Correction to Stereoselective Alkene Isomerization Over One Position

General Catalyst Control of the Monoisomerization of 1-Alkenes to trans-2-Alkenes ... A General Strategy for Open-Flask Alkene Isomerization by Ruthen...
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Addition/Correction pubs.acs.org/JACS

Correction to Stereoselective Alkene Isomerization Over One Position Casey R. Larsen and Douglas B. Grotjahn* J. Am. Chem. Soc. 2012, 134, 10357−10360. DOI: 10.1021/ja3036477 S Supporting Information *

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age 10358. The substrates and products in Table 1, entries 4 (5, 5a) and 12 (13, 13a) feature a tert-butyl dimethylsilyl (TBDMS) ether substituent (correctly identified for 5 and 5a in Supporting Information, pages S7−S8, and revised to 13 and 13a in Supporting Information, pages S17−S18, respectively) rather than the TMS group shown. Page 10359. Table 4, entry 3b was performed using 2 mol % catalyst, not 0.1 mol % as indicated by superscript b. In Scheme 2, the isolated yield of 29a was 95%, not 96%. Supporting Information has been corrected. Pages S3−S4. Results from isomerization of diallyl ether with 0.5 mol % catalyst 1 are now shown as Table S1, instead of results with 2 mol %. Page S7−S48. Several tables are renumbered to be in sequence, without changes to the contents. Page S17. Table S14 showed incorrect data for isomerization of 13 to 13a but now provides the correct data. The results in the manuscript (Table 1, entry 12) are correct, other than changing the reaction time listed from