FROM SHELL CHEMICAL - C&EN Global Enterprise (ACS Publications)

FROM SHELL CHEMICAL

• • • in tank cars and drums Here are typical reactions of Allyl Alcohol that may suggest ways through which you can accomplish useful chemical syntheses: Polymerization

Reactions i n v o l v i n g THE DOUBLE BOND

Homopolymers Linear copolymers* | Cross-linked copolymers* CH2-CH-CH2OH

Halogens (X 2 )

I I Amines (RNH 2 )

I

|_X X CH2-CH2-CH2OH

I

RNH

Organic Acids (RCOOH)

Reactions i n v o l v i n g THE HYDROXYL GROUP

CH2 = CH-CH 2 OOCR CS2 and KOH

1 H2S

Oxidation

Reactions i n v o l v i n g

PKS-C-O—C3H5

Rearrangement

II S CH 2 =CH-CH 2 SH

3(HCOOH) CH3-CH2-CHO

BOTH FUNCTIONS *Linear copolymers with mono-allyl esters, styrene and other singly unsaturated compounds; cross-linked copolymers with di- and tri-allyl esters of di- and tribasic acids and with drying oils.

Alkylation(C 6 H 6 )

C

H3-CH-CH2

I

I

C6H5 C6H5

A 96-page book which summarizes the known properties and uses of Ally! Alcohol will be mailed upon receipt of your letterhead request. Samples of Allyl Alcohol for evaluation are available.

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