Number 80 - American Chemical Society

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Number 80 compiled by Veronica M. Cornel Department of Chemistry, Reedley College, 339 West Carpenter AVenue, Reedley, California 93654 [email protected]

Reviews are listed in order of appearance in the sources indicated. In multidisciplinary review journals, only those reviews which fall within the scope of this Journal are included. Sources are listed alphabetically in three categories: regularly issued review journals and series volumes, contributed volumes, and other monographs. Titles are numbered serially, and these numbers are used for reference in the index. Major English-language sources of critical reviews are covered. Encyclopedic treatises, annual surveys such as Specialist Periodical Reports, and compilations of symposia proceedings are omitted. This installment of Recent Reviews covers principally the latter part of the 2005 literature. Previous installment: J. Org. Chem. 2006, 71(1), 438-47. Supporting Information Available: A file containing this Recent Review compilation in Microsoft Word and the data in plain text that can be imported into Endnote (using Refer style) and Reference Manager databases. This material is available free of charge via the Internet at http://pubs.acs.org.

Regularly Issued Journals and Series Volumes Accounts of Chemical Research 1. Hazari, N.; Mountford, P. Reactions and Applications of Titanium Imido Complexes. 2005, 38(11), 839-49. 2. Taylor, R. J. K.; Reid, M.; Foot, J.; Raw, S. A. Tandem Oxidation Processes Using Manganese Dioxide: Discovery, Applications, and Current Studies. 2005, 38(11), 851-69. Advances in Carbohydrate Chemistry and Biochemistry 3. Garegg, P. J. Synthesis and Reactions of Glycosides. 2004, 59, 69-134. 4. El Khadem, H. S.; Fatiadi, A. J. Hydrazine Derivatives of Carba Sugars and Related Compounds. 2004, 59, 135-73.

11. Muniz, K. Bifunctional Metal-Ligand Catalysis: Hydrogenations and New Reactions within the Metal-(Di)Amine Scaffold. 2005, 44(41), 6622-7. 12. Trost, B. M.; Frederiksen, M. U.; Rudd, M. T. RutheniumCatalyzed Reactions - A Treasure Trove of Atom-Economic Transformations. 2005, 44(41), 6630-66. 13. Tidwell, T. T. Catalytic Asymmetric Esterification of Ketenes. 2005, 44(42), 6812-4. 14. Breit, B. Supramolecular Approaches to Generate Libraries of Chelating Bidentate Ligands for Homogeneous Catalysis. 2005, 44(42), 6816-25. 15. Astruc, D.; Lu, F.; Aranzaes, J. R. Nanoparticles as Recyclable Catalysts. The Frontier between Homogeneous and Heterogeneous Catalysis. 2005, 44(48), 7852-72.

Angewandte Chemie, International Edition in English 5. Braun, T. Oxidative Addition of NH3 to a Transition-Metal Complex: A Key Step for the Metal-Mediated Derivatization of Ammonia? 2005, 44(32), 5012-4. 6. Sugiura, M.; Kobayashi, S. N-Acylhydrazones as Versatile Electrophiles for the Synthesis of Nitrogen-Containing Compounds. 2005, 44(33), 5176-86. 7. Sanchez, L.; Martin, N.; Guldi, D. M. Hydrogen-Bonding Motifs in Fullerene Chemistry. 2005, 44(34), 5374-82. 8. Bringmann, G.; Mortimer, A. J. P.; Keller, P. A.; Gresser, M. J.; Garner, J.; Breuning, M. Atroposelective Synthesis of Axially Chiral Biaryl Compounds. 2005, 44(34), 5384-427. 9. Woodward, S. Organocopper for the Craftsman Cunning at His Trade. 2005, 44(35), 5560-2. 10. Najera, C.; Sansano, J. M. Catalytic Enantioselective 1,3Dipolar Cycloaddition Reaction of Azomethine Ylides and Alkenes: The Direct Strategy to Prepare Enantioenriched Highly Substituted Proline Derivatives. 2005, 44(39), 6272-6.

Canadian Journal of Chemistry 16. Chiou, W.-H.; Lee, S.-Y.; Ojima, I. Recent Advances in Cyclohydrocarbonylation Reactions. 2005, 83(6-7), 681-92. 17. Lin, I. J. B.; Vasam, C. S. Review of Gold(I) NHeterocyclic Carbenes. 2005, 83(6-7), 812-25. The Chemical Record 18. Breslow, R. Biomimetic Selectivity. 2001, 1(1), 3-11. 19. Chisholm, M. H. Factors Influencing the Reductive Cleavage of C-X Multiple Bonds in their Reactions with Metal-Metal Multiple Bonds (X ) C, N, O, S). 2001, 1(1), 12-23. 20. Noyori, R.; Suga, S.; Oka, H.; Kitamura, M. Self-and Nonself-Recognition of Chiral Catalysts: The Origin of Nonlinear Effects in the Amino-Alcohol Catalyzed Asymmetric Addition of Diorganozincs to Aldehydes. 2001, 1(2), 85-100. 10.1021/jo063302d CCC: $33.50 © 2006 American Chemical Society

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21. Yamada, H.; Shimizu, S.; Kobayashi, M. Hydratases Involved in Nitrile Conversion: Screening, Characterization and Application. 2001, 1(2), 152-61. 22. Miller, M. L.; Ojima, I. Chemistry and Chemical Biology of Taxane Anticancer Agents. 2001, 1(3), 195-211. 23. Scott, A. I. Reflections on the Discovery of Nature’s Pathways to Vitamin B12. 2001, 1(3), 212-27. 24. Paquette, L. A. The Sclerophytin A Adventure. 2001, 1(4), 311-20. 25. Soai, K.; Sato, I.; Shibata, T. Asymmetric Autocatalysis and the Origin of Chiral Homogeneity in Organic Compounds. 2001, 1(4), 321-32. 26. Seino, H.; Mizobe, Y.; Hidai, M. Transformation of Organic Molecules on the Low-Valent [M(Ph2PCH2CH2PPh2)2] Moiety Derived from Trans-[M(N2)2(Ph2PCH2CH2PPh2)2] or Related Complexes M ) Mo, W). 2001, 1(5), 349-61. 27. Kim, S. Consecutive Carbon-Carbon Bond Formation Approach in Tandem Cyclization Reactions. 2001, 1(6), 41521. 28. Balzani, V.; Credi, A. Artificial Molecular-Level Machines. 2001, 1(6), 422-35. 29. Tundo, P.; Perosa, A. Green Organic Syntheses: Organic Carbonates as Methylating Agents. 2002, 2(1), 13-23. 30. Tokuyama, H.; Fukuyama, T. Indole Synthesis by Radical Cyclization of o-Alkenylphenyl Isocyanides and Its Application to the Total Synthesis of Natural Products. 2002, 2(1), 37-45. 31. Ichimura, K. Nonlinear Organic Reactions to Proliferate Acidic and Basic Molecules and Their Applications. 2002, 2(1), 46-55. 32. Tasler, S.; Bringmann, G. Biarylic Biscarbazole Alkaloids: Occurrence, Stereochemistry, Synthesis, and Bioactivity. 2002, 2(2), 114-26. 33. Ishibashi, H.; Ishihara, K.; Yamamoto, H. Chiral Proton Donor Reagents: Tin Tetrachloride-Coordinated Optically Active Binaphthol Derivatives. 2002, 2(3), 177-88. 34. Nielsen, M. B.; Diederich, F. The Art of Acetylenic Scaffolding: Rings, Rods, and Switches. 2002, 2(3), 189-98. 35. Itami, K.; Yoshida, J.-I. The Use of Hydrophilic Groups in Aqueous Organic Reactions. 2002, 2(4), 213-24. 36. Ryu, I. New Approaches in Radical Carbonylation Chemistry: Fluorous Applications and Designed Tandem Processes by Species-Hybridization with Anions and Transition Metal Species. 2002, 2(4), 249-58. 37. Kitamura, M.; Narasaka, K. Synthesis of Aza-Heterocycles from Oximes by Amino-Heck Reaction. 2002, 2(4), 26877. 38. Ogino, H. Synthesis of Silylene and Silyl(Silylene)Metal Complexes. 2002, 2(5), 291-306. 39. Ley, S. V.; Baxendale, I. R. Organic Synthesis in a Changing World. 2002, 2(6), 377-88. 40. Duncan, A. P.; Bergman, R. G. Selective Transformations of Organic Compounds by Imidozirconocene Complexes. 2002, 2(6), 431-45. 41. Verma, S.; Jager, S.; Thum, O.; Famulok, M. Functional Tuning of Nucleic Acids by Chemical Modifications: Tailored Oligonucleotides as Drugs, Devices, and Diagnostics. 2003, 3(1), 51-60. 42. Murahashi, T.; Ogoshi, S.; Kurosawa, H. New Direction in Organopalladium Chemistry: Structure and Reactivity of Unsaturated Hydrocarbon Ligands Bound to Multipalladium Units. 2003, 3(2), 101-11.

