A Synthetic Analog of the Biomineralization Process: Controlled

Brinda B. Lakshmi, Peter K. Dorhout, and Charles R. Martin. Chemistry ... Simon Champ , John A. Dickinson , Philip S. Fallon , Brigid R. Heywood , Mar...
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J. Am. Chem. SOC.1994,116, 41384745

4138

A Synthetic Analogue of the Biomineralization Process: Controlled Crystallization of an Inorganic Phase by a Polymer Matrix Jun Lin, Elizabeth Cates, and Patricia A. Bianconi' Contribution from the Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802 Received September 7, 1993'

Abstract: A biomimetic in situ synthesis of CdS in PEO has been devised, which produces composites in which the inorganic phase displays uniformity of size, morphology, phase, and crystallographic orientation. Such regularity is displayed in thin composite films (