T H E J O U R N A L OF I N D U S T R I A L A N D E N G I N E E R I N G C H E M I S T R Y .
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RECENT INVENTIONS.
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Nov.,
1911
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Reported by C. L. Parker, Solicitor of Chemiral Patents, hIcGill Building, Washington, D. C.
Manufacture of Cement from Furnace-Slag. U. S. Patent No. 998,358. This is a process for the manufacture of cement from liquid furnace slag or the like. Referring to the accompanying illustrations the drum has behind it another drum $, and a third drum a* is arranged above the drums and %', The glowing liquid slag is conducted and the admixture to the drum 2 by a trough or channel is led through a trough or channel 2 terminating near the circumference of the said drum. This drum pulverizes the material in the well known manner, and throws part of it against
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tact with this liquid in such a manner t h a t the gas does not escape and is absorbed and returned again t o the electrolyte. The liquid or material used should be one which will absorb chlorin gas and readily give it up. Tetrachlorid of carbon is a liquid which can be used and is especially suited for this purpose. The inventor is Mathias Pier, of Schlachtensee, Germany, assignor t o E. I. du Pont de Nemours Powder Company. Apparatus for Electrochemical Treatment of Ores. U. S. Patent No. 991,695. This invention consists in apparatus for treating gold and other ores for the extraction of their metallic contents by means of a n electric current operating in conjunction with a chemical solvent such as cyanid. Provision is usually made for circulating the treatment liquid upwardly through the ore and through precipitation boxes. For this purpose, there is provided, a storage tank 7 from which liquid is delivered t o a pipe 8, the mouth g of which is raised above the tank. The pipe 8 connects with a chamber, IO, in the bottom of the tank, from which a number of perforated distribution pipes, 11, radiate under the filter 3. Near the top of the vat x x a draw-off pipe, 1 2 , conducts the liquid to the
the drum E' and part of i t against the upper drum az. The rotate in the direction indicated in the drawing drums 2' and by the arrows, so that the material on which they act is thrown from one t o the other, and is in this manner very intimately mixed. The repeated impact of the material against the rapidly rotating drums causes it to be reduced to a fine state of pulverization, and owing t o the fact that the ingredients are brought into more intimate contact with each other complete agglomeration results. The inventor is Wilhelm Lessing, of Troisdorf, Germany. Method of Producing Halogen-Oxygen Compounds by Electrolysis. U. S. Patent No. 998,982. This is a n improvement in the method of producing halogen oxygen compounds by electrolysis, which consists in allowing evolved chlorin gases to escape from the cell, absorbing the same in a liquid, which is not miscible with the electrolyte, and which absorbs and readily gives up the chlorin gas and returning the gas t o the electrolyte. The electrolyte is maintained a t a constant level by adding to the neutral electrolyte a liquid which is not miscible with i I
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the electrolyte but which readily dissolves chlorin. This liquid should be previously saturated with chlorin. The gases developed, particularly chlorin, are brought into intimate con-
precipitation boxes 13 after passing which flows to a sump, 1 4 , and is pumped back to tank 7 . The current is passed through the ore in the same direction as the liquid; or in other words the anode is placed at the bottom of the vat and the cathodes at the top. The anode 15 is shown positioned in chamber IO. Beneath the filter 3 and supporting the same is a heavy metallic netting, 16, which forms a sort of supplementary anode for distributing the current over the ore.
Nov.,
1911
T H E JOVRh'AL O F I S D U S T R I A L AiVD E N G I N E E R I N G C H E M I S T R Y .
The cathode, marked 17 and several in number, are arranged a t the top of the vat to dip into surfaces of the liquid. They are carried upon the extremities of arms 18 having a planetary motion with respect to the axis of the vat. Such motion causes the cathodes in course of time to traverse the entire surface of the liquid and thus cause the current t o penetrate every part of the body of ore and act upon every particle of metal therein. The return circuit from the cathodes t o the source of current 2 5 is made by means of springs or brushes, 2 6 , suspended below the arms of the spider r g and resting uponrings, 2 7 , upon the spindles 22. These springs or brushes connect with a rod, 28, passing up the center of shaft 20 and making rubbing contact a t 29 with the return conductor 30. The whole of the cathode mechanism is carried in a frame, 31, which is supported by an insulating medium, 3 2 , upon the vat I. I n order to assist precipitation upon the zinc in the boxes 13, a cathode, 33, may be suspended in the discharge end of each box. A portion of the current thus passes through the liquid flowing off by pipe 1 2 and through the boxes 13,returning t o the dynamo through a conductor, 34, in which a resistance, 35, may be inserted t o regulate the amount of the diverted current. The inventor is Tullio Bubola, of Luipaardsvlei, Transvaal. Process of Obtaining Nitrogen. U. S. Patent No. 999,003. This invention relates to the production of nitrogen from atmospheric air and specifically to processes for removing oxygen from air in such manner as t o leave the residual nitrogen in condition for use in the manufacture of nitrogen compounds, particularly cyanids, which require nitrogen. The method consists in bringing air-previously deprived of all moisture and carbon dioxid-into contact with molten sodium or potassium cyanid, or a mixture thereof, a t a temperature of 500' C. or over, whereupo? the oxygen of the air will react with a portion of the cyanid, e . g., sodium cyanid to form sodium cyanate which, being perfectly miscible with the cyanid, will diffuse throughout the molten mass, while the nitrogen content of the air will remain unaffected and may be collected in the pure state. The cyanate is also of substantially the same density as the cyanid. The sodium cyanate contained in the molten cyanid may be continuously or intermittently reduced to sodium cyanid a s it accumulates above a certain percentage in the mass, by means of certainmetals, and also by carbon. The metal, e . g., iron, combines with the oxygen of the cyanate to form iron oxid which contaminates the cyanid, but will settle to the bottom of the molten mass if undisturbed. The iron does not begin to reduce the cyanate until the latter constitutes about I O per cent. or more of the molten mixture and it will continuously reduce any cyanate which may be formed in the mixture in excess of this approximate percentage. Zinc will also continuously reduce the cyanate which may tend to accumulate above a certain percentage (not determined) in the molten cyanid. The zinc oxid may be separated by settling and collected for use a s such. Carbon easily reduces the cyanate and forms a gaseous oxid
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which removes itself entirely and continuously from the molten cyanid and does not contaminate it. Coal may be used as the source of carbon, the impurities so introduced, to wit, the ash in the coal, not being particularly objectionable. If, therefore, air be injected into or passed over the surface of a body of molten sodium cyanid contained
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in a suitable metal retort, which also contains lumps of anthracite coal submerged in the cyanid, the oxygen of such air will combine with some of the molten cyanid t o form sodium cyanate, which will diffuse in the cyanid, and come into contact with the coal, which will promptly reconvert it into sodium cyanid with evolution of carbon monoxid gas: NaCNOC = NaCNCO If the reduction be effected in an ordinary pot or retort, the carbon monoxid will rise through the melt and mix with the residual nitrogen of the air so that the product will be worthless. One object of the process is to continuously or intermittently remove the oxygen from the air by means of molten cyanid, and t o continuously or intermittently reduce the resultant cyanate by means of coal in such manner that the carbon monoxid does not come into contact nor mix with the nitrogen which may, therefore, be obtained pure. Forms of apparatus which may be used for this purpose are shown in the accompanying 2lustrations. The Inventor is Charles E. Acker, of Ossining, New York, Assignor to the Nitrogen Company, of New York.
