[CONTRIBUTION FROM THE MASSACHUSETTS INSTITUTE O F TECHNOLOGY.]
REVIEW OF AMERICAN CHEMICAL RESEARCH. VOL. VI.
No.
I.
ARTHURA. NOYES,Editor. REVIEWERS: Analytical Chemistry, H. P. Talbot and W. H. Walker ; Biological Chemistry, A. G. Woodman ; Carbohydrates, G. W. Rolfe ; General Chemistry, A. A. Noyes ; Geological and Mineralogical Chemistry, W. 0. Crosby and M. I,. Fuller ; Inorganic Chemistry, H e n r y Fay ; Metallurgical Chemistry and Assaying, H. 0. Hofman ; Organic Chemistry, J. F. Norris ; Physical Chemistry, H. M. Goodwin ; Sanitary Chemistry, E. H. Richards; Industrial Chemistry, A. H. Gill and F. H. Thorp.
GENERAL AND PHYSICAL CHEMISTRY. A. A. NOYES,REVIEWER.
The Development and Application of a General Equation for Free Energy and Physico-Chemical Equilibrium. BY GILBERTNEWTONLEWIS. Pmc. Ant. Acad., 35, 1-38.--The title well indicates the general scope of the article, of which a detailed review is impracticable. T h e following laws and phenomena are considered by the author from the point of view of his general free energy equation : law of mass-action; law of constant distribution-coe5cients ; change of equilibrium with temperature including van't Hoff's equation ; van der Waals' equation ; heats of vaporization and vapor-pressure curves ; specific heats of liquids and vapors; osmotic pressure of concentrated solutions ; distribution of a solute between two solvents ; single potential differences and electromotive force of concentration cells and of those composed of the same metal in contact with the same electrolyte dissolved in two different solvents. T h e mathematical treatment of the author is unusually clear and explicit. Contribution to Our Knowledge of Aqueous Solutions of Double Salts.-IZ. ChZoorides. BY HARRYC. JONES A N D KENJIROOTA. A m . Chem. J., 22, ~-I~.-IZZ. Chlorides and Bromides. BY HARRYC. JONES A N D NICHOLASKNIGHT. Am. Chem. J . , 22, I I C - I ~ I . - T electrical ~~ conductivity of aqueous solutions, varying in concentration from 0.5-1 .o mol. per liter to a very high dilution, of a considerable number of double chlorides and bromides, was measured and compared with the sum of the conductivities of the separate components of
Review of Amcvicaiz Chemicad Research.
2
the double salt, which were in many cases measured by the authors, but in others were taken from Kohlrausch. T h e following table presents the results in a greatly condensed form. Under v is given the volume in liters in which one grammolecular weight of the double salt is dissolved, and under ‘ ‘ per cent. diff. ’ ’ is given the percentage difference (unfortunately not calculated by the authors) between the sum of the coilductivities of the separate component salts and the conductivity of the double salt. T h e four salts in the first horizontal series were investigated by Jones and Ota, the reniainder by Jones and Knight. 2I
