Electrical charge conduction mechanism in polymer membrane ion

currently under way in our laboratories. LITERATURE CITED. (1) R. P. Buck, Anal. Chem., 44, 270R (1972). (2) J. Koryta, Anal. Chlm. Acta, 61, 329 (197...
0 downloads 0 Views 629KB Size
Overcome by conditioning to desensitize the sensing eleis capab1e merit. Once desensitized, the of measuring calcium ion activity with no interferent effect LAS. The latter, however, was from the anionic surfactant observed to interact with calcium according to the usual interionic interaction principles. The interference effect of Hyamine be overcome. Such effect$however, can be utilized in conjunction with the formation of a Hyamine selective electrode. ~h~ latter can then be used as an indicator electrode in the Dotentiometric titration of anionic surfactants. I t is also possible to develop automated analyzers for the determination of cationic and anionic surfactants based on ion-electrode sensing and continuous flow techniques (39, 40). Such investigations are currently under way in our laboratories.

LITERATURE CITED (1) (2) (3) (4)

R. P. Buck, Anal. Chem., 44, 27013 (1972). J. Koryta, Anal. Chlm. Acta, 61, 329 (1972). G. A. Rechnitz, Acc. Chem. Res., 3, 69 (1970). G. A. Rechnitz. Anal. Chem., 41 (12), 109A (1969). (5) G. A. Rechnitz, Chem. Eng. News, 5 (24). 146 (1967). (6) G. J. Moody and J. D. R. Thomas, Talanta, 19, 623 (1972). (7) E. Pungor and K. Toth. Analyst(London), 95, 625 (1970). (8) W. Simon, PureAppl. Chem., 25, 811 (1971). (9) W. Simon, H. Wuhrmann, M. Vasak, L. Pioda, R. Dohner, and Z. Stefanac. Angew. Chem., lnt. Ed. fngl., g, 445 (1970). (10) A. K. Covington, Chem. Br., 5, 388 (1969). (1 1) J. Ruzicka, C. G. Lamm, and J. C. Tjell, Anal. Chim. Acta, 62, 15 (1972). (12) M. S. Frant, J. W. Ross, and J. M. Riseman, Amer. Lab., 1 (l), 14 (1969). (13) E. J. Zinser and J. A. Page, Chem. Can., 1, 3 1 (1969). (14) G. J. Moody and J. D. R. Thomas, Selective Ion-Sensitive Electrodes", Morrow Publ. Co. Ltd., Watford, Hefordshire, England, 1971.

(15) R. M. Bates, "Determination of pH. Theory and Practice", 2nd ed., J. Wiley and Sons, New York, N.Y., 1964. (16) G. Eisenman, Ed., "Glass Electrodes for Hydrogen and Other Cations: Principles and Practice", MarceCDekker, New York. N.Y., 1967. (17) R. A. Durst, Ed.. "Ion-Selective Electrodes", Nat. Bur. Stand. ( U . S . ) Spec. Publ., No. 314, US. Gov't Printing Office, Washington, D.C., 1969. (18) L. M. Chambers, Procter and Gamble Company, unpublished results. (19) J. W. Ross, Science, 156, 1378 (1967). (20) B. Fleet, T. H. Ryan, and M. J. D. Brand, Anal. Chem., 46, 13 (1974). (21) J. Bagp znd R. Vinen, Anal. Chem., 44, 1773 (1972). (22) J. W. Ross, in "Ion-Selective Electrodes", R. A. Durst, Ed., Nat. Bur. Stand. (U.S.) Spec. Publ., No. 314, U S . Gov't Printing Office, Washington. D.C.. 1969. o 57. (23) J. A. King and A.Ti