Mineral Matter and Ash in Coal - American Chemical Society

d e p o s i t l a y e r i s by r a d i a t i o n at high temperature. The values o f k ... of the deposit layer. In the range of surface temperatures ...
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26 Influence of Thermal Properties of Wall Deposits on Performance of Pulverized Fuel Fired Boiler Combustion Chambers W. Richter, R. Payne, and M. P. Heap

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Energy and Environmental Research Corporation, Irvine, CA 92718

The properties which determine heat transfer through a deposit layer of given thickness are thermal conduc­ t i v i t y , emissivity, and absorptivity. These proper­ ties vary with deposit temperature, thermal history, and chemical composition. Parametric studies and calculations for existing boilers were carried out to show the sensitivity of overall furnace performance, l o c a l temperature, and heat flux distributions to these properties in large p . f . fired furnaces. The property values used cover the range of recent experi­ mental studies. Calculations for actual boilers were carried out with a comprehensive 3-D Monte Carlo type heat transfer model. Some predictions are compared to full-scale boiler measurements. The calculations show that the effective conduction coefficient (k/Δs) of wall deposits strongly influences furnace exit temperatures. eff

The b u i l d u p o f a s h d e p o s i t l a y e r s on tube w a l l s and s u p e r h e a t e r s i n d r y bottom p . f . b o i l e r combustion chambers does n o t o n l y d e t e r i o r a t e f u r n a c e a n d o v e r a l l b o i l e r e f f i c i e n c y , but a l s o i n c r e a s e s t h e tem­ p e r a t u r e l e v e l i n f u r n a c e and c o n v e c t i v e passages and a g g r a v a t e s e x i s t i n g d e p o s i t problems. T h i s can f i n a l l y lead t o expensive out­ a g e s when d e p o s i t f o r m a t i o n c a n n o t be c o n t r o l l e d by s o o t b l o w i n g alone. S i n c e e r r o r s i n f u r n a c e d e s i g n w i t h r e s p e c t t o s l a g g i n g and f o u l i n g o r i n c o r r e c t e s t i m a t e s o f t h e impact o f f u e l c o n v e r s i o n on d e p o s i t f o r m a t i o n a r e so c o s t l y i n l a r g e b o i l e r s , t h e r e i s c o n s i d e r ­ a b l e f i n a n c i a l i n c e n t i v e t o d e v e l o p a n a l y t i c a l methods i n o r d e r t o p r e d i c t f u r n a c e performance f o r a wide range o f c o a l types and oper­ ating conditions. I t i s c l e a r t h a t such methods must take q u a n t i ­ t a t i v e l y i n t o a c c o u n t , among o t h e r t h i n g s , t h e t h e r m a l p r o p e r t i e s o f a s h d e p o s i t s , i . e . t h e r m a l c o n d u c t i v i t y , e m i s s i v i t y , and a b s o r p ­ tivity. The c u r r e n t paper p r e s e n t s r e s u l t s from v a r i o u s s t u d i e s c a r r i e d o u t by t h e a u t h o r s t o show t h e i n f l u e n c e o f t h e r m a l p r o p e r t i e s o f a s h d e p o s i t s on p e r f o r m a n c e o f l a r g e p . f . f i r e d b o i l e r f u r n a c e s . The paper i s d i v i d e d i n t o t h r e e s e c t i o n s . I n the f i r s t s e c t i o n , key 0097-6156/ 86/ 0301 -0375506.00/ 0 © 1986 American Chemical Society

Vorres; Mineral Matter and Ash in Coal ACS Symposium Series; American Chemical Society: Washington, DC, 1986.

376

MINERAL MATTER AND ASH IN COAL

p a r a m e t e r s o f o v e r a l l f u r n a c e performance a r e i d e n t i f i e d w i t h the h e l p o f a s e n s i t i v i t y s t u d y and r e l a t e d to the ash d e p o s i t prop­ erties. The second s e c t i o n summarizes e x p e r i m e n t a l d a t a of t h e r m a l p r o p e r t i e s o f d e p o s i t s and d e f i n e s t h e r a n g e o f v a l u e s p r o b a b l y o c c u r r i n g i n b o i l e r combustion chambers. In the t h i r d section, t y p i c a l p r o p e r t y v a l u e s a r e used i n c o m b i n a t i o n w i t h a s o p h i s t i c a t e d 3-D h e a t t r a n s f e r model i n o r d e r to demonstrate the e f f e c t of e x i s t i n g d e p o s i t l a y e r s on l o c a l t e m p e r a t u r e and h e a t f l u x d i s t r i b u t i o n and performance o f p a r t i c u l a r b o i l e r f u r n a c e s .

