorporate these renewable technologies into the waste treatment and energy generation

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process, policy regulations that provide energy market support would be required to promote waste

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recovery and further penetration of renewable sources. A tariff scheme, which has been generally

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acknowledged as an effective deployment policy internationally and could potentially be adopted

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in Ghana, has been modeled in our case study to explore the potential role of this governmental

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intervention scheme. The applicability of a whole-system decision support tool to the broader

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developing country context is successfully illustrated by the presented regional application.

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The rest of the article is structured as follows. Section 2 first describes the overall life cycle

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approach, optimization formulation and associated models, followed by a detailed description of

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data input mechanisms. Section 3 mainly demonstrates how the overall methodology is applied to

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a Sub-Saharan African city-region to achieve cost-optimal and sustainable development plans

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especially in the water, energy and waste treatment sectors. A series of scenarios are analyzed

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including the “business-as-usual”, “base case”, “natural constrained”, “policy interventions” and

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“GHG reduction” related.

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2. Methods

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We developed the resilience.io platform initially for integrated resource planning, which mainly

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addresses water and energy, as well as their nexus.22 It is of paramount importance to connect the

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waste treatment especially waste-to-energy pathways to these utilities. In this work, only electricity

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is studied as the representative energy product, while heat and fuel are not included in the supply-

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demand forces, but only analyzed as additional output of the energy sector to the economy. The

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ultimate goal is to develop the treatment capacity and energy recovery with the lowest economic

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and environmental costs.

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2.1 General framework

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The overall modeling framework and data flows are illustrated in Figure 1, where three key

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components are soft-linked via data feedback loops including the resilience.io platform,

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optimization and LCSA. LCSA is an evaluation tool accounting for three sustainability pillars i.e.

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life cycle environmental assessment (LCA), life cycle costing (LCC) and life cycle social

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assessment (S-LCA).

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The resilience.io platform incorporates a series of modules to perform forecasting of socio-

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demographic scenarios, simulation of spatial-temporal supply/demand profiles and planning

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investment and operational strategies to meet the SDGs for multiple sectors including water,

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energy, food and waste. For the urban region under investigation, a comprehensive database with

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respect to the current resource availability, waste treatment capacity and distribution is built based

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on national and local statistics. Key references include household water use,35 total water use and

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treatment capacity,36 waste-water treatment plants,37 new infrastructure projects,38, and household

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infrastructure access.39 More exhaustive cleaned and referenced datasets for these aspects have 7 ACS Paragon Plus Environment

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been deposited on the openAfrica data portal.40 The spatially explicit waste generation and

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resource demands are projected by using agent-based models embedded in the resilience.io

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platform. The behaviors of diverse population groups are captured, which are categorized by their

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geographical district (original and real-time in the agent-based simulation), age, gender, work

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force, income rank and access to infrastructure. The overall sustainability footprints of

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technologies and the whole socio-technical system have been evaluated using LCSA inclusive of

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social (e.g., job creation, gender equality), economic (including capital costs, operating and

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maintenance costs) and environmental (e.g., climate change) aspects. The module that optimizes

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the resource technology network uses the current pre-allocated infrastructure (existing on-the-

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ground technologies), as per above and described in the deposited openAfrica data for

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initialization.40 This module incorporates novel technologies for waste resource recovery taking

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into account land-use (e.g., land types and available area) and fiscal budget (e.g., as a maximum

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cap of total costs or relaxed to obtain the optimal planning) constraints, with an objective to

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minimize the system-wide economic and environmental costs. The results provide development

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plans for alternative technologies, infrastructure as well as production and transportation schedule

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in order to meet the SDGs.

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2.2 Optimization model structure

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The interrelationship between water, waste and energy systems is addressed through material and

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energy balances. The main optimization problem is formulated as a mixed-integer linear

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programming (MILP) problem, with a multi-objective function which accounts for capital

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expenditures (CAPEX), operating expenditures (OPEX), and environmental impacts (mainly

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GHG emissions, monetized by carbon trading prices). The additional environmental costs

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associated with the nexus, such as the impact on air quality, human health and ecosystem quality,

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are obtained from the life cycle impact analysis as part of the results, instead of directly being

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included as a cost function term in the objective function. The objective function as shown in Eq.

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(1) combines weighing factors (Wf) and metrics (m) including costs for investment (VIJ), O&M

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(VPJ), resource transportation (VQ), pipe and grid expansions (VY) and resource import costs (VI)

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with details given in Eq. (2). All spatial districts are represented by i, technology by j, resource by

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r, metric by m and time scale by t (minor time periods, e.g., hours in a day) and tm (major time

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periods, e.g., years). The detailed explanation of the variables, parameters and models can be found

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in the Supplementary Information (SI).

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Figure 1. Overall methodology for analysis of urban waste and energy sectors using decision support

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platform through Life Cycle Sustainability Assessment.

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Multiple waste streams are incorporated in the model including WW, MSW especially its organic

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fraction (OFMSW), and lignocellulosic agricultural waste (e.g., accumulated at plantations for

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treatment and energy recovery). Their geological distribution lays the foundation of quantifying

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the energy potential to be recovered through several pathways as per the superstructure diagram

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shown in Figure 2. Compared with traditional landfills or incineration to treat solid waste, catalytic

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thermal treatment (e.g., pyrolysis or gasification) or biochemical treatment (e.g., anaerobic

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digestion and aerobic process) can be promising avenue to recover energy from OFMSW in the

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form of heat and electricity. Meanwhile wastewater is often treated through chemical and aerobic

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processes or through anaerobic digestion, yielding a source of biogas for electricity or heating.

