Nucleophilicity, Copyright, ABOUT THE EDITORS, FOREWORD

Jul 1, 1987 - Nucleophilicity, Copyright, ABOUT THE EDITORS, FOREWORD, Advances in Chemistry Series. M. Joan Comstock, Series Editor...
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Nucleophilicity

In Nucleophilicity; Harris, J., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

In Nucleophilicity; Harris, J., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

Downloaded by 200.220.205.26 on November 27, 2015 | http://pubs.acs.org Publication Date: July 1, 1987 | doi: 10.1021/ba-1987-0215.fw001

A D V A N C E S IN CHEMISTRY SERIES

Nucleophilicity J. Milton Harris, EDITOR

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University of Alabama in Huntsville

Samuel P. McManus, EDITOR University of Alabama in Huntsville

Developed from a symposium sponsored by the Division of Organic Chemistry at the 190th Meeting of the American Chemical Society, Chicago, Illinois, September 8-13, 1985

American Chemical Society, Washington, DC 1987

In Nucleophilicity; Harris, J., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

215

Library of Congress Cataloging-in-Publication Data Nucleophilicity. (Advances in chemistry series, I S S N 0065-2392; 215) " D e v e l o p e d f r o m a s y m p o s i u m sponsored b y the D i v i s i o n of O r g a n i c C h e m i s t r y at the 190th annual meeting of the A m e r i c a n C h e m i c a l Society, C h i c a g o , Illinois, September 8-13, 1985."

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Bibliography: p. Includes index. 1. N u c l e o p h i l i c reactions—Congresses. I. Harris, J . Milton. II. M c M a n u s , Samuel P. III. A m e r i c a n C h e m i c a l Society. M e e t i n g (190th: 1985: C h i c a g o , Ill.) IV. A m e r i c a n C h e m i c a l Society. Division of O r g a n i c C h e m i s t r y . V. Series. QD1.A355 no. 215 I S B N 0-8412-0952-9

[QD501]

540 s

[547.1'39]

86-28843

C o p y r i g h t © 1987 A m e r i c a n C h e m i c a l Society A l l Rights Reserved. T h e appearance of the code at the bottom of the first page of each chapter in this v o l u m e indicates the copyright owner's consent that reprographic copies of the chapter m a y be m a d e for personal or internal use or for the personal or internal use of specific clients. T h i s consent is given on the condition, however, that the copier pay the stated per c o p y fee through the C o p y r i g h t C l e a r a n c e Center, Inc., 27 Congress Street, Salem, MA 01970, for c o p y i n g b e y o n d that permitted b y Sections 107 or 108 of the U.S. C o p y r i g h t L a w . T h i s consent does not extend to c o p y i n g or transmission b y any means— graphic or electronic—for any other purpose, such as for general distribution, for advertising or promotional purposes, for creating a new collective work, for resale, or for information storage and retrieval systems. T h e c o p y i n g fee for each chapter is indicated in the c o d e at the b o t t o m of the first page of the chapter. T h e citation of trade names a n d / o r names of manufacturers in this publication is not to b e construed as an endorsement or as a p p r o v a l b y A C S of the c o m m e r c i a l products or services referenced herein; nor should the mere reference herein to any d r a w i n g , specification, chemical process, or other data be regarded as a license or as a conveyance of any right or permission, to the holder, reader, or any other person or corporation, to manufacture, reproduce, use, or sell any patented invention or copyrighted work that m a y in any way be related thereto. Registered names, trademarks, etc., used in this publication, even without specific indication thereof, are not to be considered unprotected b y law.

PRINTED IN THE UNITED STATES OF AMERICA

In Nucleophilicity; Harris, J., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

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ABOUT THE EDITORS J. MILTON HARRIS is Professor of Chemistry at the University of Alabama in Huntsville. H e was Assistant Professor of Chemistry at Cali­ fornia State University, Fullerton, from 1970 to 1973 and Visiting Research Fellow at Princeton University from 1969 to 1970. H e received a B.S. in chemistry at Auburn University in 1963 and a Ph.D. in chemistry from the University of Texas at Austin in 1969. His research inter­ ests in physical organic chemistry include predicting transition-state structure, characterizing solvents and nucleophiles, and studying nucleophilic substitution. Additional research interests include synthesis of poly ethers and applications in biological purifications, surface modification, and enzyme modification and synthesis of new organic solids for use in optics and growth of crystals of these materials in microgravity.

SAMUEL P. M c M A N U S is Professor of Chemis­ try at the University of Alabama in Huntsville. He was graduated in 1960 with a B.S. degree in chemistry from The Citadel in Charleston, South Carolina, and received M . S . and Ph.D. degrees from Clemson University, specializing in organic chemistry. H e began investigating intramolecular nucleophilic reactions while still a graduate student. While a chemist at Ε. I. du Pont de Nemours' Marshall Labora­ tory in Philadelphia and with the U.S. A r m y at Redstone Arsenal in Alabama, his attention turned to the chemical reactions of polymers, a field that still attracts his attention. At the University of Alabama, D r . McManus resumed studies of nucleophilicity and has been especially active in the study of nucleophilic reactions with carbocations and ion pairs. Lately, he has explored the effects of microgravity on chemical processes. His research has led to more than 75 articles. He has also edited Organic Reactive Intermediates (1973) and coauthored Neighboring Group Participation (1976, with B. Capon). ν In Nucleophilicity; Harris, J., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

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FOREWORD The A D V A N C E S I N C H E M I S T R Y S E R I E S was

founded in 1 9 4 9 by

the American Chemical Society as an outlet for symposia and collections of data in special areas of topical interest that could not be accommodated in the Society's journals. It provides a medium for symposia that would otherwise be fragmented because their papers w o u l d be distributed among several journals or not published at all. Papers are reviewed critically according to A C S editorial standards and receive the careful attention and processing characteristic of A C S publications. Volumes in the ADVANCES IN CHEMISTRY SERIES maintain the integrity of the symposia on which they are based; however, verbatim reproductions of previously published papers are not accepted. Papers may include reports of research as well as reviews, because symposia may embrace both types of presentation.

In Nucleophilicity; Harris, J., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1987.

Advances in Chemistry Series M. Joan Comstock, Series Editor

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1987 Advisory Board Harvey W. Blanch University of California—Berkeley

Vincent D. McGinniss Battelle Columbus Laboratories

Alan Elzerman Clemson University

W. H . Norton J. T. Baker Chemical Company

John W. Finley Nabisco Brands, Inc.

James C. Randall Exxon Chemical Company

Marye Anne Fox The University of Texas—Austin

E. Reichmanis AT&T Bell Laboratories

Martin L. Gorbaty Exxon Research and Engineering Co.

C. M . Roland U.S. Naval Research Laboratory

Roland F. Hirsch U.S. Department of Energy

W. D. Shults Oak Ridge National Laboratory

G. Wayne Ivie USDA, Agricultural Research Service

Geoffrey K. Smith Rohm & Haas Co.

Rudolph J. Marcus Consultant, Computers & Chemistry Research

Douglas B. Walters National Institute of Environmental Health

In Nucleophilicity; Harris, J., et al.; Advances in Chemistry; American Chemical Society: Washington, DC, 1987.