Correction to “Baulamycins A and B, Broad-Spectrum Antibiotics

Jul 14, 2014 - Total Synthesis of Reported Structure of Baulamycin A and Its Congeners. Sandip Guchhait , Shamba Chatterjee , Ravi Sankar Ampapathi , ...
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Addition/Correction pubs.acs.org/JACS

Correction to “Baulamycins A and B, Broad-Spectrum Antibiotics Identified as Inhibitors of Siderophore Biosynthesis in Staphylococcus aureus and Bacillus anthracis” Ashootosh Tripathi, Michael M. Schofield, George E. Chlipala, Pamela J. Schultz, Isaiah Yim, Sean A. Newmister, Tyler D. Nusca, Jamie B. Scaglione, Philip C. Hanna, Giselle Tamayo-Castillo, and David H. Sherman* J. Am. Chem. Soc. 2014, 136, 1579−1586. DOI: 10.1021/ja4115924 Page 1579. In the abstract graphic, which is also used for the Table of Contents entry, five stereocenters of the baulamycin A molecule were drawn incorrectly. The corrected structure is shown below:

Page 1581. In Figure 3, the configurations at C-14 for baulamycin A and C-13 for baulamycin B were drawn incorrectly. The corrected figure is shown below.

Figure 3. Planar structure of baulamycins A (6) and B (7) showing COSY correlation with bold bonds and HMBC correlations with arrow.

Published: July 14, 2014 © 2014 American Chemical Society

10541

dx.doi.org/10.1021/ja505297x | J. Am. Chem. Soc. 2014, 136, 10541−10541