Isotopic Equilibrium Separation Factors in the ... - ACS Publications

Isotopic Equilibrium Separation Factors in the. Hydrogen Solubility Process in Platinum-. Palladium Alloys. Sir: Thestudies on platinum-palladium allo...
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bonds. 3, * Apparently, the medium-pressure lamp emits radiation below 2200 8. which can cleave the C-F bond. The mechanism that explains the results with 2537-,k. radiation is314

+ hv(2537 K.)+Hg* Hg* + CzF4 +Hg + 2CFz CFz + CzF4 + c - C ~ F ~ Hg

2CF2 +CzF4

(1) (2)

(3)

(4)

When higher-energy radiation is also present, then CzF4

A.)+C2F3 + F

-I- h~(