Research Article Cite This: ACS Catal. 2019, 9, 7520−7526
pubs.acs.org/acscatalysis
Microballs Containing Ni(0)Pd(0) Nanoparticles for Highly Selective Micellar Catalysis in Water Manisha Bihani,† Pranjal P. Bora,† Maarten Nachtegaal,‡ Jacek B. Jasinski,§ Scott Plummer,∥ Fabrice Gallou,⊥ and Sachin Handa*,†
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Department of Chemistry, and §Materials Characterization, Conn Center for Renewable Energy Research, University of Louisville, Louisville, Kentucky 40292, United States ‡ Paul Scherrer Institute, Forschungsstrasse 111, Villigen, 5232 Switzerland ∥ Novartis Institutes for Biomedical Research, 250 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States ⊥ Novartis Pharma AG, Basel, 4056, Switzerland S Supporting Information *
ABSTRACT: Both Ni(0) complexes and nanoparticles (NPs) are unstable in water, which poses a significant hindrance to their application in aqueous synthetic catalysis. To overcome these barriers, ligated Ni(0) nanoparticles (diameter
