Dendritic Anion Hosts: Perchlorate Uptake by G5-NH2 Poly

Aug 11, 2007 - However, its ClO4- binding kinetics is faster and reaches equilibrium in ∼1 h. Note also that only a high pH (∼9.0) aqueous solutio...
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Environ. Sci. Technol. 2007, 41, 6521-6527

Dendritic Anion Hosts: Perchlorate Uptake by G5-NH2 Poly(propyleneimine) Dendrimer in Water and Model Electrolyte Solutions M A M A D O U S . D I A L L O , * ,†,‡ KWESI FALCONER,‡ JAMES H. JOHNSON, JR.,‡ AND WILLIAM A. GODDARD, III† Materials and Process Simulation Center, Beckman Institute 139-74, California Institute of Technology, Pasadena, California 91125, and Department of Civil Engineering, Howard University, Washington, DC, 20059

Perchlorate (ClO4-) has emerged as a major groundwater and surface water contaminant in the United States. Ion exchange (IX) is the most widely used technology for treating water containing lower concentrations of perchlorate (