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Organometallics 2005, 24, 5188
Additions and Corrections 2005, Volume 24 Pascal Maire, Frank Breher, Hartmut Scho1 nberg, and Hansjo1 rg Gru 1 tzmacher*: Chiral Rhodium(I) and Iridium(I) Amino-Olefin Complexes: pKa, N-H Bond Dissociation Energy, and Catalytic Transfer Hydrogenation. Pages 3207-3218. Due to an erroneous conversion of energy units, the equation used to estimate the NH bond dissoziation energy (BDE) is wrong. The correct formula is BDE ) 5.74pKa + 96.5E°Fc+/Fc + C (C ) 306.9 kJ mol-1 for dmso). Therewith, the NH BDE in (R,R)-6 is 363(5) kJ mol-1, which is about the same as previously observed for other Rh(I) amine complexes H and J. OM050585B 10.1021/om050585b Published on Web 09/03/2005
