ACS Publications - American Chemical Society

McElvain. Melvin S. Newman. Kenneth S. Pitzer. Clifford .Purves. Frederick D. Rossini. George Scatchard. Glenn T. Seaborg. Esmond . Snell. William . V...
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (Registered in U. S. Patent Office)

W. A L B E R T N O Y E S , J R . , EDITOR ALLEN D.

ASSISTANT EDITORS

BLISS

MARSHALL GATES

ARTHUR B. LAMB, CONSULTING EDITOR EDITORIAL BOARD J O H N C. BAILAR, J R .

P . J. F L O R Y

F R A N K R.

PAUL D.

I. M.

S. M .

BARTLETT

KOLTHOFF

G L E N N T . SEABORG

WALTER M.

P A U L C. C R O S S

J O H N A. L E E R M A K E R S

K E N N E T H S. P I T Z E R

WILLIAM Ε.

A R T H U R W.

J. J. LINGANE

CLIFFORD B. P U R V E S

W. H .

C. S. M A R V E L

FREDERICK D.

L. ZECHMEISTER

J O H N T.

EDSALL

M E L V I N S. N E W M A N

G E O R G E SCATCHARD

R. K E I T H CANNAN DAVIDSON

LAUER

MAYO

MCELVAIN

Published semi-monthly by the American Chemical So­ ciety at 20th and Northampton Sts., Easton, Pa. Entered at the Post Office at Easton, Pa., U. S. Α., as sec­ ond-class matter. Acceptance for mailing at special rate of postage provided for in Section 1103, Act of October 3, 1917, authorized July 13. 1918. Manuscripts for publication and books for review in THIS JOURNAL should be sent to the Editor, W. Albert Noyes, Jr., Department of Chemistry, University of Rochester, Rochester 3, Ν. Υ. Correspondence regarding accepted copy, proofs and re­ prints should be directed to Assistant Editor, Allen D. Bliss, Department of Chemistry, Simmons College, 300 The Fenway, Boston 15, Mass. Business Office: American Chemical Society, 1165—16th St., N.W., Washington 6, D. C. Advertising Office: American Chemical Society, 332 West 42nd St., New York 18, Ν. Υ. The American Chemical Society and the Editors of the Journal of the American Chemical Society assume no responsi­ bility for the statements and opinions advanced by con­ tributors to T H I S JOURNAL.

Remittances and orders for subscriptions and for single

ROSSINI

ESMOND Ε. S N E L L VAUGHAN

WOODSTOCK

copies, notices of changes of address and new professional connections, and claims for missing numbers should be sent to the American Chemical Society, 1155—16th Street, N.W., Washington 6, D.C. Change of address for the Journal of the American Chemical Society must be received on or before the 18th of the preceding month. Claims for missing numbers will not be allowed (1) if received more than sixty days from date of issue (because of delivery hazards, no claims can be honored from sub­ scribers in Central Europe, Asia, or Pacific Islands other than Hawaii), (2) if loss was due to failure of notice of change of address to be received before the date specified in the preceding paragraph, or (3) if the reason for the claim is "missing from files." Annual subscription—$12.00 to non-members, $6.00 to members. Postage to countries not in the Pan American Union, $3.00; Canadian, $0.60. Single copies—current issues, $1.00, back numbers, $1.25; special rates to mem­ bers. The American Chemical Society also publishes Chemical Abstracts, Industrial and Engineering Chemistry, Chemical and Engineering News, Analytical Chemistry and Journal of Physical Chemistry. Rates on request.

(Continued from first page of cover) droxynor-5-cholenic Acid Lactone, a By-product of the Oxidation of Sitosterol H. Harry Szmant and Clare McGinnia : The Absorption Spec­ tra of Some Diaryl Ketones, Hydrazones and Azines D. S. Tarbell and M. A. McCall: The Basic Isomerization of Allyl Aryl Sulfides to Propenyl Aryl Sulfides

41 240 48

D. Stanley Tarbell and John C. Petropoulos: The Action of Aluminum Bromide on Benzyl Phenyl Ether Gino R. Treves and Frank C. Testa: Basic Esters and Quater­ nary Derivatives of ^-Hydroxy Acids as Antispasmodics... Marvin W e i s s : Acetic Acid—Ammonium Acetate Reactions: An Improved Chichibabin Pyridine Synthesis

244 46 200

BIOLOGICAL CHEMISTRY R. R. Becker and Mark A. Stahmann: The Synthesis of High Molecular Weight Lysine Polypeptides Morris Friedkin: Enzymatic Synthesis of Desoxyxanthostne by the Action of Xanthosine Fhosphorylase in Mammalian

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Tissue Irving M. Klotz, Κ. Κ. Burkhard and Jean M. Urquhart : Struc­ tural Specificities in the Interactions of Some Organic Ions with Serum Albumin

112 202