Acetone Cyanohydrin - C&EN Global Enterprise (ACS Publications)

Nov 5, 2010 - Advertisements that appeared within the print issues of Chem. Eng. News have been included in the C&EN Archives to provide a ...
0 downloads 0 Views 85KB Size
Aero*

Acetone Cvanohydrin TDisantvma/

ΟΉΟ//Ι&Ί

CH 3

OH X / C /

CH 3

\

CN

titttt/e

Acetone cyanohydrin has long been utilized as an intermediate in the manufacture of methacrylate resins. Poten­ tially valuable as an organic intermediate in many fields—surface active agents, pharmaceuticals, plasticizers, insecticides—it is now available for application research in your own laboratories. Representative of the many interesting reactions of this nitrile are:

-H 2 0

->- CH2 = C(CH 3 )-CN

ACETYLATION (CH3)2C(OH)CN

+CH.,=CO >- (CH,)?C(CN)-OCOCH3

OTHER CYANAMID NITRILES

BENZOYLATION (CH3)2C(OH)CN

Colorless Liquid — 19°C. 82°/23 m.m. 0.932/19° Solubility Water v. sol. Alcohol v. sol. Ether v. sol. Pet. ether si. sol.

m.p. b.p. sp. gr.

DEHYDRATION (CH3)>C(OH)CN

ACETONE CYANOHYDRIN

C6H6CO CI >- (CH3)2C(CN)OCOC6H6

REACTION WITH

AMINES (CoH5)oNH (CH3)2C(OH)CN - = >- (CH3)2C(CN)N(C2H5)2

References to these reactions and a number of others are contained in our technical data sheet. We suggest y o u complete the coupon below to obtain a sample and data sheet. Inquiries for commercial quantities and prices will receive our prompt attention. * Trade-mark

SAMPLE

Unsaturated nitrile Acrylonitrile CH 2 =CH CN ct—Hydroxy nitriles Glycolonitrile HO-CH2-CN Lactonitrile CH3-CHOH-CN P—Hydroxy nitrile Ethylene cyanohydrin HO-CH2-CH2-CN /3—Alkoxy propio nitrile 0— Isopropoxypropionitrile (CH,), CH-0-CH2-CH2-CN P—Halopropionitrile P—Chloropropionitrile Cl-CH2-CHo-CN Dinitrile Succinonitrile NC-CH2-CH2-CN

AND T E C H N I C A L

DATA

American Cyanamid Company Section SO*, Synthetic Organic Chemicals Dept. 30 Rockefeller Plaza, New York 20, N . Y. Gentlemen: • Send me sample of AERO Acetone Cyanohydrin • Send technical data sheet Name_ Position. Company^ Address

V O L U M E

2 6,

NO.

30

»

»

JULY

2 6,

1948

2187