Correction - Contact Sulfuric Acid from Sulfur - Industrial

Ind. Eng. Chem. , 1948, 40 (10), pp 1994–1994. DOI: 10.1021/ie50466a601. Publication Date: October 1948. ACS Legacy Archive. Note: In lieu of an abs...
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INDUSTRIAL A N D ENGINEERING CHEMISTRY

1994

According to the authors cited the heat transfer process is described by the equations:

These same equations apply to the mass transfer process. The simplest set of initial and boundary condiTions is starting with a uniform temperature, 0, of bed and flo\virig fluid and changing the inlet temperature at zero time to To: The solutions for this case, integrals containing Bessel functions, have been evaluated by numerical or graphical methods. Schumann (6) and Furnas ( 2 ) have given tv-o sets of curves

Equations 3 and 1,although approximations, are considerably more accurate than the drawings given by Furnas ( 2 ) ; the ~ d i nates of the Furnas dravings are sometimes subject to errors over 0.01. ;\loreover, the Furnas curves do not allow easy interpolation for intermediate Y values, nhich problem does not# arisr any longer. The insufficiency of rhe Furnas curves for u8c in regions of l o w concentratioii is stressed by IClotz (4). X nomog~aph(Figure 2) is based on Equation 3. It has parallel and equidistant’ scales on which are indicated

Tj T and -’

as functions of Z for a numbtir of values of Y To ranging from 1to 500. Figure 1 s h o w such curves for Y = 2, 4, and 8 (full lines) The

sholving

Vcl. 40, No. 1,o

To

~

most rapid change of the ordinates takes place in the neighborhood of Z = Y . Also shon-n in Figure 1 is the curve (brolwn line) representing

!r To l/z

[I

1

dr

iz

- .iY

J

inverse

r

\

.

.

of the rrroi functlon of

As is cviderit from Equations 3 and 4 the same noinogrqh 7‘ can be uwd l o give the --!values---that is, by jiiterehangi~igZ 2’0

=

e-‘d2&

-a

+ erf(v‘z

the

- -d/r)i

(2)

and Y and subtracting the integral from unity. This is done by turning Figure 2 upside doim arid reading the other set of smbscripts. Thus, Y = 10 and Z = 12 correspoiids to 7 2 j = 0.70, but also

where e r f ( p ) represents the error function or prohability integral

To 1 ‘e

an approximation nhich has been used by Walter (8).

T/ T - and curves are very similar to this To To latter curve and about 112 unit’of 2 at either side of it. It is seen tha,t the

rr,

Z = 1 0 a n d Y =12to--Oo.3Cu. TQ For values of Y aiid Z , higher than those indicated OIL Figure 2 the reader may easily calculate further scales to t,he nomograph. However, the _ _error ~ _ _integral vrith the simpler upper limit. of integration d.Z - 4 Y or l / Z .- 41’ thvn should be 7’ 7‘ a good appros.matiori for 2 arid ;