43. Wakatsuki, Y.; Hou, Z.; Tokunaga, M. New Reactions of 1-Alkynes Catalyzed by Transition Metal Complexes. 2003, 3(3), 144-57. 44. Nagasawa, K.; Hashimoto, Y. Synthesis of Marine Guanidine Alkaloids and Their Application as Chemical/ Biological Tools. 2003, 3(4), 201-11. 45. Schreiner, P. R.; Fokin, A. A. Selective Alkane C-HBond Functionalizations Utilizing Oxidative Single-Electron Transfer and Organocatalysis. 2004, 3(5), 247-57. 46. Mulzer, J.; Martin, H. J. Lessons Learned from Macrolide Synthesis. 2004, 3(5), 258-70. 47. Ishiyama, T.; Miyaura, N. Metal-Catalyzed Reactions of Diborons for Synthesis of Organoboron Compounds. 2004, 3(5), 271-80. 48. Satoh, T. Development of New Synthetic Methods with Aryl 1-Chlorovinyl Sulfoxides. 2004, 3(6), 329-41. 49. Gottarelli, G.; Spada, G. P. The Stepwise Supramolecular Organization of Guanosine Derivatives. 2004, 4(1), 39-49. 50. Doetz, K. H.; Jahr, H. C. Tunable Haptotropic Metal Migration in Fused Arenes: Towards Organometallic Switches. 2004, 4(2), 61-71. 51. Irie, R.; Katsuki, T. Selective Aerobic Oxidation of Hydroxy Compounds Catalyzed by Photoactivated RutheniumSalen Complexes (Selective Catalytic Aerobic Oxidation). 2004, 4(2), 96-109. 52. Fujita, K.; Yorimitsu, H.; Oshima, K. Innovative Reactions Mediated by Zirconocene. 2004, 4(2), 110-19. 53. Hamashima, Y.; Sodeoka, M. Development of Catalytic Asymmetric Reactions Via Chiral Palladium Enolates. 2004, 4(4), 231-42. 54. Kira, M.; Ishida, S.; Iwamoto, T. Comparative Chemistry of Isolable Divalent Compounds of Silicon, Germanium, and Tin. 2004, 4(4), 243-53. 55. Kita, Y.; Akai, S. 1-Alkoxyvinyl Esters: Renaissance of Half-Century-Old Acyl Donors with Potential Applicability. 2005, 4(6), 363-72. 56. Studer, A.; Schulte, T. Nitroxide-Mediated Radical Processes. 2005, 5(1), 27-35. 57. Cossy, J. Selective Methodologies for the Synthesis of Biologically Active Piperidinic Compounds. 2005, 5(2), 7080. 58. Tsuji, Y.; Richard, J. P. Reactions of Ion-Pair Intermediates of Solvolysis. 2005, 5(2), 94-106. 59. Zafra, F. The Surface Chemistry of Heterogeneous Catalysis: Mechanisms, Selectivity, and Active Sites. 2005, 5(3), 133-44. Chemical Reviews 60. Balaban, A. T.; Schleyer, P. v. R.; Rzepa, H. S. Crocker, Not Armit and Robinson, Begat the Six Aromatic Electrons. 2005, 105(10), 3436-47. 61. Rzepa, H. S. Moebius Aromaticity and Delocalization. 2005, 105(10), 3697-715. 62. Chen, Z.; Wannere, C. S.; Corminboeuf, C.; Puchta, R.; Schleyer, P. v. R. Nucleus-Independent Chemical Shifts (NICS) as an Aromaticity Criterion. 2005, 105(10), 3842-88. 63. Petrini, M. R-Amido Sulfones as Stable Precursors of Reactive N-Acylimino Derivatives. 2005, 105(11), 3949-77. 64. Garrison, J. C.; Youngs, W. J. Ag(I) N-Heterocyclic Carbene Complexes: Synthesis, Structure, and Application. 2005, 105(11), 3978-4008. J. Org. Chem, Vol. 71, No. 7, 2006 2927

