Novel metal complexes involving a multiply bridged nitrogen atom

Mihai. Elian , Maynard M. L. Chen , D. Michael P. Mingos , and Roald. Hoffmann ... Heinrich Vahrenkamp , Vernon A. Uchtman , Lawrence F. Dahl. Journal...
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COMPLEXES INVOLVING A Mu”x

Vol. 7 , No. 2, Februuvy 196‘8 TABLE VI11 OF E o FOR V(bipy),2ti3+ CALCULATION USINGTHE MARCUST H E O R Y ~ Oxidant

kn, ‘V1-1 sec-1

R U ( ~ ’ H ~ ) ~0~. 1+2 C~(bipy),~+ 6.4 F e ( E D T A ) - 23

kri

-1 X 1036 -20c

> 104

Eli’

E210

-0.1Ob 0.37e

-0.81

-0.75

( > l o 3 a t 0’) -0.12f