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Specifically, agricultural waste serves as a valuable resource for energy recovery via anaerobic

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digestion pathway.

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Figure 2. A superstructure diagram of waste and energy resource flows through multiple technologies.

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Z = ∑ m Wf (m, tm) M (m, tm)

(1)

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Where Wf (m,tm) and M(m,tm) represent the weighting factors and value for all metrics m

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evaluated in the objective function during time period tm respectively.

VM (m, tm) = ∑ j ∑ i VIJ ( j , i, m) INV ( j , i, m) + ∑ j ∑ i ∑ t VPJ ( j , i, t , m) P ( j , i, t , tm) + ∑ i ,i ' ∑ r ∑ t VQ(r , t , m) dist (i, i ') Q(r , i, i ', t , tm) + ∑ i ,i ' ∑ r VY (r , m) dist (i, i ') Y (r , i, i ', tm) + ∑ i ∑ r ∑ t VI ( r , t , m) IM ( r , i, t , tm)

(2)

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The optimization model implements a set of constraints to drive the system in satisfying the

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respective waste treatment needs and electricity demand. First, equality constraints were

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introduced to achieve mass and energy balances at each level for every technology at all spatial

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zones and during each time period. Secondly, available operable capacities for each technology

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determine the upper limits for operations. Flow limits based on pipe, transportation network and

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grid connections are also imposed, which are defined by the associated geometric distance in

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kilometers (km). Finally, the investment allowance provides an upper bound of the total allowed

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cost for further infrastructure expansion. Besides the present steady-state system planning, future

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conditions are also predicted and planned through the forecasting models accounting for key

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parameters, such as the evolution of the population, income, and employment status. The

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optimization problem was solved using the open-source GNU Linear Programming Kit (GLPK),

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as the default solver freely available for the published platform, to allow an expanded access on

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the user-side.

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2.3 LCSA and data input

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The ‘cradle-to-grave’ LCSA approach generalized as Eq. (3) has been adopted to evaluate the

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sustainability footprints of waste treatment and recovery, including gasification, pyrolysis,

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incineration and anaerobic digestion. The mid-point characterization approaches were adopted in

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the LCSA evaluation, e.g. CML baseline41 for LCA; cost-sub categories (e.g. operational cost,

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capital cost, labor costs) for LCC analyses42. As summarized in Table 1, the capital inputs and

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operation are modeled within the defined LCA system boundary based on the functional unit ‘per

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day operation for treating WW and/or bio-solid waste (including OFMSW and agricultural waste)’.

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An economic allocation is applied to the processes with multiple products, thus zero impacts

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caused by the upstream waste-generating process have been assigned to WW and OFMSW (by-

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products). A stoichiometric carbon-counting approach was used to ‘track’ the carbon flows from

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embedded carbon in waste chemical components (including carbon ‘sequestration’ into the

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agricultural waste at crop growth stage) and through waste treatment and recovery, as well as the

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release of carbon during anaerobic digestion and combustion.

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The spatially-explicit agricultural land use maps of the studied region were derived from statistical

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reports and academic studies27,43–45 which combined the biomass partitioning ratio, leading to an

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estimated distribution of agricultural lingocellulosic waste. These include the above-ground

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lignocellulosic residual fractions of cassava, maize and banana plants. Existing waste treatment

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facilities and future demographic changes were also derived from multiple published data

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sources.46–50 The empirical data was used in the LCSA evaluation of organic waste treatment and

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recovery (i.e. gasification, pyrolysis, incineration) based on the operation and capital input-output

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flows generated from the WRATE (Waste Resources Assessment Toolkit for the Environment

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generated by Golder Associates) model and empirical and operational data derived from a UK 12 ACS Paragon Plus Environment

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commercial AD plant.51 Data for other existing or potential technologies for electrical power sector

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such as hydroelectric, natural gas, coal and renewables (mainly PV and wind) were obtained from

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a combination of national reports and local data collection (see details in our previous work and

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references 52,53). Further process descriptions and data flows are detailed in the SI.

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Economic costs are analyzed through empirical process models with respect to input-output data

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of materials, feedstock, utilities and other consumed resources. The economic and social costs are

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then obtained through life cycle costing based on engineering estimation methods for each

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technology according to its characteristics. Table 1 provides an overview of environmental and

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economic performance in the waste treatment, especially waste-to-energy applications as an

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example. More information about the general energy sector including hydroelectric, fossil fuels

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and renewable energy generation can be found in the SI. 𝑖𝑖𝑖𝑖 𝑜𝑜𝑜𝑜𝑜𝑜 𝑜𝑜𝑜𝑜𝑜𝑜 𝑖𝑖𝑖𝑖 𝐸𝐸𝐼𝐼𝑘𝑘𝑘𝑘𝑘𝑘 = � � 𝐸𝐸𝐸𝐸𝐸𝐸𝑟𝑟,𝑘𝑘𝑘𝑘𝑘𝑘 𝑋𝑋𝑟𝑟,𝑠𝑠 + � � 𝐸𝐸𝐸𝐸𝐸𝐸𝑐𝑐,𝑘𝑘𝑘𝑘𝑘𝑘 𝑋𝑋𝑐𝑐,𝑠𝑠 𝑟𝑟

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𝑠𝑠

𝑐𝑐

(3)

𝑠𝑠

Where the variable 𝐸𝐸𝐼𝐼𝑘𝑘𝑘𝑘𝑘𝑘 denotes the total sustainability impacts of a given waste treatment and

recovery process (per functional unit) expressed as Key Performance Indicator kpi (e.g. cost and

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𝑖𝑖𝑖𝑖 GHG). 𝐸𝐸𝐼𝐼𝑘𝑘𝑘𝑘𝑘𝑘 is determined by the characterisation impact factors for input resource r (𝐸𝐸𝐸𝐸𝐸𝐸𝑟𝑟,𝑘𝑘𝑘𝑘𝑘𝑘 )

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s.