65. Yeung, K.-S.; Paterson, I. Advances in the Total Synthesis of Biologically Important Marine Macrolides. 2005, 105(12), 4237-313. 66. Nakata, T. Total Synthesis of Marine Polycyclic Ethers. 2005, 105(12), 4314-47. 67. Kang, E. J.; Lee, E. Total Synthesis of Oxacyclic Macrodiolide Natural Products. 2005, 105(12), 4348-78. 68. Inoue, M. Convergent Strategies for Syntheses of transFused Polycyclic Ethers. 2005, 105(12), 4379-405. 69. Hamada, Y.; Shioiri, T. Recent Progress of the Synthetic Studies of Biologically Active Marine Cyclic Peptides and Depsipeptides. 2005, 105(12), 4441-82. 70. Clive, D. L. J.; Yu, M.; Wang, J.; Yeh, V. S. C.; Kang, S. Synthetic Chemistry of Halichlorine and the Pinnaic Acids. 2005, 105(12), 4483-514. 71. Miyashita, K.; Imanishi, T. Syntheses of Natural Products Having an Epoxyquinone Structure. 2005, 105(12), 4515-36. 72. Kang, S. H.; Kang, S. Y.; Lee, H.-S.; Buglass, A. J. Total Synthesis of Natural tert-Alkylamino Hydroxy Carboxylic Acids. 2005, 105(12), 4537-58. 73. Welzel, P. Syntheses Around the Transglycosylation Step in Peptidoglycan Biosynthesis. 2005, 105(12), 4610-60. 74. Kuwajima, I.; Tanino, K. Total Synthesis of Ingenol. 2005, 105(12), 4661-70. 75. Chen, F.-E.; Huang, J. Reserpine. A Challenge for Total Synthesis of Natural Products. 2005, 105(12), 4671-706. 76. Tatsuta, K.; Hosokawa, S. Total Synthesis of Selected Bioactive Natural Products: Illustration of Strategy and Design. 2005, 105(12), 4707-29. 77. Takao, K.; Munakata, R.; Tadano, K. Recent Advances in Natural Product Synthesis by Using Intramolecular DielsAlder Reactions. 2005, 105(12), 4779-807. 78. Pachamuthu, K.; Schmidt, R. R. Synthetic Routes to Thiooligosaccharides and Thio-glycopeptides. 2006, 106(1), 16087. 79. Cooks, R. G.; Chen, H.; Eberlin, M. N.; Zheng, X.; Tao, W. A. Polar Acetalization and Transacetalization in the Gas Phase: The Eberlin Reaction. 2006, 106(1), 188-211. Chemical Society Reviews 80. Jimenez, M. C.; Miranda, M. A.; Tormos, R. Proton, Electron and Energy Transfer Processes in Excited PhenolOlefin Dyads. 2005, 34(9), 783-96. 81. Gowenlock, B. G.; Richter-Addo, G. B. Dinitroso and Polynitroso Compounds. 2005, 34(9), 797-809. 82. Leca, D.; Fensterbank, L.; Lacote, E.; Malacria, M. Recent Advances in the Use of Phosphorus-Centered Radicals in Organic Chemistry. 2005, 34(10), 858-65. 83. Barbero, A.; Pulido, F. J. Allylstannanes and Vinylstannanes from Stannylcupration of C-C Multiple Bonds. Recent Advances and Applications in Organic Synthesis. 2005, 34(11), 913-20. 84. Kiselyov, A. S. Chemistry of N-Fluoropyridinium Salts. 2005, 34(12), 1031-7. 85. Peruzzini, M.; Gonsalvi, L.; Romerosa, A. Coordination Chemistry and Functionalization of White Phosphorus Via Transition Metal Complexes. 2005, 34(12), 1038-47.

87. Blacker, J. Commercial Catalysts. 2005, (12), 22-5. Chemistry - A European Journal 88. Zhang, Q.; Curran, D. P. Quasienantiomers and Quasiracemates: New Tools for Identification, Analysis, Separation, and Synthesis of Enantiomers. 2005, 11(17), 4866-80. 89. Long, Y.-T.; Abu-Irhayem, E.; Kraatz, H.-B. Peptide Electron Transfer: More Questions Than Answers. 2005, 11(18), 5186-94. 90. Gouverneur, V.; Reiter, M. Biocatalytic Approaches to Hetero-Diels-Alder Adducts of Carbonyl Compounds. 2005, 11(20), 5806-15. 91. Maifeld, S. V.; Lee, D. Group-Selective Ring-Closing Enyne Metathesis. 2005, 11(21), 6118-26. 92. Braunschweig, H.; Whittell, G. R. Boron as a Bridging Ligand. 2005, 11(21), 6128-33. Chemistry of Heterocyclic Compounds 93. Marinicheva, G. E.; Gubina, T. I. 4,7-Dihydro-, 4,5,6,7Tetrahydro-, and Octahydroisoindoles (and Methanoisoindoles). 2004, 40(12), 1517-35. 94. Batenko, N. G.; Karlivans, G.; Valters, R. Methods for the Synthesis of Heteroaryl-Substituted 1,4-Benzo- and 1,4Naphthoquinones. 2005, 41(6), 691-717. CHEMTRACTS: Organic Chemistry 95. Berry, C. R.; Hsung, R. P. Syntheses and Stereoselective 1,2-Addition Reactions of Chiral Stannyl Allenamides. 2004, 17(8), 409-15. 96. Schall, A.; Reiser, O. Tandem Epoxidation/Stereoselective Intramolecular [4+3] Cycloaddition Reaction. 2004, 17(8), 436-41. 97. Zhang, Y.; Hsung, R. P. Transition Metal-Catalyzed [2+2+2] Cycloadditions with Ynamides. 2004, 17(8), 44250. 98. Kellogg, R. M. Transition-Metal-Free Suzuki-Type Coupling Reactions. 2004, 17(8), 451-5. 99. Zanardi, F.; Appendino, G.; Casiraghi, G. The Synthesis of the Anti-Malarial Natural Product Polysphorin and Analogues using Polymer-Supported Reagents and Scavengers. 2004, 17(11), 587-92. 100. O’Doherty, G. A.; Zhou, M. Stereocontrolled Total Synthesis of (+)-Streptazolin. 2004, 17(11), 593-9. 101. Yamada, T.; Ikeno, T. Chiral Broensted Acid-Catalyzed Mannich-Type Reaction. 2004, 17(11), 616-9. 102. Appendino, G.; Prosperini, S.; Zanardi, F.; Casiraghi, G. The Synthesis of the Thapsigargins. 2004, 17(11), 627-37. Chirality 103. Bortolini, O.; Fantin, G.; Fogagnolo, M. Bile Acid Derivatives as Enantiodifferentiating Host Molecules in Inclusion Processes. 2005, 17(3), 121-30. 104. Uccello-Barretta, G.; Balzano, F.; Salvadori, P. Rationalization of the Multireceptorial Character of Chiral Solvating Agents Based on Quinine and Its Derivatives: Overview of Selected NMR Investigations. 2005, 17(Suppl.), S243-8. Coordination Chemistry Reviews

Chemistry and Industry 86. May, O.; Groeger, H. Designer Organisms. 2005, (9), 21-2. 2928 J. Org. Chem., Vol. 71, No. 7, 2006

105. Gottfriedsen, J.; Edelmann, F. T. Lanthanides and Actinides: Annual Survey of Their Organometallic Chemistry Covering the Year 1999. 2005, 249(9-10), 919-69.

