Ordovician Hydrocarbon Migration along the Tazhong No. 10 Fault

Jan 16, 2018 - Furthermore, later fracturing and dolomitisation with hydrothermal activity coupled to improve the physical properties of grain bank re...
1 downloads 9 Views 5MB Size
Subscriber access provided by Gothenburg University Library

Article

Ordovician hydrocarbon migration along the Tazhong No.10 fault belt in the Tazhong Uplift, Tarim Basin, northwest China Weibing Shen, Xiongqi Pang, Jianfa Chen, Ke Zhang, Zeya Chen, Zhaofu Gao, Guangping Luo, and Liwen He Energy Fuels, Just Accepted Manuscript • DOI: 10.1021/acs.energyfuels.7b03542 • Publication Date (Web): 16 Jan 2018 Downloaded from http://pubs.acs.org on January 16, 2018

Just Accepted “Just Accepted” manuscripts have been peer-reviewed and accepted for publication. They are posted online prior to technical editing, formatting for publication and author proofing. The American Chemical Society provides “Just Accepted” as a free service to the research community to expedite the dissemination of scientific material as soon as possible after acceptance. “Just Accepted” manuscripts appear in full in PDF format accompanied by an HTML abstract. “Just Accepted” manuscripts have been fully peer reviewed, but should not be considered the official version of record. They are accessible to all readers and citable by the Digital Object Identifier (DOI®). “Just Accepted” is an optional service offered to authors. Therefore, the “Just Accepted” Web site may not include all articles that will be published in the journal. After a manuscript is technically edited and formatted, it will be removed from the “Just Accepted” Web site and published as an ASAP article. Note that technical editing may introduce minor changes to the manuscript text and/or graphics which could affect content, and all legal disclaimers and ethical guidelines that apply to the journal pertain. ACS cannot be held responsible for errors or consequences arising from the use of information contained in these “Just Accepted” manuscripts.

Energy & Fuels is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Published by American Chemical Society. Copyright © American Chemical Society. However, no copyright claim is made to original U.S. Government works, or works produced by employees of any Commonwealth realm Crown government in the course of their duties.

Page 1 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

1

Ordovician hydrocarbon migration along the Tazhong No.10 fault belt in the

2

Tazhong Uplift, Tarim Basin, northwest China

3

Weibing Shen a*, Xiongqi Pang b, Jianfa Chen b, Ke Zhang c, Zeya Chen b, Zhaofu Gao a, Guangping Luo b, Liwen He b

4 5

a MLR Key Laboratory of Isotope Geology, Institute of Geology, Chinese Academy of Geological

6

Sciences, Beijing 100037, China

7

b State Key Laboratory of Petroleum Resources and Prospecting, China University of Petroleum,

8

Changping District, Beijing, 102249, China

9

c Research Institute of Exploration and Development, Tarim Oilfield Company, PetroChina, Korla,

10

Xinjiang, 84100, China

11

* Corresponding Author

12

E-mail: [email protected]

13

Phone number: +8615117973405

14

Present address: Chinese Academy of Geological Sciences, No. 26, Baiwanzhuang Road, Xicheng

15

district, Beijing, P. R. China, 100037

16 17

Abstract: The Ordovician hydrocarbon migration and accumulation of the Tazhong Uplift in the

18

Tarim Basin, northwest China, is investigated from the perspective of geological and geochemical

19

analysis. Geochemical parameters successfully analyzed include the oil and gas properties,

20

Ts/(Ts+Tm) ratios, and carbon isotope ratios of gas. Results show anomaly parameter values are

21

observed in the No.10 fault belt (10FB) and the No.1 fault belt (1FB). As the distance from the 10FB

22

and 1FB increases, the parameter value anomalies weak gradually until then become disappeared in

23

the north platform belt (NPB). This saddle-like distribution of parameters indicates the hydrocarbon

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

24

is introduced into the Ordovician through 10FB and 1FB from the northern Manjiaer Depression and

25

the uplift itself. This new conclusion is different from the conventional view to a large extent, which

26

indicates that Ordovician hydrocarbon mainly derive from the Manjiaer Depression and the No.1

27

fault is the only NW-trending oil source fault. The viewpoint of 10FB as an additional hydrocarbon

28

charge place is further supported by the evidence from the hydrocarbon charge intensity, structural

29

framework, source rock distribution, and significantly improvement of the reservoir physical

30

property (7~8 times at the 10FB). Based on this hydrocarbon charge and migration process and patter,

31

the main target for further exploration activities in the Ordovician of the Tazhong Uplift should be

32

the SPB (south platform belt) and the south part of the 10FB, especially the south part of the 10FB.

33

Abstract: Hydrocarbon migration; hydrocarbon accumulation; carbonate rock; carbon isotope ratio;

34

Tazhong No. 10 fault; Tarim Basin

35

1 INTRODUCTION

36

Faults have always been widely considered as a difficult and disputed topic in petroleum

37

geology because they influence the essence features of petroleum systems, especially the petroleum

38

migration process. 1-4 The Tazhong Uplift, one of the most prolific petroliferous areas in the Tarim

39

Basin, located in the central part of the basin. 5 The uplift is formed with multi-episode structural

40

movements, and develops complex faults. 6-7 Faults in the uplift can be divided into two sub-fault

41

systems: (1) NW-trending thrust fault system mainly includes Tazhong No. 10 fault, Tazhong No. 1

42

fault, and central fault; (2) NE-trending strike-slip fault system mainly includes ZG51, ZG432, ZG43

43

and ZG441 faults. These sub-fault systems form X-shape fault combinations together (Fig.1 and Fig.

44

2). Recently, amounts of oils and gases with high-economic value have been proved in the

45

Ordovician carbonate rock of the uplift. At the end of 2012, the oil and gas reserves are

ACS Paragon Plus Environment

Page 2 of 48

Page 3 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

46

approximately equal to 5×108 t. 8 The produced Ordovician hydrocarbon in the uplift includes gases,

47

gas condensates, oil condensates, normal oils, and very waxy oils. Most of them found along the

48

fault belts (Fig. 1), which indicates it is meaningful to investigate influences of the faults on

49

hydrocarbon migration and accumulation.

50

In the last decade, significant progress has been made in the study of faults controlling on the

51

Ordovician hydrocarbon migration and accumulation in the Tazhong Uplift. Lin and Zhang (1996),

52

Zhang et al. (2000), Gu et al. (2003), Sun et al. (2003), and Han et al. (2009) proposed that the

53

Manjiaer Depression might be an dominating kitchen for the hydrocarbons in the Tazhong Uplift,

54

based on oil-source correlation of biomarkers, and suggested that the hydrocarbons were mainly

55

introduced into the uplift along the No.1 fault belt. 9-13 Similarly, Ma et al. (2004), Guo et al. (2008),

56

Xiang et al. (2010), Wu et al. (2009) used the grading rules of hydrocarbon production, oil/gas

57

properties, inclusion tracer, and diamantane index to predict the Manjiaer source kitchen, and

58

deduced the No.1 fault belt was the most important hydrocarbon migration pathway in the uplift, 14-17

59

which is supported by Yang et al. (2012) based on the analysis of reservoir physical properties. 18 In

60

the past few years, some geologists suspected that the NE-trending strike-slip faults should be gave

61

much more attention. Yang et al. (2012), Zhou et al. (2013), Pang et al. (2013a, b), and Lan et al.

62

(2014, 2015) indicated that strike-slip faults might be additional pathways for hydrocarbon migration

63

in the Tazhong Uplift, based on study of nitrogen-bearing organic compounds, crude oil trace

64

elements, and carbon isotope ratios of nature gas, and suggested that the hydrocarbon charged into

65

the Ordovician of the uplift though the intersection zones of strike-slip faults and Tazhong No. 1 fault.

66

7-8, 18-21

67

Despite recent progress in the investigation of strike-slip faults and No.1 fault jointly controlling

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

68

the Ordovician hydrocarbon migration and accumulation in the Tazhong Uplift, the focus study on

69

the No.10 fault belt is scarce, and a more thorough control mechanism analysis is required. Only few

70

research have inferred that the No. 10 fault belt was also an important channels for vertical

71

hydrocarbon migration based on the structural movement research. 22 The underlying reasons for

72

preceding deficiency of related study is due to the lack of oil-gas wells drilled along the No.10 fault

73

belt for hydrocarbon characterization and migration tracer at that time. With the penetration of

74

hydrocarbon exploration and development, lots of exploration or development wells (more than 30)

75

have been drilled along the No.10 fault belt. Combined with the geologic and geochemical methods,

76

this study investigates the secondary migration of the Ordovician hydrocarbons along the No.10 fault

77

belt. The key factors are investigated including regional structural framework, source rock

78

distribution, oil and gas properties, Ts/(Ts+Tm), and carbon isotope ratios of gases. A new model for

79

further Ordovician hydrocarbon exploration in the Tazhong Uplift has been proposed. The results can

80

provide theory and data support for further hydrocarbon accumulation mechanisms study and

81

hydrocarbon exploration activities in the Tazhong Uplift of the Tarim Basin.

82

2 NOMENCLATURE

83

Caledonian period: 570 to 410 Ma;

84

Hercynian period: 410 to 250 Ma;

85

Indosinian period: 250 to 208 Ma;

86

Yanshanian period: 208 to 65 Ma;

87

Himalayan period: 65 Ma;

88

Gas dry coefficient: C1/Ʃ(C1–C5), the relative abundance of CH4 among CH4, C2H6, C3H6, n-C4H8,

89

i-C4H8 and C5H12;

ACS Paragon Plus Environment

Page 4 of 48

Page 5 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

90

△R3: |R3-R4|/R4; R3= iC4/nC4; R4 = iC4/C3; C3 is the propane; iC4 is isobutene; nC4 is normal butane.

