Supporting Information Palladium-Catalyzed Sonogashira-Coupling Conjoined C-H Activation: A Regioselective Tandem Strategy to Access Indolo-, and Pyrrolo[1,2-a]quinolines Satya Prakash Shukla, † Rakesh K. Tiwari†, ‡ and Akhilesh K. Verma,*, † †
Synthetic Organic Chemistry Research Laboratory, Department of Chemistry, University of
Delhi, Delhi, 110007, India ‡
Department of Biomedical & Pharmaceutical Sciences, College of Pharmacy, University of
Rhode Island, Kingston, Rhode Island, USA
[email protected] Contents S. No.
Page No.
1.
Copies of 1H NMR, a]quinolines (4a−v)
13
2.
Copies of 1H NMR, a]quinolines (5a−k)
13
3.
Copies of 1H NMR, 13C NMR and HRMS of 5-nitro-1-(2-(p- S 102 − S 104 tolylethynyl)phenyl)-1H-indole (6w)
C NMR and HRMS of Indolo[1.2-
S 3 − S 68
C NMR and HRMS of Pyrrolo[1.2-
S 69 − S 101
S 1
Copies of 1H NMR, 13C NMR and HRMS
S 2
(4a) (1H NMR)
S 3
(4a) (13C NMR)
S 4
(4a) (HRMS)
S 5
(4b) (1H NMR)
S 6
(4b) (13C NMR)
S 7
(4b) (HRMS)
S 8
(4c) (1H NMR)
S 9
(4c) (13C NMR)
S 10
(4c) (HRMS)
S 11
(4d) (1H NMR)
S 12
(4d) (13C NMR)
S 13
(4d) (HRMS)
S 14
Me N
(4e) (1H NMR)
S 15
Ph
Me N
(4e) (13C NMR)
S 16
Ph
Me N
(4e) (HRMS)
S 17
Ph
Me
OMe
N
(4f) (1H NMR)
S 18
Me
OMe
N
(4f) (13C NMR)
S 19
Me
OMe
N
(4f) (1H NMR)
S 20
(4g) (1H NMR)
S 21
(4g) (13C NMR)
S 22
(4g) (HRMS)
S 23
(4h) (1H NMR)
S 24
(4h) (13C NMR)
S 25
(4h) (HRMS)
S 26
(4i) (1H NMR)
S 27
(4i) (13C NMR)
S 28
(4i) (HRMS)
S 29
(4j) (1H NMR)
S 30
(4j) (13C NMR)
S 31
(4j) (1H NMR)
S 32
(4k) (1H NMR)
S 33
(4k) (13C NMR)
S 34
(4k) (HRMS)
S 35
(4l) (1H NMR)
S 36
(4l) (13C NMR)
S 37
(4l) (HRMS)
S 38
(4m) (1H NMR)
S 39
(4m) (13C NMR)
S 40
(4m) (HRMS)
S 41
(4n) (1H NMR)
S 42
(4n) (13C NMR)
S 43
(4n) (HRMS)
S 44
(4o) (1H NMR)
S 45
(4o) (13C NMR)
S 46
(4o) (HRMS)
S 47
(4p) (1H NMR)
S 48
(4p) (13C NMR)
S 49
(4p) (HRMS)
S 50
(4q) (1H NMR)
S 51
(4q) (13C NMR)
S 52
(4q) (HRMS)
S 53
(4r) (1H NMR)
S 54
(4r) (13C NMR)
S 55
(4r) (HRMS)
S 56
(4s) (1H NMR)
S 57
(4s) (13C NMR)
S 58
(4s) (HRMS)
S 59
(4t) (1H NMR)
S 60
(4t) (13C NMR)
S 61
(4t) (HRMS)
S 62
(4u) (1H NMR)
S 63
(4u) (13C NMR)
S 64
(4u) (HRMS)
S 65
(4v) (1H NMR)
S 66
(4v) (13C NMR)
S 67
(4v) (HRMS)
S 68
(5a) (1H NMR)
S 69
(5a) (13C NMR)
S 70
(5a) (HRMS)
S 71
(5b) (1H NMR)
S 72
(5b) (13C NMR)
S 73
(5b) (HRMS)
S 74
(5c) (1H NMR)
S 75
(5c) (13C NMR)
S 76
(5c) (HRMS)
S 77
(5d) (1H NMR)
S 78
(5d) (13C NMR)
S 79
(5d) (HRMS)
S 80
(5e) (1H NMR)
S 81
(5e) (13C NMR)
S 82
(5e) (HRMS)
S 83
(5f) (1H NMR)
S 84
(5f) (13C NMR)
S 85
(5f) (HRMS)
S 86
CH3
N
(5g) (1H NMR)
S 87
CH3
N
(5g) (13C NMR)
S 88
CH3
N
(5g) (HRMS)
S 89
(5h) (1H NMR)
S 90
(5h) (13C NMR)
S 91
(5h) (HRMS)
S 92
(5i) (1H NMR)
S 93
(5i) (13C NMR)
S 94
(5i) (HRMS)
S 95
(5j) (1H NMR)
S 96
(5j) (13C NMR)
S 97
(5j) (HRMS)
S 98
CF3 N
(5k) (1H NMR)
S 99
CF3 N
(5k) (13C NMR)
S 100
CF3 N
(5k) (HRMS)
S 101
(6w) (1H NMR)
S 102
(6w) (13C NMR)
S 103
(6w) (HRMS)
S 104