106. Wong, W.-Y. Metalated Molecular Materials of Fluorene Derivatives and Their Analogues. 2005, 249(9-10), 971-97. 107. Herndon, J. W. The Chemistry of the Carbon-Transition Metal Double and Triple Bond: Annual Survey Covering the Year 2003. 2005, 249(9-10), 999-1083. 108. Vicente, J.; Arcas, A. Aqua Palladium Complexes: Synthesis, Properties and Applications. 2005, 249(11-12), 1135-54. 109. Lewinski, J.; Zachara, J.; Justyniak, I.; Dranka, M. Hydrogen-Bond Supramolecular Structure of Group 13 Schiff Base Complexes. 2005, 249(11-12), 1185-99. 110. Kirillov, E.; Saillard, J.-Y.; Carpentier, J.-F. Groups 2 and 3 Metal Complexes Incorporating Fluorenyl Ligands. 2005, 249(11-12), 1221-48. 111. Venkataramanan, N. S.; Kuppuraj, G.; Rajagopal, S. Metal-Salen Complexes as Efficient Catalysts for the Oxygenation of Heteroatom Containing Organic Compounds-Synthetic and Mechanistic Aspects. 2005, 249(11-12), 1249-68. 112. Schull, T. L.; Knight, D. A. Organometallic Phosphonic Acids: Synthesis and Coordination Chemistry. 2005, 249(1112), 1269-82. 113. Masarwa, A.; Rachmilovich-Calis, S.; Meyerstein, N.; Meyerstein, D. Oxidation of Organic Substrates in Aerated Aqueous Solutions by the Fenton Reagent. 2005, 249(17-18), 1937-43. 114. Trzeciak, A. M.; Ziolkowski, J. J. Structural and Mechanistic Studies of Pd-Catalyzed C-C Bond Formation: The Case of Carbonylation and Heck Reaction. 2005, 249(2122), 2308-22. Current Medicinal Chemistry 115. Rupprath, C.; Schumacher, T.; Elling, L. Nucleotide Deoxy Sugars: Essential Tools for the Glycosylation Engineering of Novel Bioactive Compounds. 2005, 12(14), 1637-75. 116. Dai, W.-M.; Guan, Y.; Jin, J. Structures and Total Syntheses of the Plecomacrolides. 2005, 12(17), 1947-93. 117. Sousa, M. E.; Pinto, M. M. M. Synthesis of Xanthones. An Overview. 2005, 12(21), 2447-79. Current Organic Chemistry 118. Botta, B.; Cassani, M.; D’Acquarica, I.; Subissati, D.; Zappia, G.; Delle Monache, G. Resorcarenes: Hollow Building Blocks for the Host-Guest Chemistry. 2005, 9(12), 1167-202. 119. Gandon, V.; Aubert, C.; Malacria, M. Cycloadditions, Cycloisomerizations and Related Reactions of Alkynes Bearing Group 13 or 14 Heteroelements. 2005, 9(17), 1699-712. 120. Guijarro, D.; Yus, M. The Favorskii Rearrangement: Synthetic Applications. 2005, 9(17), 1713-35. 121. Csende, F.; Stajer, G. Versatile Reactivity and Catalytic Effects of Copper(II) Halides in Organic Syntheses. 2005, 9(17), 1737-55. 122. Torres, M.; Gil, S.; Parra, M. New Synthetic Methods to 2-Pyridone Rings. 2005, 9(17), 1757-79. Current Organic Synthesis 123. Cipolla, L.; Peri, F.; La Ferla, B.; Redaelli, C.; Nicotra, F. Carbohydrate Scaffolds for the Production of Bioactive Compounds. 2005, 2(2), 153-73.

124. El Ashry, E. S. H.; Rashed, N.; Ibrahim, E. S. I. Strategies of Synthetic Methodologies for Constructing β-Mannosidic Linkage. 2005, 2(2), 175-213. 125. Schirrmacher, R.; Schirrmacher, E.; Muehlhausen, U.; Kaina, B.; Waengler, B. Synthetic Strategies Towards O6Substituted Guanine Derivatives and Their Application in Medicine. 2005, 2(2), 215-30. 126. Stratakis, M. Oxyfunctionalization of Alkenes by DyeSensitized Intrazeolite Photooxygenation. 2005, 2(2), 281-99. 127. Czarnocki, Z.; Siwicka, A.; Szawkalo, J. Selected Recent Advances in the Stereoselective Synthesis of Isoquinoline and β-Carboline Derivatives with the Use of Chiral Auxiliaries of Natural Origin. 2005, 2(3), 301-31. 128. Merino, P.; Tejero, T.; Delso, J. I.; Mannucci, V. Stereoselective Allylation Reactions of Imines and Related Compounds. 2005, 2(4), 479-98. 129. Ding, K.; Li, X.; Ji, B.; Guo, H.; Kitamura, M. Ten Years of Research on NOBIN Chemistry. 2005, 2(4), 499545. 130. Zhu, H. J.; Jiang, J. X.; Ren, J.; Yan, Y. M.; Pittman, C. U., Jr. Recently Developed Organometallic Complexes of Zn, Cu(Zn, Li), Fe, Ru and Less-Used Ions. Use in Selective 1,2-or 1,4-Additions, Transfer Hydrogenations, Aldol Reactions and Diels-Alder Reactions. 2005, 2(4), 547-87. European Journal of Organic Chemistry 131. Halton, B. The Fulvalenes. 2005, (16), 3391-414. 132. Escoubet, S.; Gastaldi, S.; Bertrand, M. Methods for the Cleavage of Allylic and Propargylic C-N Bonds in Amines and Amides - Selected Alternative Applications of the 1,3Hydrogen Shift. 2005, (18), 3855-73. 133. Luh, T.-Y.; Lee, C.-F. Dithioacetals as Zwitterion Synthons. 2005, (18), 3875-85. 134. Baudoin, O. The Asymmetric Suzuki Coupling Route to Axially Chiral Biaryls. 2005, (20), 4223-9. 135. Heber, D.; Roesner, P.; Tochtermann, W. Cyclooctyne and 4-Cyclooctyn-1-ol. Versatile Building Blocks in Organic Synthesis. 2005, (20), 4231-47. 136. Jaeckel, C.; Koksch, B. Fluorine in Peptide Design and Protein Engineering. 2005, (21), 4483-503. 137. Narasaka, K.; Kitamura, M. Amination with Oximes. 2005, (21), 4505-19. 138. Kotha, S.; Brahmachary, E.; Lahiri, K. Transition MetalCatalyzed [2+2+2] Cycloaddition and Application in Organic Synthesis. 2005, (22), 4741-67. 139. Kilroy, T. G.; O’Sullivan, T. P.; Guiry, P. J. Synthesis of Dihydrofurans Substituted in the 2-Position. 2005, (23), 4929-49. 140. Bock, V. D.; Hiemstra, H.; van Maarseveen, J. H. Cu(I)-Catalyzed Alkyne-Azide Click Cycloadditions from a Mechanistic and Synthetic Perspective. 2006, (1), 51-68. Heterocycles 141. McDermott, G.; Yoo, D. J.; Oelgemoller, M. Photochemical Addition Reactions Involving Phthalimides. 2005, 65(9), 2221-57. 142. Molteni, G. Stereoselective Cycloadditions of Nitrilimines as a Source of Enantiopure Heterocycles. 2005, 65(10), 2513-37. J. Org. Chem, Vol. 71, No. 7, 2006 2929

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Journal of Physical Organic Chemistry

158. Evans, W. J.; Kozimor, S. A.; Ziller, J. W. Molecular Octa-Uranium Rings with Alternating Nitride and Azide Bridges. 2005, 309(5742), 1835-8. 159. Dalgarno, S. J.; Tucker, S. A.; Bassil, D. B.; Atwood, J. L. Fluorescent Guest Molecules Report Ordered Inner Phase of Host Capsules in Solution. 2005, 309(5743), 2037-9. 160. Siegel, J. Inventing the Nanomolecular Wheel. 2005, 310(5745), 63-4. 161. Fletcher, S. P.; Dumur, F.; Pollard, M. M.; Feringa, B. L. A Reversible, Unidirectional Molecular Rotary Motor Driven by Chemical Energy. 2005, 310(5745), 80-2. 162. Mohammed, O. F.; Pines, D.; Dreyer, J.; Pines, E.; Nibbering, E. T. J. Sequential Proton-Transfer Through Water Bridges in Acid-Base Reactions. 2005, 310(5745), 83-6. 163. Frenking, G. Building a Quintuple Bond. 2005, 310(5749), 796-7. 164. Fischer, J.; Baumgartner, J.; Marschner, C. Synthesis and Structure of Sila-Adamantane. 2005, 310(5749), 825. 165. Nguyen, T.; Sutton, A. D.; Brynda, M.; Fettinger, J. C.; Long, G. J.; Power, P. P. Synthesis of a Stable Compound with Fivefold Bonding between Two Chromium(I) Centers. 2005, 310(5749), 844-7. 166. Sun, Z.-D.; Takagi, K.; Matsushima, F. Separation and Conversion Dynamics of Four Nuclear Spin Isomers of Ethylene. 2005, 310(5756), 1938-41.