91

23, 24

92

Ts/(Ts+Tm): 17α-22,29,30-trisnorhopane /(17α-22,29,30-trisnorhopane +

93

18α-22,29,30-trisnorhopane) ratio;

94

HI: hydrocarbon index

95

3 GEOLOGICAL SETTING

96

The Tazhong Uplift, one of three typical uplifts in the Tarim Basin, is surrounded by the

97

Tangguzibasi Depression in the southwest, the Manjiaer Depression in the northeast and the Awati

98

Depression in the northwest (Fig. 1). The NW-SE-trending Tazhong Uplift converges towards the

99

east and open towards the west. It is subdivided into four structural tectonic units: the east burial hill,

100

the south slope, the central faulted horst belt, and the north slope.13 The north slope contains: the

101

No.1 fault belt (1FB), the north platform belt (NPB), the No.10 fault belt (10FB), and the south

102

platform belt (SPB) from north to south (Fig. 1). The 1FB is the boundary between the Manjiaer

103

Depression and the Tazhong Uplift, and is about 230 km long and 5-10 km wide with an inverted “S”

104

shape. The 10FB is mainly composed of the No.10 fault and accompanied second rifts, with 50 km

105

long, west-north-west trending, thrust characteristic, and shows an inverted L-shape. It is adjacent to

106

the east burial hill to the southeast, and vanishes along Z1 well area to the northwest (Fig. 1).

107

The 10FB and 1FB mainly experienced three discernable evolution stages (Fig. 2): (1) the start

108

of fault activity featuring extensional structure during the Cambrian-Early Ordovician. The

109

extensional faulting influence during this period set the border between the Tazhong Uplift and the

110

Manjiaer Depression. As a result, the 1FB and 10FB developed in the Middle Ordovician, and

111

formed the south-north zoning structural framework in the Tazhong Uplift. Influenced by the zoning

112

characteristics, the reservoir characteristic and hydrocarbon distribution in the Tazhong Uplift varied

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

113

across the 10FB. 21, 25, 26 The karst reservoir was well developed in the north side because of its flat

114

slope and sufficient water leaching. On the contrary, the karstification of the south side was relatively

115

poor for the existence of a steep slope. (2) A period of predominantly tectonic reversal occurring and

116

transforming into the thrust reversal fault system during the Middle-Later Ordovician. The eastern of

117

the Tazhong Uplift experienced intense uplift and formed large erosion unconformities. The 1FB and

118

10FB were reactivated, and they came into thrust reversal in this period. The 1FB and 10FB not only

119

controlled the structural framework of north-south zoning, but also the distribution of the structural

120

traps.

121

period, and then a multi-layered and uniform succession of sediments were deposited.6,21,29 As shown

122

in representative profiles, the No.1 fault and No.10 fault cut the strata from the oldest to youngest

123

(Cambrian, Ordovician, Silurian, and ending in the Silurian) (Fig. 2). The early formed 10FB and

124

1FB have been divided into several blocks by the striking faults, i.e., ZG441, ZG46, ZG43, and

125

ZG51 from west to east (Fig. 2). The NE strike–slip faults also extended down to the Proterozoic

126

basement.7, 21, 27

6, 21,27,28

(3) Final to shape in the late Ordovician. The Tazhong Uplift was completed after this

ACS Paragon Plus Environment

Page 6 of 48

Page 7 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

127 128

Fig. 1. Ordovician reservoired oil-gas distribution in the Tazhong Uplift, Tarim Basin.

129 130

Fig. 2. Representative profiles illustrate the tectonic frameworks of different segments of the No.10

131

fault belt.

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 8 of 48

132

Drilled formations in the Tazhong Uplift from the bottom to top include: the Cambrian,

133

Ordovician, Silurian, Devonian, Carboniferous, Paleozoic, Triassic, and Cretaceous, with the Jurassic

134

missing (Fig. 3). The Ordovician system is characterized by marine carbonate platform facies. There

135

are six kinds of micro-facies developing in the study area: mound, reef, slope, restricted platform,

136

beach, and interbank sea facies. 19 Excellent reservoir belts with grain beach and organic reef facies

137

have been developed in the north slope of the Tazhong Uplift, where is also the best area with the

138

advantage for hydrocarbon resources exploration potentiality of the Ordovician carbonate. 7,30-33 Due

139

to sea level fluctuation, nine sedimentary cycles have been developed, and the overall thickness

140

reached about 100~300 m. 34 The 10FB is located on the carbonate platform inner area, and mainly

141

developed

142

oolites, intraclast limestones, and most bioclast limestones.8 The scale of a single reef or grain beach

143

is small, with a thickness of about tens of centimeters to several meters, and interbedded lime

144

mud-mound 25. The single reef or grain beach width varies between 2 km and 5 km. Thus, correlating

145

the lithologies, especially of the reef body, from the wells is difficult

146

reservoir-caprock assemblages can be identified in the Ordovician (Fig. 3). Among them, the Lower

147

Ordovician Yingshan Formation weathered crust is the most important hydrocarbon produced

148

reservoir, with Upper Ordovician micritic limestone (Liang 3-5 section) as caprock. The Yingshan

149

Formation experienced large-scale weathering and erosion, with large-scale development of karst

150

and corrosion holes in structure highs. Furthermore, later fracturing and dolomitisation with

151

hydrothermal activity coupled to improve the physical properties of grain bank reservoirs in the

152

Yingshan Formation. 35

organic

reef

and

grain

beach

systems

153

ACS Paragon Plus Environment

which

is

composed

by

7

. Three sets of

Page 9 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

154 155

Fig. 3. Lithology and petroleum geological settings in the Tazhong Uplift.

156 157

The overall distribution of oil and gas fields in the Tazhong Uplift is characterized by laterally

158

“E–W blocking, N–S zoning, oil in the west, and gas in the east”, 26 and characterized by the

159

superimposition of the multi-layer and multi-type reservoirs in vertical, with Upper Ordovician

160

Lianglitage reef reservoirs and Lower Ordovician Yingshan weathering crust reservoirs. 35 It has been

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

161

widely accepted that the Ordovician hydrocarbon in the Tazhong Uplift derived from the

162

Middle-Upper Ordovician and the Cambrian-Lower Ordovician source rock. 6,12,36-43 Biomarkers of

163

the potential Middle-Upper Ordovician source rocks and related oil are characterized by regular “V”

164

type sterane with C27 > C28 < C29. By contrast, biomarkers of the potential Cambrian-Lower

165

Ordovician source rocks and oil have the characteristics of low abundance of regular sterane of

166

“slanted line type” or “reverse L type” with C27 < C28 < C29, together with high abundance of

167

phenylisoprenoids, 4-alkyl-24-ethyl cholane, of triaromatic dinophyceae steroids, and gammacerane.

168

A higher abundance of phenylisoprenoids is considered to be related to Cambrian source rocks.12

169

4 SAMPLING AND METHODS

170

Parts of oil and gas composition testing data obtained from the Tarim Oilfield Company of

171

PetroChina. 59 Ordovician oil samples and 49 Ordovician gas samples selected for composition

172

analysis were collected from wellhead separators in the Tazhong Uplift.

173

4.1 Molecular Composition Measurements of Crude Oil

174

The molecular compositions of oil samples were tested using a gas chromatographyrmine

175

spectrometry (GC-MS). After removing asphaltenes, oil sample was segregated into saturated and

176

aromatic fractions by a silica/alumina chromatographic column. Hexane and benzene were used to

177

extract the saturated and aromatic hydrocarbons, respectively. Ether was then used to extract the

178

nonhydrocarbon organic compounds. Then, an Agilent 5975i GC-MS was used to analyze

179

hydrocarbon content. For operating GC, the oven temperature was set at 100 °C for 1 min and then

180

ramped to 140°C at a rate of 10 °C/min, subsequently to 300°C at 2 °C/min, and maintained for 20

181

min. The carrier gas was helium, and injector operated at a liner flow of 0.8 cm3/min. The MS was

182

handled with an ionization energy of 70 eV.

ACS Paragon Plus Environment

Page 10 of 48

Page 11 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

183

Energy & Fuels

4.2 Molecular Composition and Stable Carbon Isotope Measurements of Natural Gases

184

The molecular compositions of gas samples (without H2S) were tested using an Agilent 6890N

185

gas chromatograph equipped with a flame ionization detector and a thermal conductivity detector.

186

Individual hydrocarbon gas components (C1–C4) were separated using a capillary column (PLOT

187

Al2O3 50 m × 0.53 mm). Non-hydrocarbon gases were separated using two capillary columns (PLOT

188

Molsieve 5 Å 30 m × 0.53 mm, PLOT Q 30 m × 0.53 mm). GC oven temperature was initially set at

189

30 °C for 10 min, and then ramped to 180 °C at 10 °C/min. All the gas compositions have made

190

oxygen-free correction and the corresponding correction for nitrogen. Stable carbon isotope values

191

were measured on a Thermo Delta V Advantage instrument interfaced with a HP 5890II gas

192

chromatograph. The gas chromatograph was equipped with a Poraplot Q capillary column (30 m× 0.32

193

mm), and carrier gas was helium. Gas components were separated on the gas chromatograph in a

194

stream of helium, converted into CO2 in a combustion interface, and then injected into the mass

195

spectrometer. Samples were injected at an initial temperature of 50 °C (maintained for 3 min), after

196

which the oven was heated to 190 °C at a rate of 15 °C/min, and maintained at that temperature for 15

197

min. Gas samples were analyzed in triplicates, and the stable carbon isotope data are expressed in the

198

delta notation in permil (‰) relative to VPDB (Vienna Pee Dee Belemnite, δ13CVPDB = 0‰).

199

Measurement precision is ±0.5‰ for δ13C. Analytical precision is estimated to be ±0.3‰.