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The uncertainty analysis toolbox for LCSA is available under the integrated modeling framework,

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but exceeding the spectrum of the current scope. Under our uncertainty analysis tool, statistical

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methods (maximum likelihood estimation and goodness of fit) and expert judgement based

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approach (pedigree matrix) have been developed to quantify the inventory uncertainties due to

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cumulative effects of data variability or inventory uncertainties. At LCSA impact assessment level,

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𝑜𝑜𝑜𝑜𝑜𝑜 𝑖𝑖𝑖𝑖 𝑜𝑜𝑜𝑜𝑜𝑜 or emitted compound c (𝐸𝐸𝐸𝐸𝐸𝐸𝑐𝑐,𝑘𝑘𝑘𝑘𝑘𝑘 ) and the input or output flows (𝑋𝑋𝑟𝑟,𝑠𝑠 𝑜𝑜𝑜𝑜 𝑋𝑋𝑐𝑐,𝑠𝑠 ) at a life cycle stage

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a Monte Carlo simulation approach is introduced to estimate the uncertainties in characterised

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results introduced by the statistical variability or temporal, geographical and technology gaps in

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the inventory data. Such methodology functions can greatly amplify the confidence in the research

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findings and provide more robust and tangible evidence in the support of optimal decision-making.

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However, uncertainty analyses are not demonstrated in this paper but will be investigated in

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follow-up studies. Table 1 Model configuration for waste treatment and recovery technologies

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Treatment technology

Key operational parameter a

Waste streams (Input)

Life span a

Technology description a

Incineration

OFMSW

25year

Large-scale Efficiency=19% b moving grate incinerator

Gasification

OFMSW

Grate gasification

Efficiency= 18.8% b

Pyrolysis

OFMSW WW

Twin rotary kiln pyrolysis Continuous feeding thermophilic twostep digestion

Efficiency=13.3% b

Large-scale AD

25year 25year 20year

a

257 258 259 260 261 262 263 264 265

Efficiency= 17.2% b OLR for WW= 3.2 kg COD/m3/day c OLR for solid waste = 6 kg COD/m3/day

Biogas 94% COD conversion d OFMSW and Biogas -86% WW COD c conversion d OFMSW Corn Stover Literature-based biogas Cassava leaf estimation e Banana leaf Small-scale OFMSW 15Small-scale single Efficiency= 18.7% b Biogas: 86% AD year step digestion OLR=6 kg COD conversion d COD/m3/day c Banana leaf Literature-based Corn stover biogas Cassava leaf estimation e a. The representative AD and thermochemical pathways were modeled based on the operation and capital input-output flows generated from WRATE model and empirical and operational data derived from a UK commercial AD plant.54,55 b. Efficiency refers to the surplus electricity and heat generated and exported to grids from waste energy recovery. In incineration, on-site operation and transformation loss account for 22.1% electricity generated. Electrical conversion efficiency in AD is 20.35% with 15.7% and 8.1% of the generated electrical power consumed to operate large-scale and small-scale AD respectively.54,55 c. Organic loading rate (OLR) is measured in terms of the chemical oxygen demand (COD) of feed to a unit volume of digester per unit time56;. ORL of 3.17 kg COD/m3/day and 6 kg COD/m3/day was

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assumed for WWT and AD co-digestion (refer to co-digestion of wastewater and organic solid waste) , respectively.57,58 d. The COD removal efficiency for WWT and AD co-digestion was assumed as 99% (94% converted to biogas, 5% to cell mass) and 91% (86% converted to biogas, 5% to cell mass) respectively.54,55 e. The biogas production potential were estimated based on the empirical work on AD of lignocellulosic biomass as well as the representative data obtained from literature on chemical composition and characterisation of different waste streams in Ghana. 47,49,57–60

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3. Scenarios analysis and results

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The Greater Accra Metropolitan Area (GAMA) in Ghana, which has a large potential for energy

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recovery from waste, is studied here for its optimal development strategies. The model aims to

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satisfy waste treatment needs and electric power consumption for the region divided into sixteen

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functioning zones. We first forecast the required demand from base year 2010 until 2030 and

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benchmark it with statistical reports. A series of scenarios including “business-as-usual”, “base

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case”, “resource constrained”, “policy interventions” and “GHG reduction” are analyzed

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sequentially.

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3.1 Business-as-usual and base case scenarios

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A total of seven wastewater treatment methods, six municipal solid waste (including WW and

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MSW co-digestion) and two agro-waste treatment technologies for three locally common

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agricultural products (banana, cassava, and corn) were analyzed with respect to waste-to-energy

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pathways. An additional set of thirteen power generation technologies which are existing or

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promising to be utilized in Ghana are also accounted for in the case study to evaluate how energy

287

recovered from waste fits within the entire power system.