149. Filarowski, A. Intramolecular Hydrogen Bonding in o-Hydroxyaryl Schiff Bases. 2005, 18(8), 686-98.

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143. Hultzsch, K. C.; Gribkov, D. V.; Hampel, F. NonMetallocene Rare Earth Metal Catalysts for the Diastereoselective and Enantioselective Hydroamination of Aminoalkenes. 2005, 690(20), 4441-52. 144. Nagy, A.; Novak, Z.; Kotschy, A. Sequential and Domino Sonogashira Coupling: Efficient Tools for the Synthesis of Diarylalkynes. 2005, 690(20), 4453-61. 145. Arisawa, M.; Terada, Y.; Theeraladanon, C.; Takahashi, K.; Nakagawa, M.; Nishida, A. Development of Novel Reactions using Ruthenium Carbene Catalyst and Its Application to Novel Methods for Preparing Nitrogen-Containing Heterocycles. 2005, 690(24-25), 5398-406. 146. Cavallo, L.; Correa, A.; Costabile, C.; Jacobsen, H. Steric and Electronic Effects in the Bonding of N-Heterocyclic Ligands to Transition Metals. 2005, 690(24-25), 5407-13. 147. Jones, N. D.; Cavell, R. G. Phosphorus-Substituted Carbene Complexes: Chelates, Pincers and Spirocycles. 2005, 690(24-25), 5485-96. 148. Wu, Y.-T.; Kurahashi, T.; De Meijere, A. Some Recent Applications of Fischer Carbene-Metal Complexes in Organic Synthesis. 2005, 690(24-25), 5900-11.

Organic Preparations and Procedures International 150. Synoradzki, L.; Ruskowski, P.; Bernas, U. Tartaric Acid and Its o-Acyl Derivatives. Part 1. Synthesis of Tartaric Acid and o-Acyl Tartaric Acids and Anhydrides. 2005, 37(1), 3763. Research on Chemical Intermediates 151. Palit, D. K. Photophysics and Excited-State Relaxation Dynamics of p-Hydroxy and p-Amino-Substituted Benzophenones: A Review. 2005, 31(1-3), 205-25. Russian Journal of Organic Chemistry 152. Zefirova, O. N.; Nurieva, E. V.; Ryzhov, A. N.; Zyk, N. V.; Zefirov, N. S. Taxol: Synthesis, Bioactive Conformations, and Structure-Activity Relationships in Its Analogs. 2005, 41(3), 315-51. 153. Koval, I. V. Synthesis, Structure, and Physicochemical Characteristics of Thiols. 2005, 41(5), 631-48. 154. Mamardashvili, N. Z.; Koifman, O. I. Porphyrin-Calix[4]arenes. 2005, 41(6), 787-806. Science 155. Ihee, H.; Lorenc, M.; Kim, T. K.; Kong, Q. Y.; Cammarata, M.; Lee, J. H.; Bratos, S.; Wulff, M. Ultrafast X-ray Diffraction of Transient Molecular Structures in Solution. 2005, 309(5738), 1223-7. 156. Burns, C. J. Bridging a Gap in Actinide Chemistry. 2005, 309(5742), 1823-4. 157. Stahl, S. S. Palladium-Catalyzed Oxidation of Organic Chemicals with O2. 2005, 309(5742), 1824-6. 2930 J. Org. Chem., Vol. 71, No. 7, 2006

167. Baldoli, C.; Cerea, P.; Giannini, C.; Licandro, E.; Rigamonti, C.; Maiorana, S. The Metal-Conjugated Peptide Nucleic Acid Challenge. 2005, (13), 1984-94. 168. Iwamatsu, S.-i.; Murata, S. Open-Cage Fullerenes: Synthesis, Structure, and Molecular Encapsulation. 2005, (14), 2117-29. 169. Nair, V.; Dhanya, R.; Rajesh, C.; Devipriya, S. Recent Developments in the Chemistry of Quinonimides. 2005, (16), 2407-19. 170. Laschat, S.; Becheanu, A.; Bell, T.; Baro, A. Regioselectivity, Stereoselectivity and Catalysis in Intermolecular Pauson-Khand Reactions: Teaching an Old Dog New Tricks. 2005, (17), 2547-70. 171. Osborn, H. M. I. Development of New Methodologies for Entry to Targets of Therapeutic Interest. 2005, (17), 257186. 172. Mondal, M. Sodium Methylsulfinylmethylide: A Versatile Reagent. 2005, (17), 2697-8. 173. Mulamoottil, V. A. Bismuth(III) Nitrate Pentahydrate - A Versatile Reagent in Organic Synthesis. 2005, (17), 2699700. 174. Rilatt, I.; Caggiano, L.; Jackson, R. F. W. Development and Applications of Amino Acid Derived Organometallics. 2005, (18), 2701-19. 175. Tang, Y.; Ye, S.; Sun, X.-L. Telluronium and Sulfonium Ylides for Organic Transformation. 2005, (18), 2720-30. 176. Agnihotri, G. Chloramine-T (Sodium N-Chloro-pToluenesulfonamide). 2005, (18), 2857-8. SynthesissStuttgart 177. Goldfuss, B. Organolithiums in Enantioselective Additions to π* and σ* Carbon-Oxygen Electrophiles. 2005, (14), 2271-80.

178. Plietker, B. Selectivity Versus Reactivity - Recent Advances in RuO4-Catalyzed Oxidations. 2005, (15), 245372. 179. Olsen, C. A.; Franzyk, H.; Jaroszewski, J. W. NAlkylation Reactions and Indirect Formation of Amino Functionalities in Solid-Phase Synthesis. 2005, (16), 2631-53. 180. Ding, H.; Friestad, G. K. Asymmetric Addition of Allylic Nucleophiles to Imino Compounds. 2005, (17), 2815-29. 181. Frieman, B. A.; Taft, B. R.; Lee, C.-T.; Butler, T.; Lipshutz, B. H. Nickel-in-Charcoal (Ni/C): An Efficient Heterogeneous Catalyst for the Construction of C-C, C-N, and C-H Bonds. 2005, (17), 2989-93. 182. Kar, A.; Argade, N. P. A Concise Account of Recent SN2′ Grignard Coupling Reactions in Organic Synthesis. 2005, (18), 2995-3022. Tetrahedron 183. Pihko, A. J.; Koskinen, A. M. P. Synthesis of PropellaneContaining Natural Products. 2005, 61(37), 8769-807. 184. Singh, V.; Iyer, S. R.; Pal, S. Recent Approaches Towards Synthesis of Cis-Decalins. 2005, 61(39), 9197-231. 185. Piggott, M. J. Naphtho[2,3-c]furan-4,9-diones and Related Compounds: Theoretically Interesting and Bioactive Natural and Synthetic Products. 2005, 61(42), 9929-54. 186. Connolly, D. J.; Cusack, D.; O’Sullivan, T. P.; Guiry, P. J. Synthesis of Quinazolinones and Quinazolines. 2005, 61(43), 10153-202. 187. Srikanth, G. S. C.; Castle, S. L. Advances in Radical Conjugate Additions. 2005, 61(44), 10377-441. 188. Majumdar, K. C.; Basu, P. K.; Mukhopadhyay, P. P. Formation of Five- and Six-Membered Heterocyclic Rings under Radical Cyclization Conditions. 2005, 61(45), 10603-42.

