INDUSTRIAL AND ENGINEERING CHEMISTRY
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Vol. 42, No. 7
(6) Gilmour, R., J . SOC.Chem. Ind., 41, 293-4T (1922). (13) Moor, V. G., Kanep, E. K., and Dobkin, I. E., Trans. Ezptl. (6) Hildebrand, J. H., “Solubility of Konelectrolytes,” 2nd cd., Research Lab. K h e m g a s , Materials o n Cracking and Chemical chap. 111, 1936. Treatment of Cracking Products U.S.S.R., 3, 320-8 (1937). (14) Othmer, D. F., JND.EXG.CHEM.,35, 614-20 (1943). (7) Kireev, V. A., and Popov, A. A . , J . Applied Chem. (U.S.S.E.), 7, 489-94 (1934). (15) Othmer, D. F., and Morley, F. R., Ibid.,38,751-7 (1946). (16) Pascal, P., Dupuy, Ero, and Garnier, Bull. soc. chim. France, (8) Laar, J. J. v a n , 2 . phusik Chem., 72, 723-51 (1910); 83, 599608 11913). 29, 9-21 (1921). . , (9) Lichtenstein, H.J., and Twigg, G . H., Trans. F a ~ a d a ySoc., 44, (17) Ponndorf, W., Ber., 64, 1913-6 (1931). 905-9 (1948). (18) Scatchard, G., and Hamer, W.J., J . Am. Chem. Soc., 57, 1805(10) Lubatti, J., J . SOC.Chem. Ind., 51, 361-7T (1932). 9 (1935). (11) Maass, 0.. and Boomer, E. H.. J . Am. Chem. Soc., 44, 1709-28 (19) Timmermans, J., and Hennant,-Roland, -MMme., J . chim. phys., (1922). 34, 693-739 (1937). (12) Margules, M., Sitzber. A k u d . Wiss Wien, itlath.-nutunu. K ~ S S E . 11, 104, 1243-78 (1895). RECEIVED December 28, 1949.
Solubility Diagrams for Ternary and Quaternary Li Correction and Addendum Since the article on “Solubility Diagrams for Ternary and Quaternary Liquid Systems” appeared [Smith, J. C., ISD. ENQ. CHEM.,41, 2932 (1949)], several errors and omissions have been called to the author’s attention. On page 2932 in Table I
ADDITIONALSYSTEMS Components of Aqueous Ternary Systems Acetone Chloroform Glycerol n-Heptane n-Hexane Polyvinylpyrrolidone (Kollidon) Allyl alcohol Carbon tetrachloride Trichloroethylene Ethanol Benzene Ethyl acetate Ethyl ether Toluene Trichloroethylene Trichloroethylene m-Xylene ~\‘Ha)zSOr
Etkyl ether Ethanol Vinyl pyrrolidone &PO4 Glycerol Acetone tert-Amyl alcohol Aniline Benzyl alcohol %-Butylalcohol Cyclohexanol Methyl ethyl ketone Methanol iMethylmethacrylate Methyl ethyl ketone Benzene Butyl Cellosolve Chlorobenzene Glycerol n-Heptane n-Hexane 1,1,2-Triohloroethane Trichloroethylene Phenol Benzine Isopropyl alcohol Diisopropyl ether n-Propyl alcohol n-Propyl acetate Pvridine Benzoic acid Toluene Diethylamine Ethanol Trichloroethylene Allyl alcohol Ethanol Ethanol Methyl ethyl ketone Nicotine Vinylpyrrolidone Ethyl acetate Ethyl ether Methylene chloride
Temp.,
C.
25,60
the citation number for the system water-acetaldehyde-vinyl acetate should be ( 112), not (102). On page 2933 the temperature listed for the system water-ethanol-p-xylene should be 15” C., not 0’ C.; the system water-ethanol-p-nitrotoluene should be water-ethanol-0-nitrotoluene, although incorrectly listed in several places in the original reference (21). The system benzenetoluene-n-heptane-methyl sulfate should be deleted from Table IV on page 2935. Additional ternary systems for which data are available are listed, with literature citations.
25 25
LITERATURE CITED
25
25
25 and b.p.
25 and b.p. 25 70
20 25 25 20,67 25 33 20 25 0
25 7.6, 25,48.6
25.75
25,75 25 60 25 25
25, 50 25 25 25
25
25 25
25 80,90
25 20,35 50
25 25 25 and b.p. 25 20,67 25 17
25 25 2 :.
system-
(Al) Bonner, W. D., and Williams, R.I. B., J . Phga. Chem., 44, 404 (1940). (A2) Colburn, A. P., and Phillips, J. C., Trans. Am. Inst. Cham. Engrs., 40, 333 (1944). (A3) Copenhaver, J. W.,a n d Bigelow, 1LI. H., “Acetylene and Carbon Monoxide Chemistry,” pp. 76-9, New York, Reinhold Publishine Corls.. 1049. (A4) Elgin, J. C . (to ColGte-Palmolive-Peet Co.), U. S. Patent 2,479,041 (Aug. 16, 1949). (A5) Frere, F. J., IND. ENGI. CHEM., 41, 2366 (1949). (A6) Griswold, J . , Chu, P. L., a n d Winsauer, W. O., Ibid., 41, 2352 (1949). (A7) Hands, C. H. G., and Norman, W. S., Trana. Inst. Chem. Engirs. (London),23, 76 (1945). (AS) Kooi, J., Rec. trav. chim., 68, 34 (1949). (A9) Mertslin, P. B., J . Gen. Chem. (U.S.S.R.), 8, 1742 (1938). (A10) Mondain-llonval, P., and Quiquerez, J., Bull. a m . him,, 7, 240 (1940). ( A l l ) Newman, hl., Hayworth, C. B., a n d Treybal, R. E., IND. ENC.CHEV.,41, 2039 (1949). (A12) Reilly, J., Kelly, D. F., a n d O’Connor, M., J . Chem. SOC. (London), 1941, 275. (A13) Reinders, W., a n d Minjer, C. I-I. de, Rec. trav. c h i m . , 66, 552 (1947). (A14) Ibid., p. 573. (A15) Ruderman, L. Ya., J. Applied Chem. (U.S.S.R.), 20, 908 (1947). (816) Shell Chemical Co.. San Francisco, “Methyl E t h y l Ketoiie,” pp. 33, 34, 1938. (A17) Smith, T. E., and Bonner, R. F., IND.ENG.CHEM..42, 896 (1950). (A18) Traube, J., and Neuberg, O., 2. physik. Chent., 1, 509 (1887). (819) Treybal. R. E., and Vondrak, 0. J., IND.ENG.CHEnf., 41, 1761 (1949). (A20) Ust-Kachkintsev, V. F., and Khlebnikov. P. A., J . Gen Chem. (U.S.S.R.),9, 1742 (1939). (A21) Wehn, W. E., a n d Franke, N. W., IND.ENG.CHBM.,41, 2853 (1949). (A22) Zhuravlev, E. F., Bull. inst. recherche8 bid. Perm., 11, 37 (1937).
. ,
J. C. S m m