288

In a business-as-usual scenario, the existing infrastructure has little capacity to treat wastewater

289

and MSW and only 63% of total citizens’ electricity demand satisfied. Therefore, the resilience.io

290

model can largely contribute in providing an optimized investment and operations plan for all

291

potential and existing technologies which in return minimizes the total system cost. 15 ACS Paragon Plus Environment

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292

By investing on the available array of technologies, the municipal facilities can gradually meet all

293

citizens’ essential requirements and gradually reach each SDG by 2030. The CAPEX investment

294

to meet this goal was estimated around 16.87 billion USD for the GAMA region’s waste treatment

295

and power sector, excluding sunk investments in existing units evaluated in the base year (2010),

296

while the yearly OPEX by 2030 is estimated at 439.0 million with an associated 22.12 million

297

metric tonnes CO2 equivalent GHG emissions. It is evident from the results that large-scale

298

anaerobic digestion is a more effective solution among all wastewater treatment approaches, while

299

gasification and large-scale anaerobic co-digestion are suggested for MSW treatment. Combined

300

Cycle Gas Turbines (CCGT) and onshore wind energy conversion systems have dominant

301

advantages among power supply technologies due to their relatively low costs, accounting 63%

302

and 33% of total power supply respectively. However, the adoption of power facilities is limited

303

by the availability of fuel sources and renewable energy potential, especially for large-scale

304

application, which makes the “base case” optimized plan rarely feasible in real-world conditions.

305

To obtain a more realistic development plan, location and resource-specific constraints are added

306

when generating the investment and operation strategies, so that the environment variability is

307

appropriately accounted for.

308

3.2 Scenarios with natural resources constraints

309

In the following scenario of resource constrained planning, land and resource constraints are

310

imposed to suggest a localized technology selection. For example, the extensive land use of wind

311

energy conversion systems and water bodies for large hydro plants are not available in most

312

regions and agricultural conditions render significant regional differences. Accounting for these

313

realistic factors, the results indicate a bio-economy scenario in which agro-wastes are fully utilized

314

for energy recovery. Both large and farm-scale anaerobic digestion is preferable in all cases with 16 ACS Paragon Plus Environment

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benefits of energy recovery from waste. A combination of gasification and incineration (solid

316

waste), large-scale AD (WW and OFMSW co-digestion, agro-waste digestion), and farm-scale

317

AD (agro-waste) provides waste treatment strategies at the lowest cost. Figure 3 below gives an

318

overview of the most financially efficient technology mix with respect to dispatched capacities

319

that fulfil the total power demand. The minimized cost for a resource constraint scenario is higher

320

than the base case, with CAPEX requiring 34.91 billion USD over 20 years; annual OPEX was

321

found to be 516.9 million with all infrastructure in place, which is equivalent to 79.6 USD per

322

capita for the whole waste treatment and power sectors and coupled with 54.95 million metric

323

tonnes CO2 equivalence.

0.2993%

0.0013% 40.08%

45.42%

42.3731% 57.3263% 8.27% 2.08% 4.16% decentralized_activated_sludge_system

large_AD_co

large_AD_agro

decentralised_aerobic_treatment_plant

farm_AD_agro

incinerator_MSW

large_AD_co

gasification_MSW

large_AD_WW

(a) Model suggested wastewater treatment (b) Model suggested municipal solid waste and technologies (by wastewater handling agro-wastes treatment technologies (by solid capacity).

waste handling capacity).

324

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44% 3% 4% 13% 4% 1% 43%

1%

325

gas_CCGT coal_IGCC large_AD_co large_AD_WW large_AD_banana large_AD_casava large_AD_corn farm_AD_banana farm_AD_casava farm_AD_corn incinerator_MSW gasification_MSW solar_P-si-ground solarthermal_trough hydro_small wind_onshore hydro_large biofuel_cassava wind_offshore

326

(c) Optimal power supply technologies (by generation capacity).

327

Figure 3. Technology mix with minimal costs for meeting SDG goals in 2030 (scenario with

328

natural resources constraints).

329

The results suggested that the large-scale anaerobic digestion is the preferred solution among all

330

wastewater treatment routes, while gasification and large-scale anaerobic co-digestion are

331

suggested for MSW treatment. To have an in-depth understanding of the life-cycle performance

332

of the obtained technology landscape, Figure 4(a) further demonstrates the energy generation from

333

multiple waste-to-energy pathways, plus commonly exploited fossil fuel and renewable energy

334

generation plants for GAMA in 2030. It is obvious that fossil fuels still play a main role in energy

335

provision; this can be explained by the cost advantages of Coal Integrated Gasification Combined

336

Cycle (IGCC) and Gas CCGT over other power supply technologies despite their carbon-intensive

337

nature (Figure 4(a)). Additionally, as a key metric in the social LCA, labor hours required to

338

operate the waste treatment and power utility infrastructure imply the creation of 2,134 full-time

339

job per year (Figure 4(b)).

340

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Power Generation / kWh/year

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341

1.0E+10

1.0E+09

1.0E+08

1.0E+07

1.0E+06

(a) Power generation per year of selected power generation technologies.

342 AKWAPIM_SOUTH GA_SOUTH GA_EAST TEMA_METROPOLITAN VOLTA_RIVER KPONE_KATAMANSO LA_NKWANTANANG_MADINA LEDZOKUKU_KROWOR ADENTAN NSAWAM_ADOAGYIRI AWUTU_SENYA_EAST ACCRA_METROPOLITAN GA_CENTRAL ASHAIMAN GA_WEST

Thousands

LA_DADE_KOTOPON

343

0

100

200

300

400

500

344

(b) Labor needs (hours equivalent per year) in each studied region in GAMA from waste and

345

energy sectors.

346

Figure 4. Model suggested capacities and production rates per year for technologies in 2030

347

(scenario with natural resources constraints). 19 ACS Paragon Plus Environment

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348

3.3 Scenarios with policy interventions

349

The previous section illustrated how spatial constraints of natural resources can potentially affect

350

investment allocation. Additionally, decision makers also face political challenges or the need to

351

take into account other key considerations outside the model’s scope, for instance to implement

352

interventions which encourage, penalize or even ban certain technologies. The materialized

353

approach adds flexibility to the users in imposing user-based interventions and obtain an optimized

354

plan within the frame of these user-defined conditions.