200

Different from the other gas compounds which was determined using an Agilent 6890N gas

201

chromatograph, the H2S concentrations were measured in oil field locale. The methods for H2S

202

measurement were also different from the other gas compounds. In brief, H2S-bearing gas was

203

bubbled through 50mL glass jars containing 0.5 × 10-2 zinc acetate to precipitate ZnS. ZnS was

204

oxidized by adding 10 mL 0.01mol/L Iodine solution and 10 mL 1mol/L HCl until blended well.

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

205

After 2~3 min reaction, solution was transferred to 250 mL iodine flask and added 2~3 mL starch

206

solution. Then, it was added 0.01mol/L sodium thiosulfate until the blue disappeared. The H2S

207

concentration of gas was calculated in accordance with the measurement law of mass spectrometry

208

(State Standard of China (GB/T 11060).

209

5 RESULTS

210

As Ordovician oils and gases originated from the Cambrian-Ordovician source rocks, previous

211

studies has shown that oils have uniform middle-high maturity, such as TeMNr, TMNr, Ts/(Ts+Tm),

212

are approximately > 0.6, > 0.6, > 0.5, respectively. 44-46 In addition, other geochemical parameters,

213

such as tricyclic terpane, gamma napalite and methyl sterane, are almost uniform, and indicated that

214

the Ordovician hydrocarbon accumulation in the Tazhong Uplift is almost uniform.

215

12,40,47-48

216

Ordovician hydrocarbon migration of the Tazhong Uplift. 8,15,20-21, 49-50

217

5.1 Oil Properties

Subsequently, crude oils and gases properties and compositions could be good tracers for

218

The oil compositions and properties vary regularly during the process of migration. 9,51 The

219

Ordovician oils are mainly light crude with density of 0.76~0.88 g/cm3, wax content of 1.6%~18.5%,

220

sulphur content of 0%~0.67%, and viscosity of 0.75~8.21 mPas. The oil properties have

221

characteristics with obvious belts (Fig. 4 and Fig. 5). In generally, oil properties have saddle-like

222

distribution: compared to the NPB, there are significant parameter abnormities in the 1FB and 10FB,

223

as shown by relatively low densities and high wax contents (Fig. 4 and Fig. 5). For example, the wax

224

contents in the 1FB are higher than 7% with highest 16.1% (TZ86), in the NPB are lower than 8%

225

with lowest 1.6% (TZ168), and in the 10FB are higher than 7% with highest 18.5% (ZG51). In

226

addition, the wax contents are anomaly high along the No.1 fault and No.10 fault and regularly

ACS Paragon Plus Environment

Page 12 of 48

Page 13 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

227

decrease with the distance increasing from the two faults. For example, the wax contents decrease

228

from 9.9% to 5.8% and then increase to 9.2% (ZG1-ZG503-ZG433C). On the contrary, the densities

229

are anomaly low in the two fault belts and regularly increase with the distance increasing from the

230

No.1 fault and No.10 fault. For example, the oil densities increase from 0.78 g/cm3 (ZG10) to 0.81

231

g/cm3 (ZG106), and then decrease to 0.78 g/cm3 (ZG43).

232 233

Fig. 4. Oil density distribution in the Ordovician reservoirs in the Tazhong Uplift.

234

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

235 236

Fig. 5. Wax content distribution in the Ordovician reservoirs in the Tazhong Uplift.

237 238

The lateral variations in the oil properties indicate that the 1FB and 10FB are both the places

239

where the hydrocarbon charges. After arriving at the Tazhong Uplift, oils continue migrating in two

240

directions, namely, from southwest to northeast in the 10FB and from northeast to southwest in the

241

1FB. As the oils and gases are mainly from the Cambrian-Ordovician source rocks, the above

242

characteristic seems to be caused by the higher maturity gases which generated in later periods

243

charging into the crude oils generated in earlier periods; the densities proximal to the No.1 fault and

244

No.10 fault reduce, and the wax contents increase. However, on account of the migration obstacles

245

and the strong heterogeneity of the Ordovician carbonate rocks, it is rarely observed that oils mixed

ACS Paragon Plus Environment

Page 14 of 48

Page 15 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

246

with gases in the areas far away from the No.10 fault and No.1 fault, and the densities are relatively

247

larger, and the wax contents lower.

248

Analysis of fluid inclusions in reservoirs reveals three stages of oil–gas inclusions in

249

gas-condensate reservoirs in the Tazhong Uplift, including the first-stage oil–gas inclusions, the

250

second-stage oil–gas inclusions and the third-stage gas inclusions.

251

temperatures of the hydrocarbon inclusions correspond to Middle Caledonian (70-90

252

Hercynian (100-125 ℃) and Late Himalayan (120-155 ℃) fluids (Fig. 6). 53, 54 This suggests that three

253

stages of effective hydrocarbon charge are preserved in the Tazhong Uplift: oil filling occurred in the

254

Middle Caledonian and the Late Hercynian, however, gas filling in the Late Himalayan. Analysis of

255

oil and gas maturity provide direct evidence that highly overmature gases, which were mainly

256

sourced from the Cambrian-Lower Ordovician source rocks during the Himalayan period, flushed

257

and invaded into the previous oil reservoirs, which generated in the middle Caledonian and late

258

Hercynian periods.

259

gas-condensate reservoirs than in oil reservoirs,

260

Zhang (2000). 10 The analysis of maturities of oils in the Tazhong Uplift shows that the oils from

261

different types of reservoirs have significantly different maturities. Meanwhile, maturity of

262

Ordovician gases in the Tazhong Uplift is calculated according to the equation proposed by Dai

263

(1992): δ13C1=14.13 lg Ro – 34.39 and oil maturity according to the methylphenanthrene index MPI1

264

proposed by Radke et al. (1982). 56, 57 The results show that gas maturity in gas-condensate reservoirs

265

is substantially different from the oil maturity. However, gas maturity in volatile-oil reservoirs are

266

slightly different from the oil maturity. Oil and gas maturities in normal oil reservoirs are almost the

267

same. These suggest that the oils and gases in gas-condensate reservoirs are not from the same period;

39-40,48

52,53

The peak homogenization ℃),

Late

Zhu et al. (2014) found the δ13Coil is commonly heavier by 1‰ in 55

which is consistent with the opinion expressed in

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Page 16 of 48

268

high maturity gases from a later period may wash and alter an ancient oil reservoir, causing different

269

maturities of oils and gases.

270 271

Fig. 6 Geothermal and burial history of stratums in the Tazhong Uplift

272 273

Charging of the dry gases changed the densities of the oils. Most of the gases dissolved into the

274

oils, and oil densities vary. Along the gas migration direction, dry gas invasion energy decreased.

275

Correspondingly, oil densities increase gradually along the migration direction. Hydrocarbon

276

accumulation near the source faults (No1. fault and No.10 fault) is typically characterized by gas

277

condensate reservoir with lower densities resulting from the charge sequences (Fig. 1 and Fig. 2),

278

and oil densities increase gradually with increasing distance. Meanwhile, the wax contents are also

279

influenced by dry gas invasion. Previous studies have shown that the late charge of a gas into oil

280

reservoirs would result in deasphalting oil and an increase oil wax contents

281

experienced gas invasion commonly show a sharp decrease in the light components of normal

ACS Paragon Plus Environment

58-62

. Oils that

Page 17 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

282

alkanes but a relatively moderate decrease in the heavy components, which resulted in the forming

283

of waxy oils. 63-64 Proximal to faults, oils with high wax contents have been detected, proving that

284

hydrocarbon was indeed charging along the No.1 fault and No.10 fault.

285

There are two interpretations for the observed oil property distribution. First, depositional facies

286

vary among the Ordovician reservoirs (Fig. 7). Facies in the 1FB and 10FB are mainly reef and

287

beach, and changed to inter-bank sea in the NPB. The facies of inter-bank sea always have poor

288

reservoir physical property, and created migration obstacles. This leads to discontinuity of

289

hydrocarbons (Fig. 7). Second, in the Ordovician carbonate reservoirs, the markedly faulting and

290

karstification lead to the complex pore-fissure-fracture reservoirs space system. It is obvious that the

291

proximal reservoir’s porosity and permeability have been improved significantly by faulting.

292

Pore-fissure-fracture space systems with relatively high porosity and permeability are usually

293

segmented by the surrounding wall-rocks with ultra-low porosity and permeability, which make a

294

direct contribution to the relatively independent fracture-cave units. 65-66 Due to the discontinuity

295

distribution of pore-fissure-fracture reservoir, the hydrocarbon migration with long distance is

296

limited. That is, on account of the migration obstacles caused by the strong heterogeneity of the

297

carbonate rocks, it is rarely observed that oil mixed with gas in the areas far from away from the 1FB

298

and 10FB, and low wax contents and high densities can be observed.

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

299 300

Fig. 7. Facies distribution in the Ordovician reservoirs in the Tazhong Uplift.

301 302

5.2 Gas Properties

303

In process of natural gas migration and accumulation, the gas properties and compositions

304

change systematically and regularly and have usually been a good tracer for hydrocarbon migration

305

history. 67-68 Properties of the Ordovician gases sampled from the Ordovician are complex. The CH4

306

contents range from 79.3% to 94.6%. The range of gas/oil ratios are from 0 m3/m3 to 13, 527 m3/m3,

307

and gas dry coefficients are generally higher than 0.90. The H2S contents also change largely,

308

ranging from 0% to 23.10%. Following the same variation rules of the oil properties, the Ordovician

309

gas properties change systematically and regularly. As shown in the plane distribution maps of

310

gas/oil ratio (GOR) (Fig. 8), dryness coefficients (Fig. 9), and H2S contents (Fig. 10), it is clear that

311

natural gas properties can be divided into three belts, which represented the intensity of gas charging

312

and migration are various. The three gas property parameters are characterized by high anomalies in

ACS Paragon Plus Environment

Page 18 of 48

Page 19 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

313

the 1FB and 10FB. The H2S contents are 1000 times higher and the GOR is 2~3 times higher along

314

the No.10 fault and No.1 fault (Fig. 8 and Fig. 10). The gas dryness coefficients in the 1FB and 10FB

315

are mainly higher than 0.95 and 0.94, respectively, but they are lower than 0.93 with the lowest 0.72

316

(ZG26) in the NPB (Fig. 9). All of them decrease away from the No.10 fault and No.1 fault and can

317

be tracers for the influence of gas migration. The afore-mentioned facts indicate that the late gas

318

charge and migrate along the two faults. As the distance from the No.1 and No.10 faults increase, the

319

gas charge intensity becomes small.

