Modified Active Site Coordination in a Clinical Mutant of Sulfite

Christian J. Doonan, Heather L. Wilson, K. V. Rajagopalan, Robert M. Garrett, Brian Bennett, Roger C. Prince and Graham N. George*. J. Am. Chem. Soc. ...
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Modified Active Site Coordination in a Clinical Mutant of Sulfite Oxidase [J. Am. Chem. Soc. 2007, 129, 9421–9428]. Christian J. Doonan, Heather L. Wilson, K. V. Rajagopalan, Robert M. Garrett, Brian Bennett, Roger C. Prince, and Graham N. George* Page 9425. In the caption to Figure 5, panel B, there is an error in the assignment of the points. The correct caption and figure are given below:

Figure 5. (B) pH dependence of the MoV EPR signals. The points show

the experimental MoV integrated EPR signal intensity: O low-pH type 1, b low-pH type 2, and 2 high-pH. The lines are computed curves for the equilibrium discussed in the text, using pKa values of 6.1 and 8.0.

JA802011N 10.1021/ja802011n Published on Web 04/18/2008

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J. AM. CHEM. SOC. 2008, 130, 6298

10.1021/ja802011n CCC: $40.75  2008 American Chemical Society