355

As a commonly adopted policy intervention in the energy sector, a feed-in tariff is taken as an

356

example, which allows surplus power generation to be sold back to the grid. This provides

357

advantageous prices depending on different sources, so as to encourage higher penetration of

358

renewable sources in the overall electricity supply scheme. Local feed-in rates for wind, solar,

359

hydro and gas, recovered from wastes and biomass, were obtained from the Ghanaian domestic

360

Public Utilities Regulatory Commission (PURC). The results of a scenario with these tariffs are

361

shown in Figure 5(a) below and demonstrate how government enforced incentives can promote

362

clean energy technologies to boost the waste-to-energy utilization. With the same capital

363

investment, operational costs are significantly reduced mainly due to a selection of different

364

technologies benefiting from the feed-in-tariffs. Only 24.3 USD per capita per year of OPEX is

365

required to satisfy all waste treatment and energy demand, which is a 69.5% reduction when

366

compared with the OPEX of 79.6 USD in the previous case (no FIT set). The map gives an

367

overview of the studied region with the pie charts denoting the proportion of energy recovered

368

from local waste sources including WW, MSW and agro-waste in the total electricity supply from

369

the optimized results, for the SDG target year of 2030. The other suggested investment strategies

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370

and operation plans for each region are returned by the model from 2010 to 2030, where the SDGs

371

are expected to be gradually met.

(a)

Waste-to-Energy

district (with FIT).

penetration

by (b) Economic and environmental performance with different carbon price and enabled CCS technology.

372

Figure 5. Performance indicators of the whole waste and energy systems to satisfy total demand

373

in year 2030 (scenarios with policy interventions through FIT and carbon price).

374

3.4 Scenarios with environmental and climate change impacts

375

In this scenario, we specifically focus on the climate change impacts from a life cycle perspective.

376

When the carbon trading price increases (especially to multiples of the current level of 12.5 USD

377

per metric tonnes carbon) the overall dominant weighting of GHG emissions becomes more

378

significant in the total cost. This leads the energy sector towards a low-carbon transition. Although

379

it comprises a certain amount of economic benefits, long-term sustainability is witnessed

380

especially when coupled with novel technology selection. For example, advanced carbon capture

381

and storage (CCS) technologies can be introduced as an option to partly substitute traditional fossil

382

fuel plants for cleaner energy supply, instead of fully switching to renewable resources. The cost 21 ACS Paragon Plus Environment

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383

therefore does not obtain a significant increment (less than 18%), while the CO2 equivalent GHG

384

emissions can be reduced by more than 70.9% when compared with the scenarios without CCS

385

facilities. A total of 1,749 jobs is required to operate the infrastructure in all the studied sectors.

386

Figure 5(b) further compares each cost category under the scenarios of low, medium and high

387

carbon prices, indicating that the costs of decarbonisation are modest, with additional job creation

388

being beneficial for the whole society. From a local government’s perspective currently the costs

389

cannot be fully met domestically. This is due to the fact that the annual government budget for the

390

entire country fluctuates around 7 billion USD. The solutions could be rendered feasible if carbon

391

trading pricing is introduced at a level that provides sufficient returns for investors. This would

392

enable international capital investment to become more attractive in low carbon infrastructure

393

projects supporting waste-water-energy-land nexus.

394

4. Discussions

395

The development of waste-to-energy pathways brings substantial benefits to reduce GHG

396

emissions with improved resource allocation efficiency. Through a comprehensive LCSA, the

397

materials, energy, economic, environment and social impacts of a system can be evaluated

398

successfully. As a summary, we have presented a holistic approach to provide decision support for

399

urban waste treatment and power supply. The demand data is obtained by statistical sources and

400

agent-based simulation by formulating a system in which people, infrastructure and technologies

401

interact in a reciprocal relationship with the surrounding environment. The resource-technology-

402

network optimization model further evaluates available resources and returns the optimal

403

development/investment strategies under the given set of constraints, as explored in the respective

404

scenarios.

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405

The distinct optimal strategies emerged by varying policy (e.g., FIT) and technology options (e.g.,

406

land constraints, CCS), with substantial implications for overall technology systems and the extent

407

of waste-to-energy integration, as well as CAPEX and OPEX levels to SDG targets on water,

408

wastewaters and energy. Land constraints resulted in a reduction of gas CCGT and shift from

409

onshore wind to coal IGCC capacity and increased large-scale AD of crop residues and MSW, at

410

double the CAPEX and 17% more OPEX. By imposing a FIT to support waste utilization for

411

energy, previously marginal sources can be efficiently converted, providing a growth of share in

412

electricity generation, with a 70% reduction in OPEX. When the advanced CCS and a high carbon

413

price (125 USD/ton CO2) areintroduced, GHG emissions reductions of 70% can be achieved at a

414

manageable increase level of CAPEX (18%). The interaction between policies and technology that

415

emerges in the wastewater and energy sectors shows that distributed energy generation

416

technologies and waste-circular systems can be integrated. Water flows and wastewater treatment

417

sector have been formulated in the optimization model, contributing to the objective functions.

418

The optimization model presented in this study can be further expanded to address other water-

419

related issues such as the consumption of different categories of water and aquatic system quality

420

degradation (e.g. eutrophication, freshwater toxicity). This may lead to significant shift in the

421

optimal solutions e.g. coal-driven technologies, which may appear to be less competitive if

422

considering their water quality degradation profiles. Being able to address such cross-domain

423

interactions and focusing on the whole system or nexus level is one of the main advantages of the

424

presented approach herein.

