Catalyzed Alkane Fluorination

PdII-Catalyzed Aromatic Fluorination - Accounts

Sep 22, 2016 - This modification process was avoided altogether by synthesizing a âpremodifiedâ ligand, HGPhos (L5), which was converted to the corresponding COD-based Pd(0) precatalyst P3 (Figure 14a). However, high yields of aryl fluoride were


Sep 22, 2016 - DOI: 10.1021/acs.accounts.6b00247. Publication Date ... This prompted the synthesis of a variety of âpremodifiedâ ligands and the identification of one that led to an expanded substrate scope, including (hetero)aryl triflates and b

PdII-Catalyzed Aromatic Fluorination - American

Sep 22, 2016 - In this Account, we describe the discovery and development of a Pd-catalyzed CâF cross-coupling process and the systematic developments that made this once .... bromo-3-methylbenzonitrile to afford 4 in 74% yield (Figure. 3b). .....


Sep 22, 2016 - Biography. Aaron C. Sather was born in Seattle, Washington. He received his B.Sc. from the University of Oregon, where he worked on arsenic remediation and anion recognition with Prof. Darren W. Johnson. He then moved to The Scripps Re


Sep 22, 2016 - ACS AuthorChoice - This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of ...

Palladium-Catalyzed Fluorination of CarbonâHydrogen Bonds

May 10, 2006 - Experimental details and spectroscopic and analytical data for new compounds. This material is available free of charge via the Internet at http://pubs.acs.org.

Palladium-Catalyzed Regio- and Enantioselective Fluorination of

Sep 6, 2011 - This report describes the Pd(0)-catalyzed fluorination of linear allylic chlorides and bromides, yielding branched allylic fluorides in high selectivity. Many of the significant synthetic limitations previously associated with the prepa

Palladium-Catalyzed Fluorination of Carbon ... - ACS Publications

The Journal of Organic Chemistry 2017 82 (2), 1260-1265 ..... Phillip J. Milner , Tom Kinzel , Yong Zhang , and Stephen L. Buchwald ..... Synthetic and Mechanistic Studies on Pd(0)-Catalyzed Diamination of ..... Organic Letters 2009 11 (14), 3120-312

Silver-Catalyzed Vinylogous Fluorination of Vinyl Diazoacetates

Nov 14, 2013 - Shinobu Takizawa , Fernando Arteaga Arteaga , Kenta Kishi , Shuichi Hirata , and Hiroaki Sasai. Organic Letters 2014 16 (16), 4162-4165.

Mechanistic Investigations of Palladium-Catalyzed Allylic Fluorination

Jan 21, 2014 - ... Jean-Denys Hamel , Mathilde Vandamme , and Jean-FranÃ§ois Paquin ... Anna Lena Raza , Moritz F. Kuehnel , Maria Talavera , Michael ...

Catalyzed Alkane Fluorination

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