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Parametric

Study of O v e r a l l Furnace

Performance

The p a r a m e t r i c s t u d i e s w e r e c a r r i e d o u t i n o r d e r t o i d e n t i f y the most i m p o r t a n t p a r a m e t e r s i n f l u e n c i n g o v e r a l l f u r n a c e heat a b s o r p ­ tion. These parameters a r e : ο A d i a b a t i c Flame Temperature ο F i r i n g Density ο Total Emissivity ο Temperature of Heat S i n k S u r f a c e s ο Flow and Heat R e l e a s e P a t t e r n s F i g u r e 1 shows how these q u a n t i t i e s a r e r e l a t e d i n a complex manner to e a c h o t h e r , to f u e l c h a r a c t e r i s t i c s , to f u r n a c e o p e r a t i n g c o n d i t i o n s , and to w a l l d e p o s i t s . Some o f t h e r e l a t i o n s h i p s i n t h i s f i g u r e w e r e i n v e s t i g a t e d u t i l i z i n g a s i m p l e w e l l - s t i r r e d f u r n a c e m o d e l (I) which assumed t r a n s p o r t of gray r a d i a t i o n . This w e l l - s t i r r e d analysis predicted q u a l i t a t i v e l y t h e d e p e n d e n c e o f f u r n a c e e f f i c i e n c i e s r i f and e x i t temperature T , both r e l a t e d by E q u a t i o n 1 e x

T

M C 0

n

f

- ι -

— -

p

ex IT 0

(T

e x

-

T ) 0

(l)

:

Qo on f u r n a c e d e s i g n and o p e r a t i n g c o n d i t i o n s . An important d e s i g n parameter i s the f u r n a c e h e i g h t L r e q u i r e d to o b t a i n a d e s i r e d e f f i c i e n c y o r e x i t t e m p e r a t u r e (1 m of f u r n a c e h e i g h t c o r r e s p o n d s a p p r o x i m a t e l y to $500,000). I t was found t h a t the h e i g h t L depends c o n s i d e r a b l y on the c h a r a c t e r i s t i c s o f the w a l l d e p o s i t s , e s p e c i a l l y in large furnaces. T h i s i s shown i n F i g u r e s 2 and 3 i n which the efficiency i s p l o t t e d over the h e i g h t L w i t h s u r f a c e temperature T o f d e p o s i t s and s u r f a c e e m i s s i v i t i e s e as p a r a m e t e r s . The c a l c u l a t i o n s were c a r r i e d out f o r a r e c t a n g u l a r f u r n a c e box of w i d t h L/3. O t h e r i n p u t parameters a r e l i s t e d i n the f i g u r e s . The s t r o n g impact of w a l l temperatures f o r l a r g e r s i z e s ( F i g u r e 2) i s due t o t h e f a c t t h a t l a r g e f u r n a c e v o l u m e s a p p r o a c h b l a c k r a d i a t o r s and volume e m i s s i v i t i e s cannot be i n c r e a s e d anymore by i n c r e a s e i n s i z e . F o r f u r n a c e s o p e r a t e d w i t h the same t h e r m a l i n p u t a t low e f f i c i e n ­ c i e s , the presence of w a l l d e p o s i t s r e q u i r e s o n l y a moderate increase i n size. A r e d u c t i o n of s u r f a c e e m i s s i v i t i e s from 1 ( c l e a n " s o o t y " w a l l s ) t o 0.4 w h i c h i s t h e l o w e s t range r e p o r t e d f o r ash d e p o s i t s a l s o c a u s e s a drop of r\f o r r e q u i r e s an i n c r e a s e i n h e i g h t i n o r d e r t o m a i n t a i n rif ( F i g u r e 3 ) . The s i z e r e q u i r e d v a r i e s n o n l i n e a r l y w

w

Vorres; Mineral Matter and Ash in Coal ACS Symposium Series; American Chemical Society: Washington, DC, 1986.

26.

t

RICHTER ET AL.

Adiabatic

Performance

377

Load

Input .

Density • Furnace Geometry Fuel Composition Combustion Conditions

Heat S i n k Area •

Downloaded by FUDAN UNIV on January 10, 2017 | http://pubs.acs.org Publication Date: April 2, 1986 | doi: 10.1021/bk-1986-0301.ch026

Chambers

Heating Value Moisture Content Ash Content Excess A i r A i r & Fuel Preheat

Flame Temperature -

Thermal Firing

of Boiler Combustion

E m i s s i v i t y eg of Combustion Products •

Total

Emissivity · I Emissivity e I s o r p t i v i ty a ι Heat Sink

w

w

Abof Wall

^Therm. C o n d u c t i v i t y •

Temperature of ^ Heat Sink Surface

Net Heat k



Flux

D e n s i t yf