Charge Neutralization Process of Mobile Species at Any Distance from

Chem. 2006, 78, 6733-6739). The original eq 19 is wrong. The following is the correct version: AC800195A. 10.1021. Published on Web 03/20/2008. ∂Cl(x,...
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Anal. Chem. 2008, 80, 3058

Correction Charge Neutralization Process of Mobile Species at Any Distance from the Electrode/solution Interface. 1. Theory and Simulation of Concentration and Concentration Gradients Developed during Potentiostatic Conditions Fernando Garay* and Cesar A. Barbero (Anal. Chem. 2006, 78, 6733-6739)

The original eq 19 is wrong. The following is the correct version:

{

∂Cl(x,t)/∂t )

- Dj

m

∂2Cj(x,t)



zlCl(x,t)

(

m

∑[D z

j j

∂x

2

Cj(x,t)]

j

m

∂Φ(x,t) ∂Cl(x,t) zl

∂I(t) 1

j

-

∂x2

[Djzj∂2Cj(x,t)/∂x2] -

∑[D z

Cl(x,t) -

∂x

2

j

m

2

j j

j

)}

+

∂Cj(x,t)/∂x]

j j

∑[D z

∂x FA

Cj(x,t)]

(19)

AC800195A 10.1021 Published on Web 03/20/2008

3058 Analytical Chemistry, Vol. 80, No. 8, April 15, 2008

10.1021/ac800195a CCC: $40.75

© 2008 American Chemical Society Published on Web 03/20/2008