320 321

Fig. 8. GOR distribution in the Ordovician reservoirs in the Tazhong Uplift.

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

322 323

Fig. 9. Dry coefficient distribution in Ordovician reservoirs in the Tazhong Uplift.

324

325 326

Fig. 10. H2S content distribution in the Ordovician reservoirs in the Tazhong Uplift.

ACS Paragon Plus Environment

Page 20 of 48

Page 21 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

327

Energy & Fuels

Fu and Liu (1992) and Miao et al., (2011) summarized the law of △R3.

23-24

Due to the

328

differences of molecular polarity and volume, natural gases produce chromatographic migration

329

fractionation in seepage migration process. With the migration distance increasing, R3 increases and

330

R4 decreases. The |R3-R4| also shows an increasing trend, so △R3 shows a more significant increase

331

as a good reference for natural gas migration. The value of △R3 shows a significant increase in

332

relation to increasing migration distance. The deeper values of △R3 are smaller, but the shallow

333

values are larger in the same wells, for example, in wells ZG44C, ZG43, ZG431 and ZG51 near the

334

No.10 fault (Fig. 11), which indicates an increasing vertical migration distance and the 10FB is a gas

335

charge place.

336

(a)

(b)

337 338 339

(c)

(d)

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

340 341

Fig. 11. Vertical migration characteristic of gas with the parameter of △R3. The △R3 value is smaller

342

in the deeper reservoir. The dashed line is the boundary line of △R3 value with different depth. The

343

wells are seen in Figure 1. (a) Well ZG43; (b) ZG431; (c) ZG44C; (d) ZG51.

344 345

Controlled by the strong heterogeneity of the Ordovician carbonate rocks, gases derived from

346

the Cambrian-Lower Ordovician source rocks in the Himalayan period firstly occupied the nearby

347

pore-fissure-fracture systems after introducing along the No.1 fault and No.10 fault, and then

348

migrated far away. In the presence of Cambrian gypsum, thermochemical sulfate reduction was

349

active, 69 and the overmature gases were mixed with H2S. Therefore, gases with higher H2S contents

350

can be found in the reservoir beds near the No.10 fault and No.1 fault. This resulted in abnormally

351

high GOR, high gas dryness coefficients, high H2S contents, high wax contents and low densities

352

near the No.1 fault and No.10 fault. The afore-mentioned parameter anomalies gradually disappeared

353

as the distances from the two gas source faults increased.

354

5.3 Crude Oil Composition and Maturity Parameter

355

Property and composition discontinuities of crude oils are widely suggested to be the

ACS Paragon Plus Environment

Page 22 of 48

Page 23 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

356

inheritance which oils firstly charged into the reservoirs. 70-74 For the same source rocks, over time,

357

the maturity of generated hydrocarbon increases constantly. Therefor oil migration pathway and

358

orientation can be speculated based on tendencies of decreasing oil maturity.

359

ratio can be applied to crude oil that experienced the peak period of hydrocarbon generation, to

360

recognize low-mature, mature, and high-mature oil, which is a valuable crude oil maturity index. The

361

smaller the distance from oil to the source rocks is, the higher the Ts/(Ts+Tm) ratio is. To the

362

contrary, with distance becoming larger away from the source, the ratio tends to be smaller. The

363

successful application of this oil maturity index in the Ordovician carbonate reservoir of karst

364

pore-fissure type in the Halahatang Area of the Tarim Basin, 76 clearly shows that the Ts/(Ts+Tm)

365

ratio is effective indicator for tracing oil migration in carbonate rocks.

74-75

The Ts/(Ts+Tm)

366

Synthesized with the Ordovician crude oil data, the Ts/(Ts+Tm) ratios vary as the distance from

367

the faults (Fig. 12), and follow the same variation rules of the wax contents, gas/oil ratios, H2S

368

contents, and gas dryness coefficients. Ts/(Ts+Tm) ratios are high in the 1FB and 10FB and

369

decreases sideways, which indicates that the horizontal migration distance increases and the two

370

faults are the oil source faults (Fig. 12). This viewpoint was further supported by the vertical

371

distribution of hydrocarbon. For example, the TZ11 Oilfield and TZ12 Oilfield, adjacent to No. 10

372

fault, are characterized by compound oilfields, where the counts of vertical hydrocarbon layer are

373

obviously larger than within the oilfields far away from the No. 10 fault, such as the ZG6 Oilfield

374

(Fig. 13). In addition, other geochemical parameters of crude oil sampled from different reservoirs in

375

the TZ11/TZ12 Oilfield vary regularly. Compared to the Silurian oils, the Ordovician oils have larger

376

amount of nitrogen compounds, 4,6-DMDBT/1,4-DMDBT ratio, 2, 4-DMDBT/1,4-DMDBT ratio,

377

and

4-MDBT/

1-MDBT

ratio,

while

have

smaller

1,8-DMCA/2,7-DMCA

ACS Paragon Plus Environment

ratio

and

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

378

1,8-DMCA/1,7-DMCA ratio (Fig. 13). This comparison of geochemical parameters also indicates

379

that the No. 10 fault is oil migration fault.

380 381

Fig. 12. Ts/(Ts+Tm) ratio distribution in the Ordovician reservoirs in the Tazhong Uplift.

382 383

Fig. 13. Vertical migration characteristic of oil with geochemical parameters in the section.

ACS Paragon Plus Environment

Page 24 of 48

Page 25 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

384

The afore-mentioned pattern of crude oil molecule parameters occurs because the effects of

385

multiple hydrocarbon charges and the hydrocarbon in short supply during the later accumulation

386

periods. The over-mature hydrocarbon which generated during the later period can hardly migrate

387

through a long distance and charging into reservoirs far away from the source faults. As a

388

consequence,

389

much higher of maturity than that accumulated farther away.

390

5.4 Gas Maturity Parameter

oil

accumulated

near

the

No.1

fault

and

No.10

fault

trend

to

be

391

Geochemical characteristics of natural gas including carbon isotope ratio are inherited from the

392

time when gas charge into the reservoirs. 9, 77 As gas maturity increases, the gas composition would

393

become enriched in the

394

mature they would be, and the more

395

that gas enriched in the 13C usually distributed close to source rocks. The successful application of

396

carbon isotope compositions in the Ordovician carbonate reservoir of karst pore-fissure type in the

397

Lunnan Area of the Tarim Basin indicate carbon isotope ratios of gases can trace the gas migration. 49,

398

80

399

13

C. 70, 78-79 The later the natural gases charged into reservoirs, the more 13

C would become enriched. 9, 70, 79 The above facts indicated

According to the 51 Ordovician gas samples, there are various

13

C values for methane gases

400

(Fig. 14). The gas samples with lower maturity are mainly from the NPB. The more mature gas

401

samples with higher carbon isotope ratios are from the 1FB and 10FB, indicating that they are

402

generated in the relatively late period. Carbon isotope ratios of gases are large along the No.1 fault

403

and No.10 fault, and decrease gradually with increasing distance from the two faults. For example,

404

carbon isotope ratios are -38.0‰ in Well ZG2, decreasing gradually to -47.6‰ and -44.6‰ in Well

405

ZG501 and ZG5, and then increasing to -41.6‰ in Well ZG433C (Fig. 14). This indicates an

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

406

apparent hydrocarbon migration and the No.1 fault and No.10 fault are gas charge pathways. This

407

pattern has the same explanation as the crude oil maturity parameters.

408 409

Fig. 14. Methane carbon isotope composition distribution in the Ordovician reservoirs in the

410

Tazhong Uplift.

411

6 DISCUSSION

412

6.1 Hydrocarbon Charging and Migrating Along the No.10 Fault Belt

413

6.1.1 Theoretical Support

414

Assuming that oils and gases in reservoirs charge from one side, along the oils and gases

415

migration direction, properties and charge intensity of oils and gases may regularly change after a

416

gradient. 9 As discussed previously, traditional viewpoint indicated that the Ordovician oils and gases

417

in the uplift are mainly introduced along the No.1 fault from the northern Manjiaer Depression, and

ACS Paragon Plus Environment

Page 26 of 48

Page 27 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

418

then migrated from north to south. 7-8,18-21 Based on this model, it can be inferred that the oils and

419

gases charge intensity is anomaly high at the No.1 fault (oil source fault) and tended to decrease as

420

distance increased away from the fault. Consequently, a critical boundary for oils and gases

421

charging and accumulation in the Ordovician of the uplift would exist, such as 35 km away from the

422

No.1 fault. 8,19-20 That is, the area beyond this hydrocarbon charging and accumulation boundary,

423

such as 10FB and SFB, would develop few oil-gas fields. But that is not the case, the 10FB and SFB

424

have lots of oil and gas reservoirs nowadays (Fig. 1). In addition, regional tectonic framework in the

425

hydrocarbon charge period controlled secondary hydrocarbon migration. 81-82 After hydrocarbons

426

charged into a conductive layer, they would migrate from low part to the high part by buoyancy. 83

427

Based on the “volume balance” theory,

428

hydrocarbon charge period, is modeled (Fig. 15). It shows the 10FB is the apparently high part in the

429

north slope of the uplift, which forms a “shelter” and makes the SFB is blocked from the

430

hydrocarbon charge from the Manjiaer Depression. These make the probability of hydrocarbon

431

accumulation in the SFB become much lower. But lots of hydrocarbon wells drilled in the SFB, such

432

as the Z1 well area. Subsequently, it is reasonable to deduce that there is an additional hydrocarbon

433

charge place near to the SFB, and the 10FB is the ideal match. Anomalies of all the parameters in

434

the10FB are the best evidence for the new conclusion.