425

As the Government of Ghana is currently elaborating on a long-term national development plan to

426

steer the country through the next 40 years, the platform shows clear evidence of benefits for

427

decision makers through our local dissemination events. Various government interventions can be 23 ACS Paragon Plus Environment

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428

studied in the model, such as carbon trading prices in collaboration with international agencies,

429

clean energy technology incentives by local governments, and most importantly satisfying demand

430

targets to achieve the sustainable development goals. Bio-renewable energy recovered from waste

431

treatment using anaerobic digestion was shown to be one of the most promising sustainable energy

432

source options in the studied region. The process serves as a reliable method to treat waste while

433

the digested sludge can be used as soil fertilizer or landfill cover. To implement such technologies,

434

it is necessary to tailor the policy measures and technology integration with local and international

435

support mechanisms. Capital expenditures for infrastructure in the GAMA context are borne

436

partially by dedicated national governmental funds for regions and via international loans. Novel

437

instruments for developing countries, such as the Green Climate Fund, can support the incremental

438

capital cost that emerged as part of a loan package, to ensure that novel infrastructure is climate

439

proof. Equally important is the demonstrated reduction in OPEX as this needs to be sustainable

440

locally from energy and water utility revenues, with the respective increase in job creation to

441

support such payments.

442

This study has set up an example for systematic resource nexus analysis for developing

443

countries/regions to leverage global development. Future work will explore a broader range of

444

waste-to-energy technologies and apply the presented methodology to other city regions. The

445

detailed investigation of various CCS and clean energy technologies and their broader

446

environmental impacts associated with costs of disposal and environmental remediation are out of

447

the current research scope and is part of our future work plans. We will also analyze additional

448

scenarios, such as different tariff and incentive settings applied to electricity derived from different

449

feedstocks across multiple regions, resilient adaptions to changes of natural environment,

450

international investment, regulations and roadmap for clean energy transitions. 24 ACS Paragon Plus Environment

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451

Acknowledgements

452

The authors are grateful to the Department for International Development (UK) for financial

453

support to the Future Proofing African Cities for Sustainable Growth project (grant number

454

203830). The Ghana Technical Group is greatly acknowledged for the useful discussions on data

455

input and case studies. We also deeply thank the Ecological Sequestration Trust (TEST) for

456

platform delivery at http://resilience.io to disseminate case study results and findings. XW thanks

457

MOE AcRF Tier 1 Grant for financial support to the project “Pathways to resilient Food-Energy-

458

Water-Waste Nexus” (P13-ChBE). MG would like to acknowledge EPSRC for financial support

459

through project ‘ReSBio’ (EP/N034740/1).

460 461

Supporting Information Available including:

462

Part A: Input parameters, Part B: Model details and Part C: Parameters and results of each

463

scenario. This information is available free of charge via the Internet at http://pubs.acs.org

464 465 466 467

Reference

468

(1)

469 470 471

Cohen, B. Urbanization in developing countries: Current trends, future projections, and key challenges for sustainability. Technol. Soc. 2006, 28 (1–2), 63–80.

(2)

Nilsson, M.; Griggs, D.; Visback, M. Map the interactions between Sustainable Development Goals. Nature 2016, 534 (15), 320–322. 25 ACS Paragon Plus Environment

Environmental Science & Technology

472

(3)

473

Page 26 of 33

United Nations General Assembly. Transforming our world: The 2030 agenda for sustainable development; 2015.

474

(4)

IEA. Key World Energy Statistics 2016; 2016.

475

(5)

International Energy Agency (IEA). World Energy Outlook 2016; Paris, 2016.

476

(6)

FAO. Food wastage: Key facts and figures; 2016.

477

(7)

Alhamwi, A.; Medjroubi, W.; Vogt, T.; Agert, C. GIS-based urban energy systems models

478

and tools: Introducing a model for the optimisation of flexibilisation technologies in urban

479

areas. Appl. Energy 2017, 191, 1–9.

480

(8)

Ramaswami, A.; Russell, A. G.; Culligan, P. J.; Sharma, K. R.; Kumar, E. Meta-principles

481

for developing smart, sustainable, and healthy cities. Science (80-. ). 2016, 352 (6288), 940–

482

943.

483

(9)

Leung Pah Hang, M. Y.; Martinez-Hernandez, E.; Leach, M.; Yang, A. Insight-Based

484

Approach for the Design of Integrated Local Food-Energy-Water Systems. Environ. Sci.

485

Technol. 2017, 51 (15), 8643–8653.

486

(10) IEA. Energy Technology Perspectives 2016; 2016.

487

(11) Othman, M. N.; Lim, J. S.; Theo, W. L.; Hashim, H.; Ho, W. S. Optimisation and targeting

488

of supply-demand of biogas system through gas system cascade analysis (GASCA)

489

framework. J. Clean. Prod. 2017, 146, 101–115.

490

(12) Delval, F.; Guo, M.; van Dam, K. H.; Stray, J.; Haigh, K.; Görgens, J.; Shah, N. Integrated

491

multi-level bioenergy supply chain modelling applied to sugarcane biorefineries in South

26 ACS Paragon Plus Environment

Page 27 of 33

492

Environmental Science & Technology

Africa. Comput. Aided Chem. Eng. 2016, 38, 2037–2042.

493

(13) Nguyen, R.; Guo, M.; Musikavong, C.; Bamroongrugsa, N.; Shah, N. Supply Chain

494

Optimisation of Nipa-based bioethanol industry in Thailand. Comput. Aided Chem. Eng.

495

2016, 38, 913–918.

