Carbenoids. Metal-assisted ionization - Journal of the American

Nov 1, 1986 - J. Am. Chem. Soc. , 1986, 108 (23), pp 7435–7436. DOI: 10.1021/ja00283a064. Publication Date: November 1986. ACS Legacy Archive...
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J. Am. Chem. SOC. 1986, 108, 7435-7436

7435

Scheme I

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6 Figure 1.

plot of N-(S)-(-)-(4-methylcyclohexylidene)fluoroacetyl-L-(-)-ephedrine. ORTEP

Scheme I

4

ca. 10-20% of linalol is ~ b t a i n e d . ~ . ~ . ~ Compressed geraniol films are similarly unreactive, again giving