84

the Ordovician’ top structure form during the major

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

435 436

Fig.15. Structural form of the top of the Ordovician during the major accumulation period in the

437

Tazhong Uplift.

438

6.1.2 Source Condition

439

The requirement for hydrocarbon charging along the 10FB is that the No.10 fault contacts with

440

the source rock. That is, source rocks must develop in the Tazhong Uplift itself. Similar to

441

considerable progress in determination of hydrocarbon source rock intervals in last decade, the

442

researches of source kitchen are also fruitful in the Tazhong petroleum system.

443

For a long time, the Manjiaer Depression was considered to be the primary source kitchen for

444

the Ordovician hydrocarbon in the Tazhong petroleum system by vast majority of geochemists (Fig.

445

16),

446

additional kitchen and be gave much more attention. According to oil-source rock correlation of

8-9,11-12,20

but some geologists who suggested that the Tazhong Uplift itself ought to be an

ACS Paragon Plus Environment

Page 28 of 48

Page 29 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

447

biomarkers, such as 4-alkyl-24-ethyl cholane, 24-norcholestane, gammacerane, diasteranes, and

448

triaromatic dinosteroids, the geologists deduced Middle-Upper Ordovician source rocks and

449

Lower-Middle Cambrian source rocks deposited in the north slope facies of the Tazhong Uplift itself

450

should be the potential source rocks for the Ordovician oils and gases.

451

Cambrian source rocks deposited in the evaporation lagoon, inner sag, and organic shelf, with the

452

lithology composed mainly of black shale and phosphorite. 50 They have high hydrocarbon potential

453

with thicknesses of 10~300 m, TOC (total organic carbon) of 1.1%~3.5% with an average of 1.4%,

454

and HI (hydrocarbon index) of 2.0 to 230.1 mg/g. The Middle-Upper Ordovician source rocks were

455

of some evaporative lagoonal and organic facies deposited on an inner platform, with the lithology

456

composed mainly of muddy limestone and gray phosphatic silica. The thicknesses of them ranges

457

from 10 m to 150 m, TOC, from 1.1% to 2.5% with an average of 1.0%, HI, from 1.6 mg/g to 156.2

458

mg/g. Most of the rock samples (cores) in the Tarim Basin range in age from Ordovician to

459

Cambrian, too old to contain land-plant-derived vitrinites for the measurement of Ro. The reflectance

460

of solid bitumen in the samples was measured as Rb. The Rb values were transformed into Ro values

461

using the following empirical relationship which was based on measurements of samples from China.

462

85

463

(vitrinite reflectance) ranging from 1.5% to 3.0% and from 0.5% to 1.2%, respectively. 38,40, 86-87 As

464

noted, the source rocks in the Tazhong Uplift itself reached hydrocarbon generation peak and can

465

provide significant support for hydrocarbon charging and migrating along the No.10 fault belt.

37-40

The Lower-Middle

The two set of source rocks in the uplift are both in high mature to over mature stage, with Ro

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

466

(a)

467 468

(b)

469 470

Fig. 16. Source rock distribution in the Tarim Basin (modified from the Zhang et al., 2000a, b, 2012).

471

(a) The Lower-Middle Cambrian source rock. (b) The Middle-Upper Ordovician source rock.

ACS Paragon Plus Environment

Page 30 of 48

Page 31 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

472

Energy & Fuels

6.1.3 Reservoir Properties Distribution

473

Limited carrier beds with a higher porosity and permeability usually are dominant pathways for

474

oil and gas migration. 88-90 The Ordovician carbonate rocks in the Tazhong Uplift show a low matrix

475

porosity of less than 5% and a low permeability of less than 1 mD. Therefore faults and associated

476

fractures are crucial for reservoir characterization. The faults promote development of a system of

477

micro-cracks and fractures increase reservoir space. These features serve as fluid flow, increasing the

478

reservoir porosity and permeability and enhancing the activity of underground fluids, such as the

479

structurally control hydrothermal reservoir. 91 From the Ordovician carbonate reservoir model of the

480

Tazhong Uplift, it follows that the fractures in different belts are distributed differently. Generally,

481

the 1FB and 10FB develop more open fractures due to multiphase activity of the No.1 fault and

482

No.10 fault. The fracture orientation is parallel to the direction of the trending thrust faults

483

(northwest); in contrast, the fractures in the NPB and SFB grow less intensely and do not show

484

tendency to develop gapping, resulting in relatively poor reservoir conditions in those belts.

485

Meanwhile, the faults break through the land surface and increase the depth of the karstification zone

486

during the karst stage, improving the reservoir bed quality. Karst-weathered crust reservoir beds

487

develop in the Lower Ordovician of the Tazhong Uplift. 92 By integrating the fracture distribution

488

(based on fault density) with weathering crusts (based on sedimentary facies and structural highs),

489

the Ordovician reservoirs’ porosity and permeability have been analyzed. The porosity and

490

permeability of reservoirs in the 1FB and 10FB are 7~8 times higher than that in NPB and SPB (Fig.

491

17). With the distance increasing from the No.1 fault and No.10 fault, the reservoir physical property

492

become worse, and industry hydrocarbon wells decrease (Fig. 17). Based on the analysis of

493

relationship between logged reservoir physical property and reservoir oil-bearing property, the

ACS Paragon Plus Environment

21

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

494

commercial hydrocarbon yet discovered is all distributed in reservoirs with relatively high porosity

495

and permeability (porosity > 1.8%, permeability > 0.1 MD), and oil saturation increase with the

496

porosity and permeability increasing (Fig. 17). These can deduce that the 1FB and 10FB featuring

497

good reservoir property is prone to be rich in hydrocarbons, which are preferred hydrocarbon

498

migration pathway.

499

(a)

500 501

(b)

502 503

Fig.17. Physical properties distribution of reservoirs in the Ordovician of the Tazhong Uplift. (a)

504

Porosity distribution. (b) Permeability distribution.

ACS Paragon Plus Environment

Page 32 of 48

Page 33 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

505

Energy & Fuels

6.2 Application for Hydrocarbon Exploration

506

Enormous progress of the Ordovician hydrocarbon exploration activities in the 1FB, NPB and

507

the north part of the 10FB of the Tazhong Uplift have been got, and exploration activities are moving

508

further towards the south part of the 10FB and SFB nowadays. 93-94 Whether the SFB and south part

509

of the 10FB have hydrocarbon exploration potential or not become a large challenge.

510

Hydrocarbon, sourced from the Manjiaer Depression, mainly charges into the uplift along the No.1

511

fault and laterally migrates into the northern part of north slope. However, little hydrocarbon can

512

migrate with a long distance and get accumulation in the south part of the 10FB and SFB based on

513

the afore-mentioned analysis. The lack of sufficient oil sources make that some geochemists deduce

514

the limited exploration potential of south part of the 10FB and SFB. 64 In our work, the Ordovician

515

hydrocarbon discovered in the uplift can derive from both the Manjiaer Depression and the Tazhong

516

Uplift itself, and we confirm that the No. 10 fault is an additional oil-migrated fault (Fig. 18).

517

Hydrocarbon, originated from the Tazhong Uplift itself, mainly charges into the Tazhong Uplift

518

along the 10FB and gets accumulation nearby. In addition, previous studies proved the SFB and

519

south part of the 10FB have the similar reservoir and caprock condition to the 1FB and NPB (Fig.18).

520

18,93

521

and it is wise to choose the south part of the 10FB first.

50,64

Consequently, we can indicate the SPB and south part of the 10FB have exploration potential,

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

522 523

Fig. 18. The Ordovician hydrocarbon migration and accumulation model in Tazhong petroleum

524

system.

525

7 CONCLUSION

526

(1) Hydrocarbons are introduced into the Ordovician of the Tazhong Uplift from the northern

527

Manjiaer Depression and the uplift itself through the 10FB and the 1FB. Hydrocarbon charge and

528

migration patter lead to anomalies of all the parameters in the 10FB and the 1FB.

529

(2) After introducing along the 10FB and 1FB, hydrocarbon migrated into the SPB and NPB

530

along different directions. As the distance from the 10FB and 1FB increases, the anomalies weak

531

gradually until then become disappeared in the NPB.

532

(3) The viewpoint of 10FB as an additional hydrocarbon charge place is further supported by

533

the evidence from the hydrocarbon charge intensity, structural framework, source rock distribution,

534

and significantly improvement of the reservoir physical property (7~8 times at the 10FB).

535

(4) As geological conditions for hydrocarbon accumulation in the SPB and the south part of the

536

10FB are similar to those of 1FB and NPB, SFB and south part of the 10FB have exploration

537

potential, and south part of the 10FB should be emphasized.

ACS Paragon Plus Environment

Page 34 of 48

Page 35 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

538

Energy & Fuels

ACKNOWLEDGEMENTS

539

The authors thank the Tarim Oilfield Company of PetroChina for supporting the work and

540

providing samples and data. This work was funded by the National 973 Basic Research Program (no.

541

2011CB201100). The authors are particularly grateful to Professor Ryuzo Tanaka and three

542

anonymous reviewers for their constructive review and comments for the manuscript.

543

REFERRNCES

544

(1) Losh, S.; Eglington, L.; Schoell, M.; Wood, J. Vertical and lateral fluid flow related to a large

545

growth fault, south Eugene Island Block 330, offshore Louisiana. AAPG Bulletin 1999, 83,

546

244–276.

