Aromatic Substitution. X.1 The AlCl3·CH3NO2-Catalyzed Benzylation

A Study of Essentially Free Carbocations Derived via Diazonium and Oxo Diazonium Ions in the Liquid Phase. Ron W. Darbeau, Emil H. White, Fenhong Song...
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GEORGEA. OLAH,STEPHEN J. KUHNAND SYLVIA H. FLOOD

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VOl. 84

TABLE I1 EXTRACTION AND GAS CHROMATOGRAPHY DATA % H?SOa at pK.

Ether

KD’~

Slope uf log plotu

Concn. of stock s o h . , Columnb Column vol. Yo packing temp., O C .

Flow ratc, ml./min.

Hcx;2trietliylcne oxide -2.02 33 ti8 0.88 1.