189. Montalbetti, C. A. G. N.; Falque, V. Amide Bond Formation and Peptide Coupling. 2005, 61(46), 10827-52. 190. Ozturk, T.; Ertas, E.; Mert, O. Dithienothiophenes. 2005, 61(47), 11055-77. 191. McAllister, L. A.; McCormick, R. A.; Procter, D. J. Sulfide- and Selenide-Based Linkers in Phase Tag-Assisted Synthesis. 2005, 61(49), 11527-76. 192. Alonso, F.; Beletskaya, I. P.; Yus, M. Non-Conventional Methodologies for Transition-Metal Catalyzed Carbon-Carbon Coupling: A Critical Overview. Part 1: The Heck Reaction. 2005, 61(50), 11771-835. Tetrahedron: Asymmetry 193. Davies, S. G.; Smith, A. D.; Price, P. D. The Conjugate Addition of Enantiomerically Pure Lithium Amides as Homochiral Ammonia Equivalents: Scope, Limitations and Synthetic Applications. 2005, 16(17), 2833-91. 194. Kolodiazhnyi, O. I. Asymmetric Synthesis of Hydroxyphosphonates. 2005, 16(20), 3295-340. Topics in Current Chemistry 195. Niyomura, O.; Kato, S. Chalcogenocarboxylic Acids. 2005, 251(Chalcogenocarboxylic Acid Derivatives), 1-12. 196. Toda, F. Thermal and Photochemical Reactions in the Solid State. 2005, 254(Organic Solid State Reactions), 1-40. 197. Komatsu, K. The Mechanochemical Solid-State Reaction of Fullerenes. 2005, 254, 185-206. 198. Sakamoto, M. Photochemical Aspects of Thiocarbonyl Compounds in the Solid-State. 2005, 254, 207-32.

Monographs 199. Antonovsky, V. L., Kasaikina, A. T., Zaikov, G. E., Eds. Peroxides at the Beginning of the Third Millennium: Synthesis, Properties, Application. Nova Science Publishers, Hauppauge, NY, 2005. 200. Baeckvall, J.-E., Ed. Modern Oxidation Methods. WileyVCH Verlag: Weinheim, Germany, 2004. 201. Balkose, D., Zaikov, G. E., Eds. Modern Advances in Organic and Inorganic Chemistry. Nova Science: Hauppauge, NY, 2005. 202. Beller, M., Bolm, C., Eds. Transition Metals for Organic Synthesis: Building Blocks and Fine Chemicals. Second Revised and Enlarged Edition, Volume 2. Wiley-VCH: Weinheim, Germany, 2004. 203. Cepanec, I., Ed. Synthesis of Biaryls. Elsevier: Amsterdam, Netherlands, 2004. 204. Charette, A. B., Thomas, E. J., Eds. Compounds with Four and Three Carbon-Heteroatom Bonds: Thio-, Seleno-, and Tellurocarboxylic Acids and Derivatives; Imidic Acids and Derivatives; Ortho Acid Derivatives, Volume 22. [In; Sci. Synth.; 2005, 22]. Georg Thieme Verlag: Stuttgart, Germany, 2005. 205. Costisor, O., Linert, W., Eds. Metal Mediated Template Synthesis of Ligands. World Scientific: Singapore, 2004. 206. Davies, A. G. Organotin Chemistry, Second, Completely Revised and Updated Edition. John Wiley & Sons: Chichester, U.K., 2004.

207. Frenking, G., Ed. Theoretical Aspects of Transition Metal Catalysis. [In: Top. Organomet. Chem.; 2005, 12]. Springer: Berlin, Germany, 2005. 208. Gladysz, J. A., Curran, D. P., Horvath, I. T., Eds. Handbook of Fluorous Chemistry. Wiley-VCH: Weinheim, Germany, 2004. 209. Hanson, J. R. Organic Synthetic Methods: Basic Concepts in Chemistry. Wiley: New York, 2003. 210. Juaristi, E., Soloshonok, V. A., Eds. Enantioselective Synthesis of β-Amino Acids, Second Edition. John Wiley & Sons: Hoboken, NJ, 2005. 211. Kaloustian, M. K., Ed. Concepts and Terminology in Organic Stereochemistry. Elsevier: Amsterdam, Netherlands, 2004. 212. Krchnak, V.; Burritt, A. Chemical Combinatorial Methods. Blackwell: Oxford, U.K., 2003. 213. Marek, I., Ed. New Aspects of Zirconium Containing Organic Compounds. [In: Top. Organomet. Chem.; 2005, 10]. Springer: Berlin, Germany, 2005. 214. Murahashi, S.-I., Ed. Ruthenium in Organic Synthesis. Wiley-VCH: Weinheim, Germany, 2004. 215. Overman, L. E., Ed. Organic Reactions, Volume 66. John Wiley & Sons: Hoboken, NJ, 2005. 216. Pirrung, M., Ed. Molecular Diversity and Combinatorial J. Org. Chem, Vol. 71, No. 7, 2006 2931

Chemistry, Volume 24: Principles and Applications. Elsevier: Amsterdam, Netherlands, 2004. 217. Ramberg, P. J. Chemical Structure, Spatial Arrangement: The Early History of Stereochemistry, 1874-1914. Ashgate: Aldershot, U.K., 2003. 218. Takemura, H., Ed. New Trends in Structural Organic Chemistry, 2005. Research Signpost: Trivandrum, India, 2005. 219. Trepalin, S.; Yarkov, A. Proton NMR of Organic Compounds, Volume 3. Wiley: New York, 2004. 220. Tsuji, J., Ed. Palladium in Organic Synthesis. [In: Top. Organomet. Chem.; 2005, 14]. Vol. 14. Springer: Berlin, Germany, 2005. 221. Vorbrueggen, H. Silicon-Mediated Transformation of Functional Groups. John Wiley & Sons: Chichester, U.K., 2004.