547 548 549 550

(2) Aydin, A. Fractures, faults, and hydrocarbon entrapment, migration and flow. Marine and Petroleum Geology 2000, 17, 797–814. (3) Sorkhabi, R.B.; Tsuji, Y. Faults, fluid flow and petroleum traps. Tulsa, Oklahoma: The American Association of Petroleum Geologists 2005.

551

(4) Fall, A.; Eichhubl, P.S.; Cumella, P.; Bodnar, R.J.; Laubach, S.E.; Becker, S.P. Testing the basin–

552

centered gas accumulation model using fluid inclusion observations, Southern Piceance Basin,

553

Colorado. AAPG Bulletin 2012, 96, 2297–2318.

554 555

(5) He, D.F.; Jia, C.Z.; Tong, X.G. Discussion and analysis of superimposed sedimentary basins. Petroleum Exploration and Development 2004, 1, 1–7 (in Chinese with English abstract).

556

(6) Zhang, Z.P.; Wang,Y.; Yun,J.B.; Zhou, B.; Zhao, Z.H.; Zheng, M.L. Control of faults at different

557

evolution stages on hydrocarbon accumulation in Tazhong area, the Tarim Basin. Oil& Gas

558

Geology 2009, 3, 316–323.

559

(7) Lan, X.D.; Lü, X.X.; Yu, H.F.; Zhu, Y.M.; Ya, B. Early Palaeozic carbonate reservoirs from the

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

560

Yingshan Formation of Well block ZG-43 in Tazhong Low Rise, Central Uplift, Tarim Basin,

561

NW China, geological features and controlling factors. Geological Journal 2014, 49, 256–270.

562

(8) Pang, H.; Chen, J.Q.; Pang, X.Q.; Liu, L.F.; Liu, K.Y.; Xiang, C.F. Key factors controlling

563

hydrocarbon accumulations in Ordovician carbonate reservoirs in the Tazhong area, Tarim basin,

564

western China. Marine and Petroleum Geology 2013, 43, 88–101.

565 566 567 568

(9) Lin, R.Z.; Zhang, M. Reservoir geochemistry–the latest progress in petrogeochemistry. Journal of Xi’an Petroleum Institute 1996, 11, 8–14 (in Chinese with English abstract). (10) Zhang, S.C.; Wang, F.Y.; Zhang, B.M.; Liang, D.G.; Zhao, M.J. Geochemistry research of the Upper Ordovician source rocks in the Tarim Basin. Acta Petrolei Sinica 2000, 21, 1–7.

569

(11) Gu, Y.; Huang, J.W.; Shao, Z.B. Petroleum geochemistry and hydrocarbon migration in Tahe oil

570

field of the Tarim Basin (in Chinese with English abstract): Petroleum Geology and Experiment

571

2003, 25, 746–750.

572

(12) Sun, Y.G.; Xu, S.P.; Lu, H. Source facies of the Paleozoic petroleum systems in the Tabei Uplift,

573

Tarim Basin, NW China: implications from aryl isoprenoids in crude oils. Organic

574

Geochemistry 2003, 4, 629–634.

575

(13) Han, J.F.; Mei, L.F.; Yang, H.J.; Zhang, H.Z.; Xu, Z.M.; Gu, Q.Y.; Yu, H. F. Nonhydrocarbon

576

origin of Ordovician natural gas in Tazhong of Tarim Basin and its implications for

577

nonhydrocarbon accumulation (in Chinese with English abstract): Earth Science Frontiers 2009,

578

16, 314–325.

579 580 581

(14) Ma, A.L.; Jin, Z.J.; Zhang, D.J. Application of fluid inclusion in reservoir geochemistry (in Chinese with English abstract): Journal of Xinjiang Petroleum Institute 2004, 16, 1–5. (15) Guo, J.J.; Chen, J.F.; Wang, T.G. Oil migration orientation of the Ordovician in the Tazhong

ACS Paragon Plus Environment

Page 36 of 48

Page 37 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

582

Uplift. Journal of Southwest Petroleum University (Science & Technology Edition) 2008, 3, 8–

583

12 (in Chinese with English abstract).

584

(16) Xiang, C.F.; Pang, X.Q.; Yang, W.J. Hydrocarbon migration and accumulation along the fault

585

intersection zone: A case study on the reef–flat systems of the No. 1 slope break zone in the

586

Tazhong area, Tarim Basin. Petroleum Science 2010, 7, 211–225.

587

(17) Wu, F.F.; Zhu, G.Y.; Zhang, S.C.; Jin, Q.; Han, J.F.; Zhang, B. Types of hydrocarbon migration

588

pathways and its controlling effects on hydrocarbon distribution in Tarim Basin. Acta Petrolei

589

Sinica 2009, 3, 332–341.

590

(18) Yang, H.J.; Li, K.K.; Pan, W.Q.; Xiao, Z.Y.; Cai, C.F. Burial hydrothermal dissolution fluid

591

activity and its transforming effect on the reservoirs in Ordovician in Central Tarim. Acta

592

Petrologica Sinica 2012, 3, 783–792.

593

(19) Zhou, X.Y.; Lü, X.X.; Yang, H.J.; Wang, X.; Yu, H.F.; Cai, J.; Lan, X.D. Effects of strike–slip

594

faults on the differential enrichment of hydrocarbons in the northern slope of Tazhong area.

595

Acta petrolei sinica 2013, 4, 628–637.

596

(20) Pang, H.; Chen, J.Q.; Pang, X.Q.; Liu, K.Y.; Liu, L.F.; Xiang, C.F.; Li, S.M. Analysis of

597

secondary migration of hydrocarbons in the Ordovician carbonate reservoirs in the Tazhong

598

Uplift, Tarim Basin, China. AAPG Bulletin 2013, 97, 1765–1783.

599

(21) Lan, X.D.; Lü, X.X.; Zhu, Y.M.; Yu, H.F. The geometry and origin of strike–slip faults cutting

600

the Tazhong low rise megaanticline (central Uplift, Tarim Basin, China) and their control on

601

hydrocarbon distribution in carbonate reservoirs. Journal of Natural Gas Science and

602

Engineering 2015, 22, 633–645.

603

(22) Zhang, Z.P.; Wang,Y.; Yun,J.B.; Zhou, B.; Zhao, Z.H.; Zheng, M.L. Control of faults at different

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

604

evolution stages on hydrocarbon accumulation in Tazhong area, the Tarim Basin. Oil & Gas

605

Geology 2009, 3, 316–323.

606 607

(23) Fu, J.M.; Liu, D.H. Gas migration, reservoir and capping conditions. Science Press, Beijing, 1992, 57–157 (in Chinese with English abstract).

608

(24) Miao, Z.Y.; Chen, J.F.; Guo, J.J.; Zhang, C.; Li, W.; Wang, G.N. Geochemistical characteristics

609

of butane gas in Tarim basin, Journal of China university of mining & technology 2011, 4, 592–

610

597.

611 612

(25) Li, C.X.; Wang, X.F.; Li, B.L. Paleozoic fault systems of the Tazhong uplift, Tarim Basin, China. Marine and Petroleum Geology 2013, 39, 48-58.

613

(26) Wu, G.H.; Cheng, L.F.; Liu, Y.K. Strike-slip fault systems of the Cambrian-Ordovician and its

614

oil-controlling effect in Tarim Basin. Xinjiang Petroleum Geology 2011, 32, 239-243 (in

615

Chinese).

616

(27) Li Y.J.; Wu, G.Y.; Meng, Q.L.; Yang, H.J.; Han, J.F.; Li, X.S.; Dong, L.S. Fault systems in

617

central area of the Tarim Basin: geometry, kinematics and dynamic settings. Chinese journal of

618

geology 2008, 43(1), 82-118.

619

(28) Pang, H.; Chen, J.Q.; Pang, X.Q.; Liu, K.Y.; Xiang, C.F. Estimation of the hydrocarbon loss

620

through major tectonic events in the Tazhong area, Tarim Basin, west China. Marine and

621

Petroleum Geology 2012, 38, 195-210

622

(29) Ding, W.L.; Fan, T.L.; Yu, B.S.; Huang, X.B.; Liu, C. Ordovician carbonate reservoir fracture

623

characteristics and fracture distribution forecasting in the Tazhong area of Tarim Basin,

624

Northwest China. Journal of Petroleum Science and Engineering 2012, 86-87, 62–70.

625

(30) Wu, G.H.; Li, Q.M.; Zhang, B.S. Structural characteristics and exploration fields of the No.1

ACS Paragon Plus Environment

Page 38 of 48

Page 39 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

626

faulted slope break in the Tazhong area. Acta Petrolei Sinica. 2005, 1, 27–30 (in Chinese with

627

English abstract)

628

(31) Wang, Z.M.; Zhao, K.Z.; Wu, G.H. Characteristics and main controlling factors of the upper

629

Ordovician reef–bank reservoir development in the Tazhong I slope–break zone. Oil & Gas

630

Geology 2007, 6, 797–801 (in Chinese with English abstract)

631

(32) Chen, L.X.; Yang, H.J.; Wu, G.H. Characteristics of the Ordovician reef-shoal reservoir in

632

Tazhong No.1 slope break zone, Tarim Basin. Xinjiang Petroleum Geology 2008, 3, 327–330

633

(in Chinese with English abstract).

634

(33) Han, J.F.; Mei, L.F.; Yang, H.J.; Wu, G.H.; Xu, Z.M.; Zhu, G.Y. The study of hydrocarbon

635

origin, transport and accumulation in Tazhong area, Tarim Basin. Nature Gas Geoscience 2008,

636

18, 421–435 (in Chinese with English abstract).

637

(34) Shen, W.B.; Pang X.Q.; Jiang, F.J.; Zhang, B.S.; Huo, Z.P.; Wang, Y.Y.; Hu, Tao.; Wang, G.

