J. Agric. Food Chem. 1997, 45, 242−248
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Comparative Detection of Fluorinated Xenobiotics and Their Metabolites through 19F NMR or 14C Label in Plant Cells A. M. Serre,† C. Roby,‡ A. Roscher,‡ F. Nurit,† M. Euvrard,§ and M. Tissut*,† Laboratoire de Physiologie Cellulaire Ve´ge´tale, Universite´ Joseph Fourier, B.P. 53, F-38041 Grenoble Cedex 09, France, Laboratoire DBMS/RMBM, CEA, 17 Avenue des Martyrs, F-38054 Grenoble Cedex 9, France, and Rhoˆne-Poulenc Agro, La Dargoire, B.P. 9163, F-69623 Lyon Cedex 9, France
The metabolism of a new fluorinated fungicide [N-ethyl-N-methyl-4-(trifluoromethyl)-2-(3,4dimethoxyphenyl)benzamide] by Acer pseudoplatanus cells was studied concurrently through the use of 19F NMR and with 14C-labeled compound. Approximately 10 fluorinated compounds were observed by 19F NMR in the culture; 5 of them were identified. The detection limit was