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222. Wales, D. J., Ed. Intermolecular Forces and Clusters I. [In: Struct. Bonding.; 2005, 115]. Springer: Berlin, Germany, 2005. 223. Weinreb, S. M., Ed. Compounds with Four and Three Carbon-Heteroatom Bonds: Three Carbon-Heteroatom Bonds: Amides and Derivatives; Peptides; Lactams. [In: Sci. Synth.; 2005, 21]. Georg Thieme Verlag: Stuttart, Germany, 2005. 224. Williams, L., Ed. Nitrosation Reactions and the Chemistry of Nitric Oxide. Elsevier: Amsterdam, The Netherlands, 2004. 225. Zaikov, G. E., Ed. Chemistry of Polysaccharides. VSP: Leiden, The Netherlands, 2005. 226. Zaikov, G. E., Zaikov, V. G., Eds. Method and Theory in Physical Organic Chemistry. Nova Science: Hauppauge, NY, 2005.

Index Acetalization, polar, gas phase, 79 Acetylene, macrocycles, 34 oligomers, 34 tetraethynylethene, 34 Acid amplifiers, sulfonates, 31 Actinides, 156 organometallic, 105 Acylhydrazones, N-, electrophiles, 6 Acylimino derivatives, 63 Adamantane, silane-, 164 Aldehydes, diorganozinc addition, 20 Alkaloids, biaryl, biscarbazole, 32 Via intramolecular Diels-Alder reaction, 77 yohimbine, 75 Alkanes, metathesis, 45 with dioxiranes, 45 Alkenes, borylation, 47 oxyfunctionalization, zeolites, 126 radical conjugate additions, 187 Alkenylphenyl isocyanides, radical cyclization, 30 Alkoxyvinyl esters, 55 Alkyne-azide cycloaddition, 140 Alkynes, group 13 or 14, cycloaddition, 119 group 13 or 14, cycloisomerization, 119 with lanthanide complexes, 43 with Ru complexes, 43 Allenamides, stannyl, chiral, 95 Allenes, polysubstituted, 133 Allylic amination, with chloramine-T, 176 Allylic substitution, SN2′ Grignard coupling, 182 Allylorganostannanes, 83 Amides, 3-C-heteroatom bonds, 223 allylic C-N cleavage, 132 bond formation, 189 Amido sulfones, 63 Amidocarbonylation, 16 Amination, with oximes, 137 Amines, allylic C-N cleavage, 132 transition metal bifunctional catalyst, 11 Amino acids, non-natural, 174 R-, chiral, synthesis, 86 β, enantioselective, book, 210 Aminoalkenes, hydroamination, 143 Aminocarbonylation, intramolecular, 16 Aminochalcogenation, with chloramine-T, 176 Amino-Heck reaction, 37 Aminohydroxybinaphthyls (NOBIN), 129 Aminohydroxylation, with chloramine-T, 176 Ammonia addition, 5, 193 Ammonia derivatization, 5 Antibiotics, synthesis, 115 Anticancer agents, taxanes, 22, 152 Antileukemia agents, sclerophytin A, 24 Anti-malarial agents, polysphorin, 99 Anti-melanoma drugs, 171 Antitumor agents, 2-pyridones, 122 Antiviral agents, 2-pyridones, 122 Arene oxidation, book, 215 Arenes, fused, metal migration, 50

Aromatic electrons, 60 Aromaticity, nucleus independent chemical shifts, 62 Aromatics, Moebius, 61 Aryl-aryl coupling, stereoselective, 8 Arylchlorovinyl sulfoxides, 48 Asymmetric synthesis, 130 Autocatalysis, asymmetric, 25 Aza-azulenes, from oximes, with Pd, 37 Aza-heterocycles, from oximes, aminoHeck reaction, 37 Aziridination, with chloramine-T, 176 Azomethine ylides, 1,3-dipolar cycloaddition, 10 Base amplifiers, carbamates, 31 Benzophenones, photochemistry, 151 Benzoquinones, heteroaryl, 94 Biaryls, axially chiral, 8, 134 synthesis, book, 203 Via Ullman reaction, 215 Bile acids, molecular recognition, 103 Biomimetics, 18 Biosensors, nucleic acids, 41 Bismuth(III) nitrate pentahydrate, 173 Boron, bridging ligands, 92 Borylation, 47 Bronsted acid-base proton-transfer mechanism, 162 Carbenes, phosphorus-, 147 Carbohydrate templates, 123 combinatorial chemistry, 123 therapeutic, synthesis, 171 Carbon-transition metal multiple bond, 107 Carbonylation, Pd catalysts, 114 Carboxylic acids, chalcogen-, 195, 204 β-amino-, 193 Catalysts, nickel-in-charcoal, 181 recyclable nanoparticles, 15 semi-heterogeneous, 15 Chelates, P-carbenes, 147 Chloramine-T, 176 C-N bond, cleavage, 132 Combinatorial chemistry, book, 216 methods, book, 212 Combinatorial homogeneous catalysis, 14 Condensation, Biginelli, book, 215 Copper halides, 121 C-X multiple bond activation, dimetals, 19 Cyanohydrin, asymmetric, synthesis, 87 Cycloalkane hydrazones, 4 Cyclohydrocarbonylation, 16 Cyclooctanynol, 135 Cyclooctyne, 135 Cyclotrimerization, 138 Decalins, cis-, synthesis, 184 Diamido amine yttrium complexes, 143 Diarylalkynes, synthesis, 144 Dienynes, group selective ring closing metathesis, 91 Dihydrofurans, 2-substituted, 139 Dimethyl carbonates, methylating agent, 29 Dinitroso compounds, 81 Dithienothiophenes, 190 Dithioacetals, zwitterion synthons, 133 Eberlin reaction, 79 Enantioresolution, with bile acids, 103

Epothilone B synthesis, 46 Epoxyquinones, synthesis, 71 Ethers, polycyclic, trans-fused, 68 Ethylene, nuclear spin isomers, 166 Favorskii rearrangement, 120 Fenton reaction, organic oxidation, 113 Fischer carbene-metal complexes, 148 Fluoenyl, groups 2 and 3 complexes, 110 Fluorenes, substituted, 106 Fluorine, peptide synthesis, 136 Fluoropyridinium salts, N-, 84 Fluorous chemistry, book, 208 Fullerenes, open-cage, 168 solid-state reaction, 197 supramolecules, 7 Fulvalenes, 131 Furans, trisubstituted, 133 Glucosides, epimerization, 124 Glycolipids, synthesis, 73 Glycopeptides, synthesis, 73 Glycosidase inhibitors, 171 Glycosides, 3 Gold(I) N-heterocyclic carbenes, 17 Grignard coupling, SN2′, 182 Group 13 supramolecular Schiff base complexes, 109 Guanine derivatives, O6-substituted, 125 Guanosines, supramolecules, 49 Halichlorine, synthesis, 70 Haloalkanes, transient intermediate detection, 155 Haptotropic isomerization, 50 Heck reaction, 192 Pd catalysis, 114 Heterocycles, 4,5-dihydropyrazole, 142 N-containing, Via Ru carbenes, 145 Via [2+2+2] cycloaddition, 138 Via radical cyclization, 188 Hetero-Diels-Alderases, 90 Heterogeneous catalysis, 59 Hydrazones, carba sugars, 4 Hydroamination, with Ti imides, 1 Hydrophilic groups, aqueous reactions, 35 Hydroxyaryl Schiff bases, 149 Hydroxyphosphonates, asymmetric synthesis, 194 Imidic acids, book, 204 Imidozirconocene complexes, 40 Imines, stereoselective allylation, 128 Imino compounds, allylic addition, 180 Indole alkaloids, reserpine, 75 Indoles, from alkenylphenyl isocyanides, 30 Ingenol, synthesis, 74 Intermolecular forces, clusters, 222 Isocyanides, activation, 26 Isoindoles, hydrogenated, 93 Isomerization, solvolysis, ion-pair intermediates, 58 Isoprene polymerization, book, 201 Isoprenoids, cyclization, biomimetic, 33 Isoquinoline derivatives, 127 from oximes, with Pd, 37 Ketenes, esterification, 13 Lactams, 3-C-heteroatom bonds, 223 Lanthanides, organometallic, 105 Laulimalide synthesis, 46 J. Org. Chem, Vol. 71, No. 7, 2006 2933

