Correction-The Kinetics of Nickel Carbonyl Formation - Industrial

Ind. Eng. Chem. Process Des. Dev. , 1963, 2 (4), pp 314–314. DOI: 10.1021/i260008a015. Publication Date: October 1963. ACS Legacy Archive. Cite this...
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Table II. Vessel Shape Power Factors for Six-Blade Open-Style Turbine

WID Installation

DIT

Horizontal cylindrical tank, 5 :1

0.4

Square tank

= 1/8

Impellm Location

Center mounted

0.4

Vertical Bajj7es Location

‘Vumber

None (2) T/10

Center mounted T/4 eccentric mounted Center mounted

To indicate clearly the typical behavior of the three styles of turbines, Figure 7 shows the Power number for the ordinate rather than a power factor. For direct use as a geometric factor in Equation 1, the ratio of the N p value for a specific condition to the N p value a t “standard” conditions-Le., C/ T = l / g c a n be used. For the disk turbine, since the suction is partitioned by the disk, there is a marked reduction in power as clearance is decreased. T h e flat open-style six-blade turbine ( w / D = l / ~ ) displays a variable effect a t different clearances, but in general a slightly higher power level a t lower values of C/D. Increasing the proximity of a 45’ pitched open-style sixblade turbine (w/D = l / ~ ) ,as expected, increases power consumption. T h e data of Miller and M a n n (9) note a reduction in power rather than a n increase, but their data were taken in a n unbaffled system and thus a r e not comparable.

DISC TYPE

I

None None (4) TI10 (2) T/10

T w

wb Z

= = = =

Factor

... ...

0.75 1 .o 1. o 1 .o

90”, wall center 180°, wall center

tank diameter impeller blade width baffle width liquid depth

GREEKLETTERS

e

= angle of impeller blade from horizontal

p p

= viscosity = density

SUBSCRIPTS 1 = condition 1 2 = condition 2 EXPONENTS = a, b ,

G,

etc.

literature Cited

(1) Bates, R. L., Ind. Eng. C h m . 51, 1245 (1959). (2) Bissell, E. S., Hesse, H . C., Everett, H. J., Rushton, J. H., Chem. Eng. Progr. 43, 649 (1947). (3) Calderbank, P. H., Trans. Inst. Chem. Engrs. 36, 443 (1958). (4) Hixson, A. W., Baum, S. J.. Ind. Eng. Chem. 34, 194 (1942). (5) Hixson, A. W., Luedeke, V. C., Ibid., 29, 927 (1937). (6) Johnstone, R. E., Thring, M. W., “Pilot Plants, Models and Scale-up Methods in Chemical Engineering,” McGraw-Hill, New York. 1957. (7) Lee, R. E., Finch, C. R., Wooledge, J. D.. Ind. Eng. Chem. 49, 1849 (1957). (8) Mack, D. E., Kroll, A. E., Chem. Eng. Progr. 44,189 (1948). (9) Miller, S. A., Mann, C. A.. Trans. A.I.CI1.E. 40, 709 (1944). (10) Nanata. S.. Yokovama., T.,, Mem. Fac. Ene., Kyoto Unzv. , ‘ (Japm,”17, ’253’(195 5) .‘ (11) Nagata, S., Yokoyama, T., Maeda, H., Ibid., 18, 13 (1956). (12) O’Connell, F. D., Mack, D. E., Chem. Eng. Aogr. 46, 358, (1950). (13) Rushton, J. H., Costich, E. W.,Everett. H J.. Ibzd., 46, 395 (1950). (14) Ibid., b. 467. (15) Unwin, W. C.: Proc. Roy. Sac. (London) A31, 54 (1880). (16) Van de Vusse, J. G.. Chem. Eng. Sci.4, 178, 209 (1955). (17) White, A. M.: Brenner, E., Trans. A.Z.Ch.E. 30, 585 (1934). (18) White, A. M., Brenner, E.: Phillips, G. L4.,Morrison, M. S., Ibid., 30, 570 (1934). (19) White, A. M., Somerford, S. D., Chem. M e f . Eng. 43, 370 (1936). I

I ’ 01

, 02

03

04

CLEARANCE RATIO

Figure 7.

06 +

OB

10

I 20

C/D

Effect of turbine proximity on power

Nomenclature

C

off tank bottom, measured from underside of impeller D = impeller diameter g, = gravitational constant o r conversion factor K = constant 1 = blade length n = number of impeller blades nb = number of baffles .V = impeller speed, r.p.m. ArFp= Froude number N p = Power number NRe= Reynolds number = blade pitch = power S = impeller spacing

.

RECEIVED for review December 31, 1962 ACCEPTED June 10, 1963 A.1.Ch.E. Meeting, Chicago, Ill., December 1962.

= impeller distance

PP

314

1. o 1 .O

D/4 distance, ‘180’ longitudinal axis

I h E C PROCESS D E S I G N A N D D E V E L O P M E N T

Correction

THE KINETICS OF NICKEL CARBONYL FOR MATION I n this article by M‘. M. Goldberger and D . F. O t h m e r [IND. E N G . CHEM.PROCESSDESIGNAND DEVELOP.2, 202 (1 963) 1, on page 209, reference 8 should read : Othmer, D . F.. Luley, .4.H.. Ind. Eng.Chem. 38,408 (1946).