Azide Salts of trans-Diazidotetraamminecobalt(II1) Ion

OBSERVED ASD CALCULATED STRUCTURE FACTORS. FOR [ s( CHS)~] zB&e. 5. K&! -. Fc. 2 I? L. KIEI. 0. 0. 2. 92. -95. 1. 5. 9. 10. 9. 0. 0. 4. 32. 30. 1. 7. ...
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Inorganic Chcnz istry

918 NOTES TABLE I1 OBSERVED A S D CALCULATED STRUCTURE FOR

FACTORS

[ s(C H S ) zB&e ~]

K&!

Fc

2

I?

L

0

0

2

92

-95

1

5

9

10

0

0

4

32

30

1

7

7

5

3

0

0

6

48

48

2

2

2

53

-54

5

KIEI 9

0

0

8

15

2

2

4

8

0

0

10

12

:2

2

2

6

io

9 -8

0

2

2

136

140

2

2

8

10

12

0

2

4

6

2 1 0

0

0

0

2

6

4

-3

2 2

4

4

47

-47

0

8

11

11

2

4

6

11

9

0

2 2

10

21

22

2

4

8

17

-17

0

4

4

12

11

2

4

IO

13

12

0

4

6

27

-26

2

6

6

33

-35

:5

0

4

8

20

21

2

6

8

16

15

0

4

10

5

-4

3

3

51

51

0

6

6

28

29

3

3 3

5

60

-58

0

6

8

20

3

3

7

8

-9

0

8

8

23

-20 22

3

3

9

12

12 -3

1

1

1

15

73

3

5

5

4

1

1

3

58

58

3

5

7

8

-8

1

1

5

0

1

3

5

9

10

-11

1

1

7

14

15

3

7

7

8

-11

1

1

9

IB

19

4

4

4

:

11

7

10

4

4

6

-38

1

1 3

8 38

3

48

-46

4

4

8

0

1

1

3

5

:6

15

4

6

6

5

-5

1

3

7

0

-2

4

6

8

11

-10

1

3

9

0

4

5

5

5

29

-28 -16

6

1

5

5

20

-19

5

5

7

17

1

5

7

6

-5

5

7

7

7

-4

8

6

6

11

-11

B-B B-H C-N C- H

TABLE I11 BONDDISTANCES IN [S(CH3)a]zB6Hs 169i00lA 1 11 A 0 0 7 A 148+0 0lA 0 99 f 0 04