Herbert C. Brown, and William J. Wallace. J. Am. Chem. Soc. , 1953, 75 (24), pp 6268â6274. DOI: 10.1021/ja01120a049. Publication Date: December 1953...
Cook likewise concluded that complex formation in- volved a hydrogen bond between the proton of hy- drogen chloride and the -electrons of the aromatic ring.
Complexes of Hydrogen Chloride and Hydrogen Bromide with Aromatic Hydrocarbons in n-Heptane Solution1,2. Herbert C. Brown, and John J. Melchiore.
Faculty of Science, Masaryk University, Kotlárská 2, 611 37 Brno, Czech Republic, and Department of. Organic Chemistry, Institute of Chemical Technology, ...
Aug 6, 2000 - stability of 22 [amide][anion] complexes based on their electronic and .... anion with association constants from 0 to about 3000 M-1. However ...
Isomerization of the diethylbenzenes using zeolite catalysts. Anthony P. Bolton , Mohammed A. Lanewala , Paul E. Pickert. The Journal of Organic Chemistry ...
Sang Up Choiand John E. Willard. Contribution from the Department of Chemistry, University of Wisconsin,. Madison, Wisconsin. Received April 5,1965.
The solubilities of HBr and CH3Br in 1,2,4-trichloroben- zene and in nitrobenzene have been determined with and without gallium bromide in solution. They all ...
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crease with increasing number of methyl g r o ~ p s . ' ~apparatus and collected in convenient samples (ca. 0.3 g.) in small ampoules which were drawn down into thin, fragile The increase in intensity of the color of the solu- tips. These ampules were sealed under vacuum and the tions of aluminum bromide in these hydrocarbons aluminum bromide was observed to be analytically pure and (Table I) also supports the conclusion that these to remain in satisfactory condition for the experiments over solutions must contain an increasing concentration long periods of time. Introduction of Aluminum Bromide.-The aluminum of ArH.AlzBrficomplexes as we proceed from ben- bromide was introduced in the following manner. The tip zene to toluene to m-xylene and to mesitylene. of the weighed ampule was carefully scratched and the amWe suggest that these complexes are probably T- pule placed in the side arm of an apparatus containing a glass-enclosed hammer. The side arm was closed and the complexes16with the structure
