LEAD DUSTUP - C&EN Global Enterprise (ACS Publications)

Apr 16, 2001 - WITHIN THE SPACE OF A week, both the City of Milwaukee and the State of Rhode Island advanced lawsuits against lead paint and pigment ...
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NEWS OF THE WEEK BUSINESS

LEAD DUSTUP Milwaukee, Rhode Island sue to force manufacturers to remove lead paint

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I T H I N THE SPACE OF A

week, both the City of Milwaukee and the State of Rhode Island advanced lawsuits against lead paint and pigment makers seeking mil­ lions of dollars for the clean up of poorly maintained, mostly inner-city housing. Widely used in residential paints prior to 1955 and banned by the federal government in 1978, lead carbonate-based paints deteriorate to a dust, threatening children's developing brains and nervous systems. New York City, St. Louis, and the County of Santa Clara, Cali­ fornia, are among other munici­

ART

palities that have filed similar suits over the past decade. Milwaukee's suit seeks to recover costs from former lead pigment manufacturer NL Indus­ tries and Wisconsin paint maker Mautz Paint. Cleaning up the city's housing stocks will cost as much as $100 million, an attor­ ney for the city says. In Providence, R.I., a county superior court judge allowed a lawsuit brought by the state against paint and pigment mak­ ers in October 1999 to move to trial. T h e Rhode Island suit names not only N L Industries, but also the Lead Industries As­ sociation and paint companies

CONSERVATION

SCIENCE IN THE SERVICE OF ART Chemist helps unveil original vibrancy of a 17th century painting

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o DEMYSTIFY T H E w i z ­

ardry that takes place behind the scenes in its con­ servation division, the National Gallery of Art in Washington, D.C., last week took journalists on a tour of its labs. This was the first of what will become an annual event. In the scientific research lab, chemist Barbara H. Berrie, a conservation scientist, ex­ plained how science helped to determine that the brown paint in the oil painting "St. Sebast­ ian" was not applied by the artist, Tanzio da Varallo. Tanzio painted this picture sometime in the 1620s. But scanning elec­ HTTP://PUBS.ACS.ORG/CEN

tron microscopy of a scraping revealed that the brown paint was cadmium orange, a modern pigment. Conservator Susanna Ρ Griswold removed the brown paint, which exposed a layer of green paint seen in the drapery across the saint's lap (bottom, left). Now the question was: Should the green paint also be removed? Berrie took a microscopic sample from the drapery area that disclosed in cross section a layer of varnish between the green paint and an underlying yellow paint layer (top). Using polarized light microscopy, she identified the green paint as a

including DuPont, Glidden, and Sherwin-Williams. Responding to the Rhode Island suit, paint makers' attor­ ney Donald E. Scott points out that "in the early 1950s, the industry sponsored medical research that helped to define and publicize the health risk to chil­ dren from deteriorated, poorly maintained interior lead paint. The companies all voluntarily stopped marketing interior leadbased paint decades ago and pro­ vided product warnings." It is important to put these lawsuits in perspective, says N L Industries spokesman Alan Wheat, who notes that, "of the 40 to 50 lawsuits against the for­ mer manufacturers of lead pig­ ment that have been concluded, the companies have not lost or settled a single case. The prob­ lem is not a manufacturing prob­ lem; it is a maintenance prob­ lem."—MARC REISCH

WARNING Peeling lead-based paint is hazardous to children's health.

mixture of copper acetate and calcium carbonate. The inter­ vening varnish layer indicated to her that the green paint was the result of a previous restoration and could be removed. Removal of the green paint revealed not only a pulsating yel­ low color but the sensuous folds of the drapery as Tanzio painted it (bottom, right). Using X-ray powder diffraction, Berrie iden­ tified the yellow pigment as lead tin oxide. — LOIS EMBER

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