Lewis acid Bronsted acids (LBAs), chiral, 33 Ligands, bidentate, chelating, 14 bridging, boron, 92 N-heterocyclic, bonding, 146 synthesis, book, 205 zero-valent, 26 Lithium amides, homochiral, 193 Mannich-type reaction, with chiral Bronsted acids, 101 Mannosides, -β, 124 Marine cyclic peptides, synthesis, 69 Marine depsipeptides, synthesis, 69 Marine guanidine alkaloids, 44 Marine macrolides, synthesis, 65 Marine polycyclic ethers, synthesis, 66 Metallocenes, fluorenyl, groups 2 and 3, 110 Metallylenes, Si, Ge, Sn, isolable, 54 Metal-salen complexes, oxygenation catalysts, 111 Methanoisoindoles, hydrogenated, 93 Methylating agents, green, dimethyl carbonates, 29 Molecular hosts capsules, fluorescent probes, 159 Molecular machines, 28, 160 Molecular motors, 161 Nanomolecular wheel, 160 Naphthofuran diones, 185 quinazolinones, 186 Naphthoquinones, heteroaryl, 94 Natural product synthesis, bioactive molecules, 76 epoxyquinones, 71 intramolecular Diels Alder reaction, 77 oxacyclic macrodiolides, 67 propellanes, 183 tert-alkylamino hydroxy carboxylic acids, 72 Negishi catalysts, nickel-in-charcoal, 181 Nitric oxide, book, 224 Nitrile hydratases, 21 Nitrile, activation, 26 Nitrilimines, 1,3-dipolar cycloaddition, 142 Nitrosation, book, 224 Nitroxide radical polymerization, 56 NMR, proton-, book, 219 Nucleotide deoxy sugars, 115 Olefin polymerization, Ti imides, 1 Oligonuleotides, 41 Organoactinides, uranium nitrides, 158 Organoboron compounds, 47 Organochromium complexes, quintuple bonds, 163, 165 Organocopper, 1,4-conjugate additions, 9 SN2′ substitutions, 9 Organolithium, enantioselective addition to carbonyls, 177 enantioselective ether cleavage, 177 Organometallics, from amino acids, 174 phosphonic acids, 112 switches, 50

2934 J. Org. Chem., Vol. 71, No. 7, 2006

Organopalladium chemistry, 42 Organophosphorus ligands, white P, 85 Organophosphorus radicals, 82 Organotin, book, 206 Organozirconium compounds, book, 213 Oxidation, aerobic, catalyzed, 51 book, 200 with O2 and Pd, 157 Oxidative transformations, book, 215 Oximes, in aminations, 137 Palladium catalysis, 114 book, 220 Palladium enolates, chiral, 53 Palladium, aqua complexes, metallo-peptidases, 108 metallo-proteases, 108 Pauson-Khand reaction, intermolecular, 170 Pentadiene oligomerization, book, 201 Peptides, 3-C-heteroatom bonds, 223 coupling, 189 electron transfer, 89 nucleic acids, metal-, 167 Peptidoglycan biosynthesis, transglycosylation, 73 Peptidomimetics, carbohydrate skeleton, 123 Peroxides, book, 199 Phenol-olefin dyads, photochemistry, 80 Phthalimides, photochemical addition, 141 Physical organic chemistry, book, 226 Pincer complexes, P-carbenes, 147 Pinnaic acid, synthesis, 70 Piperidines, substituted, synthesis, 57 Plecomacrolides, 116 Polyamides, aliphatic-aromatic, degradation, book, 201 Polycycles, Via [2+2+2] cycloaddition, 138 Polyene cyclization, chiral Bronsted acids, 33 Polynitrosocompounds, 81 Polysaccharides, book, 225 Polyvinylchloride destruction, book, 201 Porphyrin-calix[4]arene, 154 Proline derivatives, synthesis, 10 Pyridone rings, 2-substituted, 122 Pyrroles, from oximes, with Pd, 37 Via dithioacetals, 133 Pyrrolinines, synthesis, 10 Quasienantiomers, 88 Quasiracemates, 88 Quinazolines, 186 Quinine, chiral solvating agents, NMR, 104 Quinonimides, 169 Radical carbonylation, fluorous tin reagents, 36 Reserpine, 75 Resorcarenes, 118 Ruthenium, book, 214 catalysis, 12 salen complexes, in oxidations, 51 Ruthenium oxide, in oxidations, 178 Selenide linkers, solid-phase synthesis, 191 Silicon-mediated transformations, book, 221

Silver N-heterocyclic carbenes, 64 Silyl(silylene) complexes, 38 Silylene complexes, 38 Sodium methylsulfinylmethylide, 172 Solid-phase synthesis, amino functionality, 179 Solid-state reactions, 196-8 photochemical, 196 thermal, 196 Solid-supported reagents, 39 Sonogashira coupling, 144 Spirocycles, P-carbenes, 147 Spiroimines, from oximes, with Pd, 37 Stereochemistry, book, 211 history, book, 217 Streptazolin, synthesis, 100 Structural organic chemistry, book, 218 Sulfide linkers, fluorous phase synthesis, 191 solid-phase synthesis, 191 Sulfonium ylides, 175 Suzuki catalysts, nickel-in-charcoal, 181 Suzuki-Miyaura coupling, aqueous, with microwaves, 98 Synthesis, book, 209 Tandem cyclization, consecutive C-C bonds, 27 Tandem epoxidation-[4+3]cycloaddition, 96 Tandem oxidation, with manganese dioxide, 2 Tartaric acids, acyl-, 150 Tartrolon B synthesis, 46 Tauropinnaic acid, synthesis, 70 Taxanes, 22 Taxol, 22, 152 Telluronium ylides, 175 Terpenoids, Via intramolecular Diels-Alder reaction, 77 Tetrahydroisoquinolines, 127 Tetrahydro-β-carboline, 127 Thapsigargins, synthesis, 102 Thiocarbonyls, solid-state photochemistry, 198 Thioglycopeptides, 78 Thioglycosides, 3 Thiols, 153 Thio-oligosaccharides, 78 Thio-sialosides, 78 Tin tetrachloride binaphthol, 33 Titanium imido complexes, 1 Transacetalization, polar, gas phase, 79 Transition metals, book, 202 catalysis, book, 207 Triazoles, 1,4-disubstituted, 140 Tyrosinase protecting groups, for amines, 171 Vinylorganostannanes, 83 Vitamin B12, biosynthesis, 23 Xanthones, synthesis, 117 Ynamides, cycloadditions, 97 Zirconocenes, 52 JO063302D