Kinetics of metal ion and metal chelate catalyzed oxidation of ascorbic

Decomposition of Ascorbic Acid in the Presence of Cadmium Ions Leads to Formation of a Polymeric Cadmium Oxalate Species with Peculiar Structural ...
0 downloads 0 Views 549KB Size
4668

81.95, X M for (CH3)2Si(0C2H& = 104.20, and X C H * = 11.17 gives C = -0.02. Using these parameters, xM values for dimethyl di-nalkoxysilanes have been calculated and summarized in Table 111. For xM values of acetoxy- and propionoxysilanes of the general formula (CH3),Si(OC=OC,H2n+l)d, Hameka's equation has been used as XM =

aA

+ d D + adE

where

D = 0.25x(Si)

+ x(OCOC,HZ,+l) +

x(Si-OCOC,H,,+,)

+ 1.5~

and

(

E = x S i