Actinobolin. I. Structure of actinobolamine - Journal of the American

Morton E. Munk , Denny B. Nelson , Frederick J. Antosz , Delbert L. Herald Jr. , Theodore H. Haskell. Journal of the American Chemical Society 1968 90...
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Actinobolin. I. Structure of Actinobolamine’ Morton E. Munk, Charles S. Sodano, Robert L. McLean, and Theodore H. Haskellz Contribution f r o m the Department of Chemistry, Arizona State University, Tempe, Arizona 85281. Received March 14, 1967

Abstract: The structure elucidation of actinobolamine, the basic fragment derived from the acid hydrolysis of the intact antibiotic, is described. The N-acetate of the free base was shown to possess a tertiary amide unit, -HC(CHOHCHs)N(Ac)CH