Cherylline, a 4-phenyl-1,2,3,4 ... - ACS Publications

(9, 100 g) was fed within 5 min, under cooling at 0-10°, into. 62.5% H2S04 (100 ml); ... alkaloid has been assigned the structure 12 from spectral, d...
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1100

Bbossi, Gbethe,

Teitel, Wildman, and Bailey

J. Org. Chem. 1970.35:1100-1104. Downloaded from pubs.acs.org by KAROLINSKA INST on 01/23/19. For personal use only.

terial (vpc, SE-30, 200°). Upon distillation, a main cut, 94 g, bp 77° (15 mm), n20d 1.4545, of a 91:9 isomeric mixture of 6 and 6a (vpc, 20M, 90°) was obtained. Cyclization of 9.—