Addition/Correction pubs.acs.org/JACS
Cite This: J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
Correction to “Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines” Brian P. Woods, Manuel Orlandi, Chung-Yang Dennis Huang, Matthew S. Sigman,* and Abigail G. Doyle* J. Am. Chem. Soc. 2017, 139, 5688−5691. DOI: 10.1021/jacs.7b03448 S Supporting Information *
Table 3. Scope of Stereoconvergent Reaction
Table of Contents. The enantiomer of the BiOx ligand that delivers the indicated absolute configuration of product is (R,R)-(4-heptyl)BiOx. The corrected graphic is shown below:
Page 5690. The absolute configuration of ligand L7 (4-heptylBiOx) was misassigned. The updated assignment requires corrections to Figure 2 and Table 3. The (S)-enantiomer of cross-coupled product 7 is obtained using the (S,S)-series of BiOx ligands. The corrected Figure 2 is given here.
a
Yield of isolated product (3 equiv of iodide). bDetermined by chiral HPLC. c10 mol % Ni, 12 mol % L7. dNo TMSCl added.
Supporting Information. Page S2. The (R,R)- not the (S,S)BiOx ligands L7-L9 were used for the studies in Figure S1. Pages S4 and S5. (R,R)-L7, not (S,S)-L7, was used for the scope studies in Tables S1, S2, and S4. Page S8. The (S)-enantiomer of cross-coupled product 7 is obtained using the (S,S)-L7 ligand in Scheme S5. Pages S12 and S13. The absolute configurations of structures S2-S5 have been corrected.
Figure 2. Impact of BiOx ligand substituent on asymmetric crosscoupling.
Page 5690. (R,R)-L7, not (S,S)-L7, was used for the scope studies in Table 3. The corrected Table 3 is shown here. We thank the Reisman laboratory for sharing information leading to this reassignment. © XXXX American Chemical Society
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DOI: 10.1021/jacs.8b05650 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
Journal of the American Chemical Society
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Addition/Correction
ASSOCIATED CONTENT
S Supporting Information *
The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/jacs.8b05650. Experimental procedures, additional reaction optimization, and spectroscopic data for all new compounds (corrected) (PDF)
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DOI: 10.1021/jacs.8b05650 J. Am. Chem. Soc. XXXX, XXX, XXX−XXX
