Molecular structure and polymerization mechanism of poly (vinyl

Apr 4, 1984 - chloride-co-carbon monoxide)1. Lyle D. Wescott, Jr.,*7 Gilberto M. Villacorta,* Frederic C. Schilling,. Irene M. Plitz,5 and William H. ...
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Macromolecules 1984,17, 2501-2507

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Molecular Structure and Polymerization Mechanism of Poly(viny1 chloride-co-carbon monoxide)l Lyle D. Wescott, Jr.,*+Gilbert0 M. Villacorta,t Frederic C. Schilling, Irene M. Plitz,g and William H. Starnes, Jr.* AT&T Bell Laboratories, Murray Hill, New Jersey 07974. Received April 4,1984 ABSTRACT Vinyl chloridecarbon monoxide copolymers, prepared by free-radical initiation at 50 “C, are shown to contain the branch structure