496

(14) Martinez-Hernandez, E.; Leach, M.; Yang, A. Understanding water-energy-food and

497

ecosystem interactions using the nexus simulation tool NexSym. Appl. Energy 2017, 206,

498

1009–1021.

499

(15) Villarroel Walker, R.; Beck, M. B.; Hall, J. W.; Dawson, R. J.; Heidrich, O. Identifying key

500

technology and policy strategies for sustainable cities: A case study of London. Environ.

501

Dev. 2017, 21, 1–18.

502 503

(16) Endo, A.; Tsurita, I.; Burnett, K.; Orencio, P. M. A review of the current state of research on the water, energy, and food nexus. J. Hydrol. Reg. Stud. 2017, 11, 20–30.

504

(17) Bazilian, M.; Rogner, H.; Howells, M.; Hermann, S.; Arent, D.; Gielen, D.; Steduto, P.;

505

Mueller, A.; Komor, P.; Tol, R.; et al. Considering the energy, water and food nexus:

506

Towards an integrated modelling approach. Energy Policy 2011, 39 (12), 7896–7906.

507

(18) Zhang, J.; Campana, P. E.; Yao, T.; Zhang, Y.; Lundblad, A.; Melton, F.; Yan, J. The water-

508

food-energy nexus optimization approach to combat agricultural drought: a case study in

509

the United States. Appl. Energy 2017.

510

(19) Coutinho-Rodrigues, J.; Simão, A.; Antunes, C. H. A GIS-based multicriteria spatial

511

decision support system for planning urban infrastructures. Decis. Support Syst. 2011, 51

512

(3), 720–726. 27 ACS Paragon Plus Environment

Environmental Science & Technology

513 514

Page 28 of 33

(20) Chang, K.-H. A decision support system for planning and coordination of hybrid renewable energy systems. Decis. Support Syst. 2014, 64, 4–13.

515

(21) Lee, M.; Keller, A. A.; Chiang, P.-C.; Den, W.; Wang, H.; Hou, C.-H.; Wu, J.; Wang, X.;

516

Yan, J. Water-energy nexus for urban water systems: A comparative review on energy

517

intensity and environmental impacts in relation to global water risks. Appl. Energy 2017,

518

205, 589–601.

519

(22) Triantafyllidis, C. P.; Koppelaar, R. H. E. M.; Wang, X.; van Dam, K. H.; Shah, N. An

520

integrated optimisation platform for sustainable resource and infrastructure planning.

521

Environ. Model. Softw. 2018, 101, 146–168.

522

(23) Wang, X.; van Dam, K. H.; Triantafyllidis, C.; Koppelaar, R. H. E. M.; Shah, N. Water and

523

Energy Systems in Sustainable City Development: A Case of Sub-saharan Africa. Procedia

524

Eng. 2017, 198, 948–957.

525

(24) Bieber, N.; Ker, J. H.; Wang, X.; Triantafyllidis, C.; van Dam, K. H.; Koppelaar, R. H. E.

526

M.; Shah, N. Sustainable planning of the energy-water-food nexus using decision making

527

tools. Energy Policy 2018, 113, 584–607.

528 529 530 531

(25) Gong, J.; Darling Bc, S. B.; You, F. Perovskite photovoltaics: life-cycle assessment of energy and environmental impacts. Energy Environ. Sci. 2015, 8 (8), 1953–1968. (26) Couture, T.; Gagnon, Y. An analysis of feed-in tariff remuneration models: Implications for renewable energy investment. Energy Policy 2010, 38 (2), 955–965.

532

(27) Mohammed, Y. S.; Mokhtar, A. S.; Bashir, N.; Saidur, R. An overview of agricultural

533

biomass for decentralized rural energy in Ghana. Renewable and Sustainable Energy 28 ACS Paragon Plus Environment

Page 29 of 33

534 535 536

Environmental Science & Technology

Reviews. 2013, pp 15–22. (28) Case Studies - resilience.io - network of integrated tools and collaboration for financing and decision making http://resilience.io/stories/ (accessed May 12, 2017).

537

(29) Ghana. Statistical Service. 2000 Population and Housing Census: Greater Accra Region

538

Analysis of District Data and Implications for Planning; Ghana Statistical Service,: Accra,

539

2005.

540

(30) Nii Ardey Codjoe Tawiah John K Anarfi Clara Korkor Fayorsey, S. E.; Tawiah, E.; Ami

541

Amedoe Chapter Nine, J.; Gaisie, S. K.; Gyamfi Chapter Ten, S.; Anarfi, J. K.; Kpakpah

542

Chapter Eleven, M.; Botchie, G.; Owusu Kagya, J.; Ankomah, A.; et al. 2010 Population &

543

Housing Census: Regional Analytical Report Greater Accra Region. 2013.

544

(31) Sanscartier, D.; MacLean, H. L.; Saville, B. Electricity production from anaerobic digestion

545

of household organic waste in Ontario: Techno-economic and GHG emission analyses.

546

Environ. Sci. Technol. 2012, 46 (2), 1233–1242.

547 548 549 550 551 552 553 554

(32) Amigun, B.; Parawira, W.; Musango, J. K. Anaerobic biogas generation for rural area energy provision in Africa. Biogas 2012, 35–62. (33) Arthur, R.; Baidoo, M.; Antwi, E. Biogas as a potential renewable energy source: A Ghanaian case study. Renew. Energy 2011, 36 (5), 1510–1516. (34) GIZ. Biogas in Ghana: Sub-Sector Analysis of Potential and Framework Conditions. 2014, pp 1–30. (35) Lamptey, F. Determination of domestic water consumption pattern in Accra, Kwame Nkrumah University of Science and Technology, 2010. 29 ACS Paragon Plus Environment

Environmental Science & Technology

Page 30 of 33

555

(36) Van Rooijen, D. J. Implications of Urban Development for Water Demand , Wastewater

556

Generation and Reuse in Water-Stressed Cities: Case studies from South Asia and sub-

557

Saharan Africa, Lougborough University, 2011.