638

Accumulation model based on factors controlling Ordovician hydrocarbons generation,

639

migration, and enrichment in the Tazhong area, Tarim Basin, NW China. Arabia Journal of

640

Geoscience 2016, 9, 346–359.

641

(35) Wang, Z.M.; Yu, H.F.; Ji, Y.G.; Jing, B.; Zhang, H.Z. Key technology for the exploration and

642

development of large-super large marine carbonate reservoirs in Tazhong area. Xinjiang

643

Petroleum Geology 2011, 32, 218–223 (in Chinese with English abstract)

644

(36) Graham, S.A.; Brassell, S.; Carroll, A.R. Characteristics of selected petroleum source rocks,

645

Xinjiang Uygur autonomous region, Northwest China. AAPG Bulletin 1990, 74, 493–512.

646

(37) Liang, D.G.; Zhang, S.C.; Zhang, B.M.; Wang, F. Understanding on marine oil generation in

647

China based on Tarim Basin. Earth Science Front (China University of Geosciences, Beijing)

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

648 649 650 651 652 653 654 655 656 657 658

2000, 7, 534–547. (38) Zhang, S.C.; Hanson, A.D.; Moldowan, J.M. Paleozoic oil–source rock correlations in the Tarim Basin, northwest China. Organic Geochemistry 2000, 31, 273–286. (39) Zhang, S.C.; Huang, H. P. Geochemistry of Paleozoic marine petroleum from the Tarim Basin, NW China: Part 1. Oil family classification: Organic Geochemistry 2005, 36, 1204–1214. (40) Hanson, A.D.; Zhang, S.C.; Moldowan, J.M. Molecular organic geochemistry of the Tarim Basin: Northwest China: AAPG Bulletin 2000, 84, 1109–1128. (41) Wang, Z.M.; Xiao, Z.Y. Comprehensive review about the marine crude oil sources of Tarim Basin. Chinese Science Bulletin 2004, 49, 1–8. (42) Xiao, Z.Y.; Lu, Y.H.; Sang, H. A typical Cambrian oil reservoir: origin of oil reservoir in Well TZ62, Tarim Basin. Geochimica 2005, 34, 155–160 (in Chinese with English abstract).

659

(43) Cai, C.F.; Li, K.K.; Ma, A.L. Distinguishing Cambrian from Upper Ordovician source rocks,

660

evidence from sulfur isotopes and biomarkers in the Tarim Basin. Organic Geochemistry 2009,

661

40, 755–768

662

(44) Li, S.M.; Pang, X.Q.; Yang, H.J. Characteristics and genetic type of the oils in the Tazhong

663

Uplift. Earth Science—Journal of China university of geosciences 2008, 5, 635–642 (in Chinese

664

with English abstract).

665

(45) Li, S.M.; Pang, X.Q.; Yang, H.J. Geochemical characteristics and implication of high thermal

666

maturity oils in the Tazhong-I faulted slope break zone. Oil & Gas Geology 2008, 2, 210–216

667

(in Chinese with English abstract).

668

(46) Han, J.F.; Mei, L.F.; Yang, H.J.; Zhang, H.Z.; Xu, Z.M.; Gu, Q.Y.; Yu, H. F. Nonhydrocarbon

669

origin of Ordovician natural gas in Tazhong of Tarim Basin and its implications for

ACS Paragon Plus Environment

Page 40 of 48

Page 41 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

670

nonhydrocarbon accumulation (in Chinese with English abstract): Earth Science Frontiers 2009,

671

16, 314–325.

672

(47) Xiao, X.M.; Liu, D.H.; Fu, J.M. Multiple phases of hydrocarbon generation and migration in the

673

Tazhong petroleum system of the Tarim Basin, People’s Republic of China. Organic

674

Geochemistry 1996, 25, 191–197.

675 676

(48) Xiao, X.M.; Song, Z.G.; Liu, D.H.; Liu, Z.F.; Fu, J.M. The Tazhong hybrid petroleum system, Tarim Basin: Marine and Petroleum Geology 2000, 17, 1–12.

677

(49) Xiang, C.F.; Wang, J.Z.; Pang, X.Q. Differential hydrocarbon migration and entrapment in a

678

karstified carbonate reservoir, a case study of the well TZ83 block of the central Tarim Uplift

679

zone. Earth Science Frontiers 2009, 6, 349–358 (in Chinese with English abstract).

680

(50) Pang, X.Q.; Chen, J.Q.; Li, S.M.; Chen, J.F.; Wang, Y.X.; Pang, H. Evaluation method and

681

application of the relative contribution of marine hydrocarbon source rocks in the Tarim basin:

682

A case study from the Tazhong area. Marine and Petroleum Geology 2016, 77, 1–18.

683 684

(51) Hwang, R.J.; Ahmed, A.S.; Moldowan, J.M. Oil composition variation and reservoir continuity: Unity field, Sudan: Organic Geochemistry 1994, 21, 171–188.

685

(52) Han, J.F.; Mei, L.F.; Yang, H.J. Hydrocarbon accumulation mechanisms of the large–sized reef–

686

shoal complex condensate gas field in the Tazhong No.1 slope break zone, Tarim Basin.

687

Xinjiang Petroleum Geology 2008, 3, 323–326 (in Chinese with English abstract)

688

(53) Zhu, G.Y.; Zhang, S.C.; Liu, K.Y.; Yang, H.J.; Zhang, B.; Su, J.; Zhang, Y.G. A well-preserved

689

250 million-year-old oil accumulation in the Tarim Basin, western China, implications for

690

hydrocarbon exploration in old and deep basins. Marine and Petroleum Geology 2013, 43, 478–

691

488.

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

692

(54) Han, J.F.; Zhang, H.Z.; Yu, H.F.; Ji, Y.G.; Sun, C.H.; Han, J.; Dong, R.X. Hydrocarbon

693

accumulation characteristic and exploration on large marine carbonate condensate field in

694

Tazhong Uplift. Acta Petrologica Sinica 2012, 28(3), 769-782.

695

(55) Zhu, G.Y.; Zhang, B.T.; Yang, H.J.; Su, J.; Liu, K.Y.; Zhu, Y.F. Secondary alteration to ancient

696

oil reservoirs by late gas filling in the Tazhong area, Tarim Basin. Journal of Petroleum Science

697

and Engineering 2014, 122, 240–256.

698 699

(56) Dai, J.X. Identification and distinction of various alkane gases. Science China (Ser. B) 1992, 2, 187–193.

700

(57) Radke, M.; Welte, D.H.; Wilisch, H. Geochemical study on a well in the Western Canada Basin:

701

relation of the aromatic distribution pattern to maturity of organic matter. Geochim. Cosmochim.

702

Acta 1982, 46 (1), 1–10.

703 704 705 706

(58) Thompson, K.F.M. Gas–condensate migration and oil fractionation in deltaic systems. Marine and Petroleum Geology 1988, 5, 237–246. (59) Thompson, K.F.M.; Kennicutt II, M.C.; Brooks, J.M. Classification of offshore Gulf of Mexico oils and gas condensates. AAPG Bulletin 1990, 74, 187–198.

707

(60) Larter, S.; Mills, N. Phase-controlled molecular fractionations in migrating petroleum charges.

708

In: England, W.A., Fleet, A.J. (Eds.), Petroleum Migration. Geological Society, London, 1991,

709

137–147.

710 711 712 713

(61) Losh, S.; Cathles, L.; Meulbroek, P. Gas washing of oil along a regional transect, offshore Louisiana. Organic Geochemistry 2002, 33, 655–663. (62) Kissin, Y. Catagenesis and composition of petroleum: origin of n–alkanes and isoalkanes in petroleum crudes. Geochim. Cosmochim. Acta. 1987, 51, 2445–2457.

ACS Paragon Plus Environment

Page 42 of 48

Page 43 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

714

(63) Zhang, S.C.; Su, J.; Wang, X.M.; Zhu, G.Y.; Yang, H.J.; Liu, K.Y.; Li, Z.X. Geochemistry of

715

Palaeozoic marine petroleum from the Tarim Basin, NW China: Part 3. Thermal cracking of

716

liquid hydrocarbons and gas washing as the major mechanisms for deep gas condensate

717

accumulations. Organic Geochemistry 2011, 42, 1394–1410.

718

(64) Wang, Z.M.; Yang, H.J.; Qi, Y.M.; Chen, Y.Q.; Xu, Y.L. Ordovician gas exploration

719

breakthrough in the Gucheng lower uplift of the Tarim Basin and its enlightenment. Natural Gas

720

Industry 2014, 1, 1–9 (in Chinese with English abstract).

721 722 723 724

(65) Wei, L.L.; Kang, Z.H. An approach to flow units in fracture and cavernous carbonate reservoirs. Xinjiang Geology 2005, 2, 169–172 (in Chinese with English abstract). (66) Guo, C.H.; Yang, Y.; Mo, Z.M. Study and discussion of f low units of fractured carbonate reservoirs. Petroleum Geology and Engineering 2006, 6, 34–37.

725

(67) Wilhelms, A.; Larter, S.R.; Leythaeuser, D.; Dypvik, H. Recognition and quantification of the

726

effects of primary migration in a Jurassic clastic sourcerock from the Norwegian continental

727

shelf. Organic Geochemistry 1990, 16, 103–113.

728 729 730 731 732 733 734 735

(68) Zhu, G.Y.; Zhang, S.C.; Liang, Y.B. Origins of the high H2S-bearing natural gas in China. Acta Geologica Sinica 2005, 79, 697–708 (in Chinese with English abstract). (69) Cai, C.F.; Hu, W.S.; Worden, R.H. Thermochemical sulfate reduction in Cambrian-Ordovician carbonates in Central Tarim. Marine and Petroleum Geology 2001, 18, 729–741. (70) England, W.A.; Mackenzie, A.S.; Mann, D.M.; Quigley, T.M. The movement and entrapment of petroleum fluids in the subsurface. Journal of Geological Society 1987, 144, 327–347. (71) England, W.A. The organic geochemistry of petroleum reservoirs. Organic Geochemistry 1990, 16, 415–425.

