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M2B10O14F6 (M=Ca, Sr): The First Two Noncentrosymmetric Alkaline-Earth Fluorooxoborates as the Promising NextGeneration Deep-Ultraviolet Nonlinear Optical Materials Min Luo, Fei Liang, Yunxia Song, Dan Zhao, Feng Xu, Ning Ye, and Zheshuai Lin J. Am. Chem. Soc., Just Accepted Manuscript • DOI: 10.1021/jacs.8b01263 • Publication Date (Web): 08 Mar 2018 Downloaded from http://pubs.acs.org on March 8, 2018
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Journal of the American Chemical Society
M2B10O14F6 (M=Ca, Sr): The First Two Noncentrosymmetric Alkaline-Earth Fluorooxoborates as the Promising Next-Generation Deep-Ultraviolet Nonlinear Optical Materials Min Luo†, Fei Liang§, ‡, Yunxia Song†, ‡, Dan Zhaoƾ, Feng Xu†, ‡, Ning Ye*, † and Zheshuai Lin§ †
Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China § Beijing Center of Crystal R&D, Key Lab of Functional Crystals and Laser Technology, Chinese Academy of Sciences, Beijing 100190, China ‡
University of Chinese Academy of Sciences, Beijing 100190, China Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China Supporting Information Placeholder ƾ
ABSTRACT: Two novel noncentrosymmetric alkaline-earth fluorooxoborates, M2B10O14F6 (M=Ca, Sr), were synthesized and characterized. Both of these two isostructural compounds had layered [B5O7F3]∞ structures with large second harmonic generation (SHG) responses ranging from 2.3 to 2.5×KH2PO4 (KDP) and short UV absorption edges (