558

(37) TTZ Bremerhaven. Biotechnology for Africa’s Sustainable water supply: Evaluation of the

559

existing water biotechnologies and water management strategies in the targeted countries;

560

Bremerhaven, 2012.

561 562 563 564 565 566

(38) Vanderpuije, A. O. Sustainable Environmental Management and Improved Sanitation, a Shared Responsibility; 2016. (39) Bentsi-Enchill, N.; Cudjoe, S. N.; Sepah, E.; Anarfi, J. K.; Gaisie, S. K. 2010 Population & Housing Census: Regional Analytical Report Greater Accra Region; 2013. (40) Koppelaar, R. H. E. M. Greater Accra Population Socio Economics and Water Access. openAfrica. 2016.

567

(41) Guinée, J. B. Handbook of Life Cycle Assessment; Springer, 2002.

568

(42) Peters, M.; Timmerhaus, K.; West, R.; Timmerhaus, K. Plant design and economics for

569

chemical engineers; McGraw-Hill Education, 2003.

570

(43) Duku, M. H.; Gu, S.; Hagan, E. Ben. A comprehensive review of biomass resources and

571

biofuels potential in Ghana. Renewable and Sustainable Energy Reviews. 2011, pp 404–

572

415.

573 574

(44) Cauthen, J.; Jones, D.; Gugerty, M. K.; Anderson, C. L. Banana and Plantain Value Chain: West Africa EPAR Brief No. 239. 2013, No. 239, 1–25.

30 ACS Paragon Plus Environment

Page 31 of 33

575 576

Environmental Science & Technology

(45) Armah, M. Investment opportunity in Ghana: Maize, Soya and Rice Production and Processing. Millenn. Dev. Authority. Accra, Ghana 2010, 23.

577

(46) Ghana Statistical Service. Population and housing census summary report; 2012.

578

(47) Miezah, K.; Obiri-Danso, K.; Kádár, Z.; Fei-Baffoe, B.; Mensah, M. Y. Municipal solid

579

waste characterization and quantification as a measure towards effective waste management

580

in Ghana. Waste Manag. 2015, 46, 15–27.

581 582 583 584

(48) Anaglate, S. A.; Rahmaputro, S.; Ruiz, C.; Rojas-Solórzano, L. R. Comparison between Landfill Gas and Waste Incineration for Power Generation in Accra, Ghana. (49) Owusu Boadi, K.; Kuitunen, M. Municipal Solid Waste Management in the Accra Metropolitan Area, Ghana. Environmentalist 2003, 23, 211–218.

585

(50) Municipal solid waste incineration plant for Accra Brewery Limited (Ghana). 2016.

586

(51) Guo, M.; Stuckey, D. C.; Murphy, R. J. Is it possible to develop biopolymer production

587

systems independent of fossil fuels? Case study in energy profiling of polyhydroxybutyrate-

588

valerate (PHBV). Green Chem. 2013, 15 (3), 706.

589

(52) Kemausuor, F.; Obeng, G. Y.; Brew-Hammond, A.; Duker, A. A review of trends, policies

590

and plans for increasing energy access in Ghana. Renewable and Sustainable Energy

591

Reviews. 2011, pp 5143–5154.

592

(53) Energy Commission of Ghana. National Energy Statistics 2000-2013. 2014, No. April, 31.

593

(54) Guo, M.; Trzcinski, A. P.; Stuckey, D. C.; Murphy, R. J. Anaerobic digestion of starch–

594

polyvinyl alcohol biopolymer packaging: Biodegradability and environmental impact

31 ACS Paragon Plus Environment

Environmental Science & Technology

595

Page 32 of 33

assessment. Bioresour. Technol. 2011, 102 (24), 11137–11146.

596

(55) Guo, M.; Stuckey, D. C.; Murphy, R. J.; Galbe, M.; Zacchi, G.; Crocker, D.; Mitchell, B.;

597

Mohammad, J.; Cantrell, K.; Pittman, C. U. Is it possible to develop biopolymer production

598

systems independent of fossil fuels? Case study in energy profiling of polyhydroxybutyrate-

599

valerate (PHBV). Green Chem. 2013, 15 (3), 706.

600 601 602 603

(56) Monson, K. D., S. R. Esteves, A. J. Guwy, R. M. D. Anaerobic Digestion of Biodegradable Municipal Solid Wastes A Review. Univerisity of Glamorgan. (57) Awuah, E.; Abrokwa, K. A. Performance evaluation of the UASB sewage treatment plant at James Town (Mudor), Accra. 2008.

604

(58) Guo, M. Life Cycle Assessment (LCA) of Light-Weight Eco-composites Materials, 2012.

605

(59) Pang, Y. Z.; Liu, Y. P.; Li, X. J.; Wang, K. S.; Yuan, H. R. Improving Biodegradability and

606

Biogas Production of Corn Stover through Sodium Hydroxide Solid State Pretreatment.

607

Energy & Fuels 2008, 22 (4), 2761–2766.

608

(60) Chanakya, H. N.; Malayil, S. Techno-economic Potential for Value Added Products from

609

Digestion of Urban Solid Wastes and Rural Residues. Dyn. Biochem. Process Biotechnol.

610

Mol. Biol. 2013, 6 (special Issue 2), 38–42.

611

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