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

736 737 738 739

(72) England, W.A. Reservoir geochemistry d a reservoir engineering perspective. Journal of Petroleum Science and Engineering 2007, 58, 344–354. (73) Horstad, I.; Larter, S.R. Petroleum migration, alteration, and remigration within troll field, Norwegian North Sea. AAPG Bulletin 1997, 81, 222–248.

740

(74) Leythaeuser, D.; Rückheim, J. Heterogeneity of oil composition within a reservoir as a

741

reflection of accumulation history. Geochimica et Cosmochimica Acta 1989, 53, 2119–2123.

742

(75) Peters, K.E.; Fowler, M.G. Applications of petroleum geochemistry to exploration and reservoir

743

management. Organic Geochemistry 2002, 33, 5–36.

744

(76) Xiao, Z.Y.; Li, M.J.; Huang, S.Y.; Wang, T.G.; Zhang, B.S.; Fang, R.H.; Zhang, K.; Ni, Z.Y.;

745

Zhao, Q.; Wang, D.W. Source, oil charging history and filling pathways of the Ordovician

746

carbonate reservoir in the Halahatang Oilfield, Tarim Basin, NW China. Marine and Petroleum

747

Geology 2016, 73, 59–71.

748

(77) Stahl, W.J. Carbon isotope fractionation in natural gases. Nature 1974, 251, 134–135.

749

(78) Dai, J.X.; Qi, H.F.; Song, Y.; Guan, D.S. Carbon isotope, types and genesis of coal-derived gas

750

compositions in China. Science in China Series 1986, 2, 1317–1326 (in Chinese with English

751

abstract).

752 753

(79) Xu, Y.C. Study on gas geochemistry in 1980s in China. Acta Sedimentologica Sinica 1992, 3, 57–69 (in Chinese with English abstract).

754

(80) Lü, X.X.; Yang, H.J.; Wang, X.; Han, J.F.; Bai, Z.K. Application of geochemical parameters in

755

hydrocabon migration studies taking Tazhong area of the Tarim as an example. Oil & Gas

756

Geology 2010, 31, 838–846 (in Chinese with English abstract).

757

(81) Du, J.H.; Zhou, X.Y.; Li, Q.M.; Wu, G.H.; Pan, W.Q.; Yang, T. Characteristics and controlling

ACS Paragon Plus Environment

Page 44 of 48

Page 45 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

758

factors of the large carbonate petroleum province in the Tarim Basin, NW China. Petroleum

759

Exploration and Development 2011, 38, 652–661.

760

(82) Wang, F.H.; Wang, Z.M.; Han, J.F.; Yu, H.F.; Ji, Y.G.; Zhao, K.Z. Geological condition of

761

hydrocarbon enrichment in condensate field in the Tazhong Uplift, Tarim Basin. Natural Gas

762

Geoscience 2009, 20:696–702 (in Chinese with English abstract).

763 764 765 766

(83) Hunt, J.M. Petroleum Geochemistry and Geology 2nd edn. W H Freeman: New York; 1994, 1– 627. (84) Qi, J.F.; Yang, Q.; Wang, Z.Y. The discussion for the problems of the basin paleotectonic map drawing. China Journal of Geology 2003, 38, 413–424 (in China with English abstract)

767

(85) Xiao, L.H.; Li, H.; Meng, Y.L.; Zhang, L.X., Wei, A.J.; Li, J.; Zhang, W.C.; Yin, X.L.; Wang,

768

Z.G. Vitrinite reflectance modeling in the over-pressured formations. Petroleum exploration and

769

development 2005, 32, 14-17.

770

(86) Wang, F.Y.; Zhang, S.C.; Zhang, B.M.; Xiao, Z.Y.; Liu, C.W. Maturity and its history of

771

Cambrian marine source rocks in the Tarim Basin (in Chinese with English abstract):

772

Geochimica. 2003, 32, 461–468.

773

(87) Yang, W.; Wei, G.Q.; Wang, Q.H.; Xiao, Z.Y. Two types of Cambrian source rocks and related

774

petroleum systems in Tarim Basin (in Chinese with English abstract): Oil & Gas Geology 2004,

775

25, 263–267.

776

(88) Miles, J.A. Secondary migration routes in the Brent sandstones of the Viking Graben and East

777

Shetland Basin, evidence from oil residues and subsurface pressure data. AAPG Bulletin 1990,

778

11, 1718–1735.

779

(89) Pratsch, J.C. The distribution of major oil and gas reserves in regional basin structures, an

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

780

example from the powder river basin, Wyoming. Journal of Petroleum Geology 1986, 9, 393–

781

412.

782 783

(90) Hao, F.; Zou, H.Y.; Jiang, Q. Dynamics of petroleum accumulation and its advances. Earth Science, Journal of China University of Geosciences 2000, 7, 11–20.

784

(91) Duggan, J.P.; Mountjoy, E.W.; Stasiuk, L.D. Fault–controlled dolomitization at Swan Hills

785

Simonette oil field (Devonian), deep basin west–central Alberta, Canada. Sedimentology 2001,

786

48, 301–323

787

(92) Yu, H.F.; Bai, Z.H.; Deng, L.P.; Jian, W.W.; Pan, Y.Y.; Zhao, Y. Determination and geological

788

significances of Yingshan Unconformity of the Lower Ordovician in Tazhong area, Tarim Basin.

789

Xinjiang Petroleum Geology 2011, 32, 231–234 (in Chinese with English abstract).

790

(93) Yang, H.J.; Wu, G.H.; Han, J.F. Characteristics of hydrocarbon enrichment along the Ordovician

791

carbonate platform margin in the central uplift of Tarim Basin: Acta Petrolei Scinica 2007, 28,

792

26–30. (in Chinese with English abstract)

793

(94) Lü, X.X.; Wang, Y.F.; Yu, H.F.; Bai, Z.K. Major factors affecting the closure of marine

794

carbonate caprock and their quantitative evaluation: A case study of Ordovician rocks on the

795

northern slope of the Tazhong Uplift in the Tarim Basin, western China. Marine and Petroleum

796

Geology 2017, 83, 231–245.

797

FIGURE CAPTION

798

Fig. 1. The Ordovician reservoired oil-gas distribution in the Tazhong Uplift, Tarim Basin.

799

Fig. 2. Representative profiles illustrate the tectonic frameworks of different segments of the No.10

800

fault belt. C = Carboniferous; D = Devonian; S = Silurian; O3s = upper Ordovician Sangtamu

801

Formation; O3l = upper Ordovician Lianglitage Formation; O1y = lower Ordovician Yingshan

ACS Paragon Plus Environment

Page 46 of 48

Page 47 of 48 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

Energy & Fuels

802

Formation; O1p = lower Ordovician Penglaiba Formation; ∈= Cambrian.

803

Fig. 3. Lithology and petroleum geological settings in the Tazhong Uplift.

804

Fig. 4. Oil density distribution in the Ordovician reservoirs in the Tazhong Uplift.

805

Fig. 5. Wax content distribution in the Ordovician reservoirs in the Tazhong Uplift.

806

Fig. 6. Geothermal and burial history of stratums in the Tazhong Uplift

807

Fig. 7. Facies distribution in the Ordovician reservoirs in the Tazhong Uplift.

808

Fig. 8. GOR distribution in the Ordovician reservoirs in the Tazhong Uplift.

809

Fig. 9. Dry coefficient distribution in the Ordovician reservoirs in the Tazhong Uplift.

810

Fig. 10. H2S content distribution in the Ordovician reservoirs in the Tazhong Uplift.

811

Fig. 11. Vertical migration characteristic of gas with the parameter of △R3. The △R3 value is smaller

812

in the deeper reservoir. The dashed line is the boundary line of △R3 value with different depth. The

813

wells are seen in Figure 1. (a) Well ZG43; (b) ZG431; (c) ZG44C; (d) ZG51.

814

Fig. 12. Ts/(Ts+Tm) ratio distribution in the Ordovician reservoirs in the Tazhong Uplift.

815

Fig. 13. Vertical migration characteristic of oil with the geochemical parameters in the section. D =

816

Devonian; S = Silurian; O3s = upper Ordovician Sangtamu Formation; O3l = upper Ordovician

817

Lianglitage Formation; O1y = lower Ordovician Yingshan Formation; O1p = lower Ordovician

818

Penglaiba Formation; ∈= Cambrian.

819

Fig. 14. Methane carbon isotope composition distribution in the Ordovician reservoirs in Tazhong

820

Uplift.

821

Fig.15. Structural form of the top of the Ordovician during the major accumulation period in the

822

Tazhong Uplift.

823

Fig. 16. Source rock distribution in the Tarim Basin (modified from the Zhang et al., 2000a, b, 2012).

ACS Paragon Plus Environment

Energy & Fuels 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

824

(a) The lower-Middle Cambrian source rock. (b) The Middle-upper Ordovician source rock.

825

Fig.17. Physical properties distribution of reservoirs in the Ordovician of the Tazhong Uplift. (a)

826

Porosity distribution. (b) Permeability distribution.

827

Fig. 18. Ordovician hydrocarbon migration and accumulation model in the Tazhong petroleum

828

system. S = Silurian; O3s = upper Ordovician Sangtamu Formation; O3l = upper Ordovician

829

Lianglitage Formation; O1y = lower Ordovician Yingshan Formation; O1p = lower Ordovician

830

Penglaiba Formation; ∈= Cambrian.

831

ACS Paragon Plus Environment

Page 48 of 48